Predicted Abundances of Carbon Compounds in Volcanic Gases on Io

We use chemical equilibrium calculations to model the speciation of carbon in volcanic gases on Io. The calculations cover wide temperature (500-2000 K), pressure (10^-8 to 10^+2 bars), and composition ranges (bulk O/S atomic ratios \~0 to 3), which overlap the nominal conditions at Pele (1760 K, 0.01 bar, O/S ~ 1.5). Bulk C/S atomic ratios ranging from 10^-6 to 10^-1 in volcanic gases are used with a nominal value of 10^-3 based upon upper limits from Voyager for carbon in the Loki plume on Io. Carbon monoxide and CO2 are the two major carbon gases under all conditions studied. Carbonyl sulfide and CS2 are orders of magnitude less abundant. Consideration of different loss processes (photolysis, condensation, kinetic reactions in the plume) indicates that photolysis is probably the major loss process for all gases. Both CO and CO2 should be observable in volcanic plumes and in Io's atmosphere at abundances of several hundred parts per million by volume for a bulk C/S ratio of 10^-3.Comment: 21 pages, 4 figures, 4 tables; accepted by Astrophysical Journa

Characterization of nanometer-sized, mechanically exfoliated graphene on the H-passivated Si(100) surface using scanning tunnelling microscopy

We have developed a method for depositing graphene monolayers and bilayers with minimum lateral dimensions of 2-10 nm by the mechanical exfoliation of graphite onto the Si(100)-2x1:H surface. Room temperature, ultra-high vacuum (UHV) tunnelling spectroscopy measurements of nanometer-sized single-layer graphene reveal a size dependent energy gap ranging from 0.1-1 eV. Furthermore, the number of graphene layers can be directly determined from scanning tunnelling microscopy (STM) topographic contours. This atomistic study provides an experimental basis for probing the electronic structure of nanometer-sized graphene which can assist the development of graphene-based nanoelectronics.Comment: Accepted for publication in Nanotechnolog

Effectiveness of fecal-derived microbiota transfer using orally administered capsules for recurrent Clostridium difficile infection

BACKGROUND: Clostridium difficile infection (CDI), a complication of antibiotic-induced injury to the gut microbiome, is a prevalent and dangerous cause of infectious diarrhea. Antimicrobial therapy for CDI is typically effective for acute symptoms, but up to one third of patients later experience recurrent CDI. Fecal-derived microbiota transplantation (FMT) can ameliorate the underlying dysbiosis and is highly effective for recurrent CDI. Traditional methods of FMT are limited by patient discomfort, risk and inefficient procedures. Many individuals with recurrent CDI have extensive comorbidities and advanced age. Widespread use of FMT requires strategies that are non-invasive, scalable and applicable across healthcare settings. METHODS: A method to facilitate microbiota transfer was developed. Fecal samples were collected and screened for potential pathogens. Bacteria were purified, concentrated, cryopreserved and formulated into multi-layered capsules. Capsules were administered to patients with recurrent CDI, who were then monitored for 90 days. RESULTS: Thirteen women and six men with recurrent CDI were provided with microbiota transfer with orally administered capsules. The procedure was well tolerated. Thirteen individuals responded to a single course. Four patients were cured after a second course. There were 2 failures. The cumulative clinical cure rate of 89% is similar to the rates achieved with reported fecal-derived transplantation procedures. CONCLUSIONS: Recurrent CDI represents a profound dysbiosis and a debilitating chronic disease. Stable cure can be achieved by restoring the gut microbiome with an effective, well-tolerated oral capsule treatment. This strategy of microbiota transfer can be widely applied and is particularly appropriate for frail patients

Fast Non-Adiabatic Two Qubit Gates for the Kane Quantum Computer

In this paper we apply the canonical decomposition of two qubit unitaries to find pulse schemes to control the proposed Kane quantum computer. We explicitly find pulse sequences for the CNOT, swap, square root of swap and controlled Z rotations. We analyze the speed and fidelity of these gates, both of which compare favorably to existing schemes. The pulse sequences presented in this paper are theoretically faster, higher fidelity, and simpler than existing schemes. Any two qubit gate may be easily found and implemented using similar pulse sequences. Numerical simulation is used to verify the accuracy of each pulse scheme

Like-charge attraction through hydrodynamic interaction

We demonstrate that the attractive interaction measured between like-charged colloidal spheres near a wall can be accounted for by a nonequilibrium hydrodynamic effect. We present both analytical results and Brownian dynamics simulations which quantitatively capture the one-wall experiments of Larsen and Grier (Nature 385, p. 230, 1997).Comment: 10 pages, 4 figure

Error Rate of the Kane Quantum Computer CNOT Gate in the Presence of Dephasing

We study the error rate of CNOT operations in the Kane solid state quantum computer architecture. A spin Hamiltonian is used to describe the system. Dephasing is included as exponential decay of the off diagonal elements of the system's density matrix. Using available spin echo decay data, the CNOT error rate is estimated at approsimately 10^{-3}.Comment: New version includes substantial additional data and merges two old figures into one. (12 pages, 6 figures

Measurements of polarized photo-pion production on longitudinally polarized HD and Implications for Convergence of the GDH Integral

We report new measurements of inclusive pion production from frozen-spin HD for polarized photon beams covering the Delta(1232) resonance. These provide data simultaneously on both H and D with nearly complete angular distributions of the spin-difference cross sections entering the Gerasimov-Drell-Hearn (GDH) sum rule. Recent results from Mainz and Bonn exceed the GDH prediction for the proton by 22 microbarns, suggesting as yet unmeasured high-energy components. Our pi0 data reveal a different angular dependence than assumed in Mainz analyses and integrate to a value that is 18 microbarns lower, suggesting a more rapid convergence. Our results for deuterium are somewhat lower than published data, considerably more precise and generally lower than available calculations.Comment: 4 pages, 4 figures. Submitted for publication in Physical Review Letter

Gyroscopic Precession and Inertial Forces in Axially Symmetric Stationary Spacetimes

We study the phenomenon of gyroscopic precession and the analogues of inertial forces within the framework of general relativity. Covariant connections between the two are established for circular orbits in stationary spacetimes with axial symmetry. Specializing to static spacetimes, we prove that gyroscopic precession and centrifugal force both reverse at the photon orbits. Simultaneous non-reversal of these in the case of stationary spacetimes is discussed. Further insight is gained in the case of static spacetime by considering the phenomena in a spacetime conformal to the original one. Gravi-electric and gravi-magnetic fields are studied and their relation to inertial forces is established.Comment: 21 pages, latex, no figures, http://202.41.67.76/~nayak/gpifass.te

Optical Conductivity in Mott-Hubbard Systems

We study the transfer of spectral weight in the optical spectra of a strongly correlated electron system as a function of temperature and interaction strength. Within a dynamical mean field theory of the Hubbard model that becomes exact in the limit of large lattice coordination, we predict an anomalous enhancement of spectral weight as a function of temperature in the correlated metallic state and report on experimental measurements which agree with this prediction in $V_2O_3$. We argue that the optical conductivity anomalies in the metal are connected to the proximity to a crossover region in the phase diagram of the model.Comment: 12 pages and 4 figures, to appear in Phys. Rev. Lett., v 75, p 105 (1995

Revisiting the influence of institutional forces on the written business plan:A replication study

The present paper re-analyzes and extends a study on institutional forces and the written business plan (Honig and Karlsson in J Manag 30(1):29–48, 2004). We attempt to examine to what extent critical decision making is evident in model and variable choice, and whether the implications provided by systematic replication efforts may serve to provide additional and perhaps unrecognized theoretical and/or empirical observations. We find that the key result—formal business planning does not affect performance, does not hold. In fact, we find evidence that formal business planning affects survival but not profitability. The re-analysis also reveals, that institutional antecedents to formal planning appear to be fragile and prone to researcher biases due to different coding and assumptions. Our study underscores the consequences of access to original data and coding material, and to rely upon current methodological explanations for subsequent analyses