Symmetric Diblock Copolymers in Thin Films (I): Phase stability in Self-Consistent Field Calculations and Monte Carlo Simulations

We investigate the phase behavior of symmetric AB diblock copolymers confined into a thin film. The film boundaries are parallel, impenetrable and attract the A component of the diblock copolymer. Using a self-consistent field technique [M.W. Matsen, J.Chem.Phys. {\bf 106}, 7781 (1997)], we study the ordered phases as a function of incompatibility $\chi$ and film thickness in the framework of the Gaussian chain model. For large film thickness and small incompatibility, we find first order transitions between phases with different number of lamellae which are parallel oriented to the film boundaries. At high incompatibility or small film thickness, transitions between parallel oriented and perpendicular oriented lamellae occur. We compare the self-consistent field calculations to Monte Carlo simulations of the bond fluctuation model for chain length N=32. In the simulations we quench several systems from $\chi N=0$ to $\chi N=30$ and monitor the morphology into which the diblock copolymers assemble. Three film thicknesses are investigated, corresponding to parallel oriented lamellae with 2 and 4 interfaces and a perpendicular oriented morphology. Good agreement between self-consistent field calculations and Monte Carlo simulations is found.Comment: to appear in J.Chem.Phy

Interfaces between highly incompatible polymers of different stiffness: Monte Carlo simulations and self-consistent field calculations

We investigate interfacial properties between two highly incompatible polymers of different stiffness. The extensive Monte Carlo simulations of the binary polymer melt yield detailed interfacial profiles and the interfacial tension via an analysis of capillary fluctuations. We extract an effective Flory-Huggins parameter from the simulations, which is used in self-consistent field calculations. These take due account of the chain architecture via a partial enumeration of the single chain partition function, using chain conformations obtained by Monte Carlo simulations of the pure phases. The agreement between the simulations and self-consistent field calculations is almost quantitative, however we find deviations from the predictions of the Gaussian chain model for high incompatibilities or large stiffness. The interfacial width at very high incompatibilities is smaller than the prediction of the Gaussian chain model, and decreases upon increasing the statistical segment length of the semi-flexible component.Comment: to appear in J.Chem.Phy

Simulations of the Magneto-rotational Instability in Core-Collapse Supernovae

We assess the importance of the magneto-rotational instability in core-collapse supernovae by an analysis of the growth rates of unstable modes in typical post-collapse systems and by numerical simulations of simplified models. The interplay of differential rotation and thermal stratification defines different instability regimes which we confirm in our simulations. We investigate the termination of the growth of the MRI by parasitic instabilities, establish scaling laws characterising the termination amplitude, and study the long-term evolution of the saturated turbulent state.Comment: 6 pages, 1 figure. To appear in Proceedings of 4th International Conference on Numerical Modeling of Space Plasma Flows (Chamonix 2009

Signaling Without Common Prior: An Experiment

The common prior assumption is pervasive in game-theoretic models with incomplete information. This paper investigates experimentally the importance of inducing a common prior in a two-person signaling game. For a specific probability distribution of the sender’s type, the long-run behavior without an induced common prior is shown to be different from the behavior when a common prior is induced, while for other distributions behavior is similar under both regimes. We also present a learning model that allows players to learn about the other players’ strategies and the prior distribution of the sender’s type. We show that this learning model accurately accounts for all main features of the data.common prior;signaling;experiment;learning

Lattice study of the infrared behavior of QCD Green's functions in Landau gauge

We summarize the current status of our numerical results for the gluon and ghost propagators and for the Kugo-Ojima confinement parameter in quenched SU(3) lattice Landau gauge theory. The data for the propagators are compared to our results obtained in the case of full QCD, simulated using two flavors of dynamical clover-improved Wilson fermions. We demonstrate that the infrared behavior of the ghost propagator is consistent with the Kugo-Ojima confinement criterion. Explicit violation of reflection positivity by the gluon propagator is shown. Additionally, we present results of a running coupling constant both at low and at large momenta.Comment: 7 pages, 8 figures, talk presented at Lattice2006 (Confinement and Topology