29 research outputs found
High-pressure study of microcrystalline tungsten trioxide phase transitions by Raman spectroscopy
A high-pressure Raman study of microcrystalline tungsten oxide was performed in the 0.1 MPa-31 GPa pressure range under isostatic and non-isostatic conditions. The phase transitions, which take place below 0.1 GPa and at 22 GPa are first order, while two further structural changes, observed at about 3 and 10 GPa, are diffuse. Surprisingly, the non-isostatic conditions do not induce inhomogeneous band broadenings and do not modify the transitions sequence observed in isostatic conditions. Compressibility of the different phases is estimated from spectral data
Nanostructure evolution in cluster-assembled WO x films synthesized by radio-frequency assisted laser ablation
Structural, electrical and gas-sensing properties of In2O3 : Ag composite nanoparticle layers
A Brief Overview of the Effect of High Pressures on the Vibrational Spectra of Biomaterials
The performance of silver modified tungsten oxide for the removal of 2-CP and 2-NP in sunlight exposure: Optical, electrochemical and photocatalytic properties
Preparing the future post-mortem analysis of beryllium-based JET and ITER samples by multi-wavelengths Raman spectroscopy on implanted Be, and co-deposited Be
High-temperature anodized WO3 nanoplatelet films for photosensitive devices
Anodization at elevated temperatures in nitric acid has been used for the production of highly porous and thick tungsten trioxide nanostructured films for photosensitive device applications. The anodization process resulted in platelet crystals with thicknesses of 20−60 nm and lengths of 100−1000 nm. Maximum thicknesses of 2.4 μm were obtained after 4 h of anodization at 20 V. X-ray diffraction analysis revealed that the as-prepared anodized samples contain predominantly hydrated tungstite phases depending on voltage, while films annealed at 400 °C for 4 h are predominantly orthorhombic WO3 phase. Photocurrent measurements revealed that the current density of the 2.4 μm nanostructured anodized film was 6 times larger than the nonanodized films. Dye-sensitized solar cells developed using these films produced 0.33 V and 0.65 mA/cm2 in open- and short-circuit conditions