57 research outputs found
Graphene-Wrapped Sulfur Particles as a Rechargeable Lithium-Sulfur-Battery Cathode Material with High Capacity and Cycling Stability
We report the synthesis of a graphene-sulfur composite material by wrapping
polyethyleneglycol (PEG) coated submicron sulfur particles with mildly oxidized
graphene oxide sheets decorated by carbon black nanoparticles. The PEG and
graphene coating layers are important to accommodating volume expansion of the
coated sulfur particles during discharge, trapping soluble polysulfide
intermediates and rendering the sulfur particles electrically conducting. The
resulting graphene-sulfur composite showed high and stable specific capacities
up to ~600mAh/g over more than 100 cycles, representing a promising cathode
material for rechargeable lithium batteries with high energy density.Comment: published in Nano Letter
The complete consensus V3 loop peptide of the envelope protein gp120 of HIV-1 shows pronounced helical character in solution
The disulfide bridge closed cyclic peptide corresponding to the whole Consensus V3 loop of the envelope protein gp120 of HIV-1 was examined by proton 2D-NMR spectroscopy in water and in a 20% trifluoroethanol/water solution. In water, NOE data support a beta-turn conformation for the central conservative GPGR region and point towards partial formation of a helix in the C-terminal part. Upon addition of trifluoroethanol, a C-terminal helix is formed. This is evidenced by NOE data, alpha-proton chemical shift changes and changes in the J(N alpha) vicinal coupling constants. The C-terminal helix is amphipathic and also occurs in other examined strains, It could therefore be an important feature for the functioning of the V3 loop
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