112 research outputs found
Stress distribution and the fragility of supercooled melts
We formulate a minimal ansatz for local stress distribution in a solid that
includes the possibility of strongly anharmonic short-length motions. We
discover a broken-symmetry metastable phase that exhibits an aperiodic,
frozen-in stress distribution. This aperiodic metastable phase is characterized
by many distinct, nearly degenerate configurations. The activated transitions
between the configurations are mapped onto the dynamics of a long range
classical Heisenberg model with 6-component spins and anisotropic couplings. We
argue the metastable phase corresponds to a deeply supercooled non-polymeric,
non-metallic liquid, and further establish an order parameter for the
glass-to-crystal transition. The spin model itself exhibits a continuous range
of behaviors between two limits corresponding to frozen-in shear and uniform
compression/dilation respectively. The two regimes are separated by a
continuous transition controlled by the anisotropy in the spin-spin
interaction, which is directly related to the Poisson ratio of the
material. The latter ratio and the ultra-violet cutoff of the theory determine
the liquid configurational entropy. Our results suggest that liquid's fragility
depends on the Poisson ratio in a non-monotonic way. The present ansatz
provides a microscopic framework for computing the configurational entropy and
relaxational spectrum of specific substances.Comment: 11 pages, 5 figures, Final version published in J Phys Chem
Universality in Glassy Low-Temperature Physics
We propose a microscopic translationally invariant glass model which exhibits
two level tunneling systems with a broad range of asymmetries and barrier
heights in its glassy phase. Their distribution is qualitatively different from
what is commonly assumed in phenomenological models, in that symmetric
tunneling systems are systematically suppressed. Still, the model exhibits the
usual glassy low-temperature anomalies. Universality is due to the collective
origin of the glassy potential energy landscape. We obtain a simple explanation
also for the mysterious {\em quantitative} universality expressed in the
unusually narrow universal glassy range of values for the internal friction
plateau.Comment: 4 pages, 5 figures, uses RevTeX
What are the interactions in quantum glasses?
The form of the low-temperature interactions between defects in neutral
glasses is reconsidered. We analyse the case where the defects can be modelled
either as simple 2-level tunneling systems, or tunneling rotational impurities.
The coupling to strain fields is determined up to 2nd order in the displacement
field. It is shown that the linear coupling generates not only the usual
Ising-like interaction between the rotational tunneling defect modes,
which cause them to freeze around a temperature , but also a random field
term. At lower temperatures the inversion symmetric tunneling modes are still
active - however the coupling of these to the frozen rotational modes, now via
the 2nd-order coupling to phonons, generates another random field term acting
on the inversion symmetric modes (as well as shorter-range interactions
between them). Detailed expressions for all these couplings are given.Comment: 12 pages, 2 figures. Minor modifications, published versio
Лазерные фазовые дальномеры: пути повышения точности
Scientific and technological progress in the field of geodetic and industrial measurements in terms of the use of laser rangefinders operating in ranges up to 5000 meters has led to a reduction in the error of such measuring instruments over the past ten years by two or more times. Such rapid development of high-precision rangefinder technologies has led to a significant revision of the requirements for their metrological support, as well as to the need to develop a new generation of length standards, the stock of metrological accuracy of which would provide an assessment of the metrological characteristics of all types of existing and promising length measuring instruments with a laser rangefinder. To solve this problem, the Institute’s staff conducted research within the framework of a number of thematic research and development works in terms of developing the appearance of a new generation of length standards operating in the range up to 5000 meters in an open atmosphere. Within the framework of this article, one of the developed models of a high-precision complex of measuring instruments for length and coordinate increments is considered, which is a serial high-precision laser phase light meter, modified by the institute’s staff in terms of the system for receiving and processing measuring signals. At the same time, in order to increase the accuracy of length measurements using the developed range finder layout, it is proposed to investigate ways to reduce the errors of the model components of the boundaries of its error. To ensure the smallest error in determining the hardware correction of the rangefinder layout, it is proposed to use funds from the state primary special standard of the unit of length. As promising ways to reduce the error in determining the phase difference of signals, it is proposed to use digital recording and signal processing devices that implement a method for calculating the phase difference of signals by mathematically processing the recorded data using a specially developed computational algorithm based on Fourier analysis. For the most accurate determination of the values of the pulse repetition frequency of signals and the values of the speed of light on the measured track, it is proposed to improve the means of determining these indicators. The use of the proposed methods to improve the accuracy of measuring the length of laser phase rangefinders allows you to provide the necessary margin of metrological accuracy. Научно-технический прогресс в сфере геодезических и промышленных измерений в части использования лазерных дальномеров, работающих в диапазонах до 5 000 метров, привел к уменьшению погрешности выше перечисленных средств измерений за последние десять лет в два и более раза. Следствием такого стремительного развития технологий высокоточной дальнометрии стал значительный пересмотр требований по их метрологическому обеспечению, а также необходимость разработки нового поколения эталонов длины, запас метрологической точности которых обеспечивал бы оценку метрологических характеристик всех типов существующих и перспективных средств измерений длины, имеющих в своем составе лазерный светодальномер. Для решения этой задачи авторами в рамках ряда тематических научно-исследовательских опытно-конструкторских работ проводились исследования с целью разработки нового поколения эталонов длины, работающих в диапазоне до 5 000 метров, в условиях открытой атмосферы. В данной статье рассмотрен один из разработанных макетов высокоточного комплекса средств измерений длины и приращений координат. Макет представляет собой высокоточный лазерный фазовый дальномер с доработанной системой приема и обработки измерительных сигналов. С помощью данного макета дальномера предлагается исследовать пути уменьшения составляющих его погрешности с целью повышения точности измерений длины. Для обеспечения наименьшей погрешности определения аппаратурной поправки макета дальномера могут служить средства из состава Государственного первичного специального эталона единицы длины. В качестве перспективных путей уменьшения погрешности определения разности фаз сигналов представляется возможным использовать устройства цифровой регистрации и обработки сигналов, в которых реализован метод расчета разности фаз сигналов путем математической обработки зарегистрированных данных с помощью специально разработанного вычислительного алгоритма на основе Фурье-анализа. Наиболее точное определение значений частоты следования импульсных сигналов и значений скорости света на измеряемой трассе может быть получено благодаря использованию высокоточных средств определения данных показателей. Реализация предложенных авторами методов повышения точности измерений длины лазерных фазовых дальномеров позволяет обеспечивать необходимый запас метрологической точности
The Ultimate Fate of Supercooled Liquids
In recent years it has become widely accepted that a dynamical length scale
{\xi}_{\alpha} plays an important role in supercooled liquids near the glass
transition. We examine the implications of the interplay between the growing
{\xi}_{\alpha} and the size of the crystal nucleus, {\xi}_M, which shrinks on
cooling. We argue that at low temperatures where {\xi}_{\alpha} > {\xi}_M a new
crystallization mechanism emerges enabling rapid development of a large scale
web of sparsely connected crystallinity. Though we predict this web percolates
the system at too low a temperature to be easily seen in the laboratory, there
are noticeable residual effects near the glass transition that can account for
several previously observed unexplained phenomena of deeply supercooled liquids
including Fischer clusters, and anomalous crystal growth near T_g
Analysis of Protein Markers in Plasma of Patients with Drug Dependence Syndrome: Observational Clinical Study
Background. In drug addiction treatment, the diagnostic process is based on the chemical toxicological determination of the intoxication substrate or its metabolite. Laboratory monitoring and prediction issues that could form the basis of secondary prevention remain unresolved. Specific nervous tissue proteins are considered to be the most promising laboratory markers of drug pathology.Objective — to determine some potential biomarkers of protein-chemical nature in the plasma of patients with drug dependence syndrome.Methods. The study was conducted according to the design of an observational clinical trial at the Narcological Dispensary of Krasnodar Krai in the period from 07.2021 to 07.2022. The main group (group 2) included 31 patients diagnosed with substance dependence syndrome. The control group (group 1, n = 15) consisted of healthy subjects submitted to occupational medical examinations. During the detoxification-stabilization therapy and rehabilitation, 5 proteins were determined in the plasma: brainand glial-derived neurotrophic factors, neuron-specific enolase, alpha-synuclein and calcium-binding protein S100B. Statistical analysis of the data involved the Mann-Whitney test for comparing the values of the control and experimental groups and the Wilcoxon test for comparing the values of one group obtained at different stages of observation. The calculations were carried out using StatPlus version 7 (AnalystSoft Inc., USA).Results. A total of 31 patients were included in the main group, 18 of them were followed up with a diagnosis of opioid dependence syndrome (n = 11) or psychostimulant dependence syndrome (n = 7). Patients dropped out of the study due to their refusal to participate in the study or undergo rehabilitation, or due to relapse of the disease. When admitted to the hospital, patients indicated a 45% decrease in brain-derived neurotrophic factor in the plasma ( p < 0.001), and a 3.9-fold decrease after rehabilitation course ( p < 0.001). Glial-derived neurotrophic factor in the plasma exceeded the controls 1.9 times ( p < 0.001) upon admission to hospital, but rapidly returned to normal values thereafter. Level of neuron-specific enolase in the plasma was also poor, 36% lower than the controls ( p <0.001), but approached the control values by the end of rehabilitation.Conclusion. The study obtained data indicating the changes in neurotrophic factors in the blood plasma of patients with opioid or psychostimulant dependence. The rehabilitation period was marked by a relatively rapid improving level of neurotrophins; however, brain-derived neurotrophic factor remained reduced despite the successful treatment, which may indicate the irreversible changes
Detection of hidden structures for arbitrary scales in complex physical systems
Recent decades have experienced the discovery of numerous complex materials. At the root of the complexity underlying many of these materials lies a large number of contending atomic- and largerscale configurations. In order to obtain a more detailed understanding of such systems, we need tools that enable the detection of pertinent structures on all spatial and temporal scales. Towards this end, we suggest a new method that applies to both static and dynamic systems which invokes ideas from network analysis and information theory. Our approach efficiently identifies basic unit cells, topological defects, and candidate natural structures. The method is particularly useful where a clear definition of order is lacking, and the identified features may constitute a natural point of departure for further analysis
Capturing the essence of folding and functions of biomolecules using Coarse-Grained Models
The distances over which biological molecules and their complexes can
function range from a few nanometres, in the case of folded structures, to
millimetres, for example during chromosome organization. Describing phenomena
that cover such diverse length, and also time scales, requires models that
capture the underlying physics for the particular length scale of interest.
Theoretical ideas, in particular, concepts from polymer physics, have guided
the development of coarse-grained models to study folding of DNA, RNA, and
proteins. More recently, such models and their variants have been applied to
the functions of biological nanomachines. Simulations using coarse-grained
models are now poised to address a wide range of problems in biology.Comment: 37 pages, 8 figure
Inference of hidden structures in complex physical systems by multi-scale clustering
We survey the application of a relatively new branch of statistical
physics--"community detection"-- to data mining. In particular, we focus on the
diagnosis of materials and automated image segmentation. Community detection
describes the quest of partitioning a complex system involving many elements
into optimally decoupled subsets or communities of such elements. We review a
multiresolution variant which is used to ascertain structures at different
spatial and temporal scales. Significant patterns are obtained by examining the
correlations between different independent solvers. Similar to other
combinatorial optimization problems in the NP complexity class, community
detection exhibits several phases. Typically, illuminating orders are revealed
by choosing parameters that lead to extremal information theory correlations.Comment: 25 pages, 16 Figures; a review of earlier work
Holographic Vitrification
We establish the existence of stable and metastable stationary black hole
bound states at finite temperature and chemical potentials in global and planar
four-dimensional asymptotically anti-de Sitter space. We determine a number of
features of their holographic duals and argue they represent structural
glasses. We map out their thermodynamic landscape in the probe approximation,
and show their relaxation dynamics exhibits logarithmic aging, with aging rates
determined by the distribution of barriers.Comment: 100 pages, 25 figure
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