Adiabatic Electron-Phonon Interaction and High-Temperature Thermodynamics of A15 Compounds

Inelastic neutron scattering was used to measure the phonon densities of states of the A15 compounds V_3Si, V_3Ge, and V_3Co at temperatures from 10 to 1273 K. It was found that phonons in V_3Si and V_3Ge, which are superconducting at low temperatures, exhibit an anomalous stiffening with increasing temperature, whereas phonons in V_3Co have a normal softening behavior. First-principles calculations show that this anomalous increase in phonon frequencies at high temperatures originates with an adiabatic electron-phonon coupling mechanism. The anomaly is caused by the thermally induced broadening of sharp peaks in the electronic density of states of V_3Si and V_3Ge, which tends to decrease the electronic density at the Fermi level. These results show that the adiabatic electron-phonon coupling can influence the phonon thermodynamics at temperatures exceeding 1000 K

Compliant rolling-contact architected materials for shape reconfigurability.

Architected materials can achieve impressive shape-changing capabilities according to how their microarchitecture is engineered. Here we introduce an approach for dramatically advancing such capabilities by utilizing wrapped flexure straps to guide the rolling motions of tightly packed micro-cams that constitute the material's microarchitecture. This approach enables high shape-morphing versatility and extreme ranges of deformation without accruing appreciable increases in strain energy or internal stress. Two-dimensional and three-dimensional macroscale prototypes are demonstrated, and the analytical theory necessary to design the proposed materials is provided and packaged as a software tool. An approach that combines two-photon stereolithography and scanning holographic optical tweezers is demonstrated to enable the fabrication of the proposed materials at their intended microscale

Electron-phonon interactions and high-temperature thermodynamics of vanadium and its alloys

Inelastic neutron scattering was used to measure the phonon densities of states (DOSs) for pure V and solid solutions of V with 6 to 7at% of Co, Nb, and Pt, at temperatures from 10 K to 1323 K. Ancillary measurements of heat capacity and thermal expansion are reported on V and V-7at%Co and used to help identify the different sources of entropy. Pure V exhibits an anomalous anharmonic stiffening of phonons with increasing temperature. This anharmonicity is suppressed by Co and Pt, but not by isoelectronic Nb solutes. The changes in phonon frequency with alloying and with temperature both correlate to the decrease in electron density of states (DOS) at the Fermi level as calculated using density functional theory. The effects of both temperature and alloying can be understood in terms of an adiabatic electron-phonon interaction (EPI), which broadens sharp features in the electron DOS. These results show that the adiabatic EPI can influence the phonon thermodynamics at temperatures exceeding 1000 K, and that thermal trends of phonons may help assess the strength of the EPI

Additively manufacturable micro-mechanical logic gates.

Early examples of computers were almost exclusively based on mechanical devices. Although electronic computers became dominant in the past 60 years, recent advancements in three-dimensional micro-additive manufacturing technology provide new fabrication techniques for complex microstructures which have rekindled research interest in mechanical computations. Here we propose a new digital mechanical computation approach based on additively-manufacturable micro-mechanical logic gates. The proposed mechanical logic gates (i.e., NOT, AND, OR, NAND, and NOR gates) utilize multi-stable micro-flexures that buckle to perform Boolean computations based purely on mechanical forces and displacements with no electronic components. A key benefit of the proposed approach is that such systems can be additively fabricated as embedded parts of microarchitected metamaterials that are capable of interacting mechanically with their surrounding environment while processing and storing digital data internally without requiring electric power