58 research outputs found

    Homogenization of the vibro-acoustic transmission on periodically perforated elastic plates interacting with flow

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    We consider acoustic waves propagating in an inviscid fluid interacting with a rigid periodically perforated plate in the presence of permanent flows. The paper presents a model of an acoustic interface obtained by the asymptotic homogenization of a thin transmission layer in which the plate is embedded. To account for the flow, a decomposition of the fluid pressure and velocity in the steady and fluctuating parts is employed. This enables for a linearization and an efficient use of the homogenization method which leads to a model order reduction effect. The dependence of an extended Helmholtz equation on the permanent flow introduces a locally periodic velocity field in the perforated plate vicinity, so that the coefficients of the homogenized interface depend on the flow. The derived model extended by natural coupling conditions provides an implicit Dirichlet-to-Neumann operator. Numerical simulations of wave propagation in a waveguide illustrate the flow speed influence on the acoustic transmission. Also some geometrical aspects are explored

    Multiscale modelling of flow due to the peristaltic wave in deforming poro-piezoelectric medium

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    The paper reports on the homogenization based modelling of fluid saturated poroelastic materials containing locally controlable piezoelectric (PZ) actuators. This option provides metamaterial properties which enable to convert the electric power into the fluid transport due to the peristaltic deformation wave induced by the propagating voltage wave. A quasi-linear PZ-poroelastic material model is proposed to respect dependence of the effective medium parameters on the deformation at the microstructure (pore) level. Due to the sensitivity analysis of the homogenized coefficient, the two-scale modelling avoids any need to update the local microconfigurations. Numerical studies has been performed as the proof of the concept

    Ultrafast Photo-Induced Charge Transfer Unveiled by Two-Dimensional Electronic Spectroscopy

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    The interaction of exciton and charge transfer (CT) states plays a central role in photo-induced CT processes in chemistry, biology and physics. In this work, we use a combination of two-dimensional electronic spectroscopy (2D-ES), pump-probe measurements and quantum chemistry to investigate the ultrafast CT dynamics in a lutetium bisphthalocyanine dimer in different oxidation states. It is found that in the anionic form, the combination of strong CT-exciton interaction and electronic asymmetry induced by a counter-ion enables CT between the two macrocycles of the complex on a 30 fs timescale. Following optical excitation, a chain of electron and hole transfer steps gives rise to characteristic cross-peak dynamics in the electronic 2D spectra, and we monitor how the excited state charge density ultimately localizes on the macrocycle closest to the counter-ion within 100 fs. A comparison with the dynamics in the radical species further elucidates how CT states modulate the electronic structure and tune fs-reaction dynamics. Our experiments demonstrate the unique capability of 2D-ES in combination with other methods to decipher ultrafast CT dynamics.Comment: 14 pages, 11 figures, and Supporting informatio
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