Microscopic analysis of the octupole phase transition in Th isotopes

A shape phase transition between stable octupole deformation and octupole vibrations in Th nuclei is analyzed in a microscopic framework based on nuclear density functional theory. The relativistic functional DD-PC1 is used to calculate axially-symmetric quadrupole-octupole constrained energy surfaces. Observables related to order parameters are computed using an interacting-boson Hamiltonian, with parameters determined by mapping the microscopic energy surfaces to the expectation value of the Hamiltonian in the boson condensate. The systematics of constrained energy surfaces and low-energy excitation spectra point to the occurrence of a phase transition between octupole-deformed shapes and shapes characterized by octupole-soft potentials.Comment: 6 pages, 5 figures, accepted for publication in Physical Review C, Rapid Communicatio

Hypervelocity binary stars: smoking gun of massive binary black holes

The hypervelocity stars recently found in the Galactic halo are expelled from the Galactic center through interactions between binary stars and the central massive black hole or between single stars and a hypothetical massive binary black hole. In this paper, we demonstrate that binary stars can be ejected out of the Galactic center with velocities up to 10^3 km/s, while preserving their integrity, through interactions with a massive binary black hole. Binary stars are unlikely to attain such high velocities via scattering by a single massive black hole or through any other mechanisms. Based on the above theoretical prediction, we propose a search for binary systems among the hypervelocity stars. Discovery of hypervelocity binary stars, even one, is a definitive evidence of the existence of a massive binary black hole in the Galactic center.Comment: 5 pages, 3 figures, shortened version, ApJL in pres

Unusual Nernst effect suggestive of time-reversal violation in the striped cuprate La2−x_{2-x}Bax_xCuO4_4

The striped cuprate La$_{2-x}$Ba$_x$CuO$_4$ ($x=\frac18)$ undergoes several transitions below the charge-ordering temperature $T_{co}$ = 54 K. From Nernst experiments, we find that, below $T_{co}$, there exists a large, anomalous Nernst signal $e_{N,even}(H,T)$ that is symmetric in field $H$, and remains finite as $H\to 0$. The time-reversal violating signal suggests that, below $T_{co}$, vortices of one sign are spontaneously created to relieve interlayer phase frustration.Comment: 5 pages, 4 figure

Tailoring pH-responsive acrylic acid microgels with hydrophobic crosslinks for drug release

Amphiphilic microgels based on the hydrophilic acrylic acid (AA) and hydrophobic crosslinks of different compositions were synthesised using a lab-on-a-chip device. The microgels were formed by polymerising hydrophobic droplets. The droplets were generated via a microfluidic platform and contained a protected form of AA, a hydrophobic crosslinker (ethylene glycol dimethacrylate, EGDMA) and a free radical initiator in an organic solvent. Following photopolymerisation and subsequent hydrolysis, AA based microgels of amphiphilic nature were produced and it was demonstrated that they can successfully deliver both hydrophilic as well as hydrophobic moieties. The model drug delivery and the swelling ability of the microgels were influenced by the pH of the aqueous solution as well as the crosslinking density and hydrophobic content of the microgels

Microfluidically fabricated pH-responsive anionic amphiphilic microgels for drug release

© 2016 The Royal Society of Chemistry. Amphiphilic microgels of different composition based on the hydrophilic, pH-responsive acrylic acid (AA) and the hydrophobic, non-ionic n-butyl acrylate (BuA) were synthesised using a lab-on-a-chip device. Hydrophobic droplets were generated via a microfluidic platform that contained a protected form of AA, BuA, the hydrophobic crosslinker, ethylene glycol dimethacrylate (EGDMA), and a free radical initiator in an organic solvent. These hydrophobic droplets were photopolymerised within the microfluidic channels and subsequently hydrolysed, enabling an integrated platform for the rapid, automated, and in situ production of anionic amphiphilic microgels. The amphiphilic microgels did not feature the conventional core-shell structure but were instead based on random amphiphilic copolymers of AA and BuA and hydrophobic crosslinks. Due to their amphiphilic nature they were able to encapsulate and deliver both hydrophobic and hydrophilic moieties. The model drug delivery and the swelling ability of the microgels were influenced by the pH of the surrounding aqueous solution and the hydrophobic content of the microgels

Symmetry breaking and manipulation of nonlinear optical modes in an asymmetric double-channel waveguide

We study light-beam propagation in a nonlinear coupler with an asymmetric double-channel waveguide and derive various analytical forms of optical modes. The results show that the symmetry-preserving modes in a symmetric double-channel waveguide are deformed due to the asymmetry of the two-channel waveguide, yet such a coupler supports the symmetry-breaking modes. The dispersion relations reveal that the system with self-focusing nonlinear response supports the degenerate modes, while for self-defocusingmedium the degenerate modes do not exist. Furthermore, nonlinear manipulation is investigated by launching optical modes supported in double-channel waveguide into a nonlinear uniform medium.Comment: 10 page

Antifreeze in the hot core of Orion - First detection of ethylene glycol in Orion-KL

Comparison of their chemical compositions shows, to first order, a good agreement between the cometary and interstellar abundances. However, a complex O-bearing organic molecule, ethylene glycol (CH$_{2}$OH)$_{2}$, seems to depart from this correlation because it was not easily detected in the interstellar medium although it proved to be rather abundant with respect to other O-bearing species in comet Hale-Bopp. Ethylene glycol thus appears, together with the related molecules glycolaldehyde CH$_{2}$OHCHO and ethanol CH$_{3}$CH$_{2}$OH, as a key species in the comparison of interstellar and cometary ices as well as in any discussion on the formation of cometary matter. We focus here on the analysis of ethylene glycol in the nearest and best studied hot core-like region, Orion-KL. We use ALMA interferometric data because high spatial resolution observations allow us to reduce the line confusion problem with respect to single-dish observations since different molecules are expected to exhibit different spatial distributions. Furthermore, a large spectral bandwidth is needed because many individual transitions are required to securely detect large organic molecules. Confusion and continuum subtraction are major issues and have been handled with care. We have detected the aGg' conformer of ethylene glycol in Orion-KL. The emission is compact and peaks towards the Hot Core close to the main continuum peak, about 2" to the south-west; this distribution is notably different from other O-bearing species. Assuming optically thin lines and local thermodynamic equilibrium, we derive a rotational temperature of 145 K and a column density of 4.6 10$^{15}$ cm$^{-2}$. The limit on the column density of the gGg' conformer is five times lower.Comment: 19 pages, 10 figures, A&A accepte

On the origin of kinematic distribution of the sub-parsec young stars in the Galactic center

Within a half-parsec from the Galactic center (GC), there is a population of coeval young stars which appear to reside in a coherent disk. Surrounding this dynamically-cool stellar system, there is a population of stars with a similar age and much larger eccentricities and inclinations relative to the disk. We propose a hypothesis for the origin of this dynamical dichotomy. Without specifying any specific mechanism, we consider the possibility that both stellar populations were formed within a disk some 6 Myr ago. But this orderly structure was dynamically perturbed outside-in by an intruding object with a mass ~10^4 Msun, which may be an intermediate-mass black hole (IMBH) or a dark stellar cluster hosting an IMBH. We suggest that the perturber migrated inward to ~0.15-0.3pc from the GC under the action of dynamical friction. Along the way, it captured many stars in the outer disk region into its mean-motion resonance, forced them to migrate with it, closely encountered with them, and induced the growth of their eccentricity and inclination. But stars in the inner regions of the disk retain their initial coplanar structure. We predict that some of the inclined and eccentric stars surrounding the disk may have similar Galactocentric semimajor axis. Future precision determination of their kinematic distribution of these stars will not only provide a test for this hypothesis but also evidences for the presence of an IMBH or a dark cluster at the immediate proximity of the massive black hole at the GC. (abridged)Comment: 14 pages, including 13 figures, typo corrected, reference added, ApJ in pres

Calculating potentials of mean force and diffusion coefficients from nonequilibirum processes without Jarzynski's equality

In general, the direct application of the Jarzynski equality (JE) to reconstruct potentials of mean force (PMFs) from a small number of nonequilibrium unidirectional steered molecular dynamics (SMD) paths is hindered by the lack of sampling of extremely rare paths with negative dissipative work. Such trajectories, that transiently violate the second law, are crucial for the validity of JE. As a solution to this daunting problem, we propose a simple and efficient method, referred to as the FR method, for calculating simultaneously both the PMF U(z) and the corresponding diffusion coefficient D(z) along a reaction coordinate z for a classical many particle system by employing a small number of fast SMD pullings in both forward (F) and time reverse (R) directions, without invoking JE. By employing Crook's transient fluctuation theorem (that is more general than JE) and the stiff spring approximation, we show that: (i) the mean dissipative work W_d in the F and R pullings are equal, (ii) both U(z) and W_d can be expressed in terms of the easily calculable mean work of the F and R processes, and (iii) D(z) can be expressed in terms of the slope of W_d. To test its viability, the FR method is applied to determine U(z) and D(z) of single-file water molecules in single-walled carbon nanotubes (SWNTs). The obtained U(z) is found to be in very good agreement with the results from other PMF calculation methods, e.g., umbrella sampling. Finally, U(z) and D(z) are used as input in a stochastic model, based on the Fokker-Planck equation, for describing water transport through SWNTs on a mesoscopic time scale that in general is inaccessible to MD simulations.Comment: ReVTeX4, 13 pages, 6 EPS figures, Submitted to Journal of Chemical Physic