Évolution temporelle de l’envasement des retenues de barrages de Tunisie

La mobilisation et l’exploitation des eaux de surface sont des pratiques anciennes en Tunisie. Les aménagements réalisés au cours du siècle dernier sont exposés à un alluvionnement plus ou moins accéléré. La capacité de stockage des retenues des barrages est sujette à une réduction progressive au cours du temps. Cette perte de capacité, parfois élevée, dépasse les prévisions de l’alluvionnement de la retenue. La quantification des sédiments piégés se base soit sur les bilans de matière solide à l’échelle d’une retenue, soit sur des levés bathymétriques ou topographiques. Les Modèles Numériques de Terrain (MNT) des retenues sont de plus en plus utilisés. Les différentes évaluations sont entachées d’une incertitude. Les retenues des barrages tunisiens perdent annuellement 0,5 % à 1 % de leur capacité par alluvionnement. L’analyse des résultats de mesures montre que l’alluvionnement est lié à l’hydrologie du cours d’eau, à la gestion de la réserve d’eau et aux manoeuvres de dévasement. La comparaison entre les résultats de mesures de l’alluvionnement et les prévisions des projets met en évidence des différences parfois relativement importantes qui sont dues au régime hydrologique des cours d’eau. En effet, une crue exceptionnelle peut provoquer un alluvionnement nettement supérieur à la moyenne annuelle en régime hydrologique normal. Les retenues méandriformes sont comblées rapidement alors que les retenues linéaires offrent la possibilité de soutirage de quantités importantes de sédiments. Les moyennes annuelles des pertes de capacité des barrages en exploitation et des barrages projetés jusqu’à 2010 permettent de quantifier les volumes des sédiments piégés à 500 Mm3. En 2030, la perte de capacité de stockage des barrages en exploitation pourrait atteindre 43 % de leur capacité initiale. Les aménagements amont et les travaux de conservation des eaux et des sols permettent de réduire le taux d’alluvionnement et de prolonger la durée de vie des grands réservoirs.The mobilization and exploitation of surface water are ancient practices in Tunisia. Installations carried out during last century are exposed to a greater or lesser degree of accelerated silting. The storage capacity of reservoirs is progressively reduced over the course of time. This sometimes accelerated loss of capacity of reserves by silting exceeds the forecasts of hydraulic installation projects. The quantification of trapped sediments is based on the assessment of a reservoir’s retained solid matter, either by bathymetric or topographic rising or by Digital Models of Grounds (DMG) corresponding to different dates. These various evaluations of the sediments trapped in reservoirs are, however, sullied with uncertainty. Tunisian reservoirs lose 0.5% to 1% of their storage capacity to silting annually. The analysis of the results presented in this study shows that silting is related to three factors: river hydrology, water reserve management and dredging operations. The comparison between the silting results and the project forecasts highlights relatively significant differences which may be due to river hydrology. Indeed a significant rising in water level can cause an increase in silting above the annual average found during normal hydrological modes. While meandering reservoirs are quickly filled with sediment, linear reservoirs can undergo dredging to remove a significant quantity of sediment. The annual averages in storage capacity losses of the dam under exploitation and its projections up to the year 2010 enable us to quantify the volumes of the sediment trapped as 500 Mm3. In 2030, the loss of storage capacity of the studied reservoirs may reach 43% of their initial storage capacities. Installations upstream and soil and water conservation efforts may reduce the rate of silting and prolong the lifespan of large dams

Comparison of the Fermi-surface topologies of kappa-(BEDT-TTF)_2 Cu(NCS)_2 and its deuterated analogue

We have measured details of the quasi one-dimensional Fermi-surface sections in the organic superconductor kappa-(BEDT-TTF)_2 Cu(NCS)_2 and its deuterated analogue using angle-dependent millimetre-wave techniques. There are significant differences in the corrugations of the Fermi surfaces in the deuterated and undeuterated salts. We suggest that this is important in understanding the inverse isotope effect, where the superconducting transition temperature rises on deuteration. The data support models for superconductivity which invoke electron-electron interactions depending on the topological properties of the Fermi surface

Real space imaging of the metal - insulator phase separation in the band width controlled organic Mott system κ\kappa-(BEDT-TTF)2_{2}Cu[N(CN)2_{2}]Br

Systematic investigation of the electronic phase separation on macroscopic scale is reported in the organic Mott system $\kappa$-(BEDT-TTF)$_{2}$Cu[N(CN)$_{2}$]Br. Real space imaging of the phase separation is obtained by means of scanning micro-region infrared spectroscopy using the synchrotron radiation. The phase separation appears near the Mott boundary and changes its metal-insulator fraction with the substitution ratio $x$ in $\kappa$-[($h$-BEDT-TTF)$_{1-x}$($d$-BEDT-TTF)$_{x}$]$_{2}$Cu[N(CN)$_{2}$]Br, of which band width is controlled by the substitution ratio $x$ between the hydrogenated BEDT-TTF molecule ($h$-BEDT-TTF) and the deuterated one ($d$-BEDT-TTF). The phase separation phenomenon observed in this class of organics is considered on the basis of the strongly correlated electronic phase diagram with the first order Mott transition.Comment: 10 pages, 8 figure

Influence of internal disorder on the superconducting state in the organic layered superconductor kappa-(BEDT-TTF)2Cu[N(CN)2]Br

We report high-sensitivity AC susceptibility measurements of the penetration depth in the Meissner state of the layered organic superconductor kappa-(BEDT-TTF)2Cu[N(CN)2]Br. We have studied nominally pure single crystals from the two different syntheses and employed controlled cooling procedures in order to minimize intrinsic remnant disorder at low temperatures associated with the glass transition, caused by ordering of the ethylene moieties in BEDT-TTF molecule at T_G = 75 K. We find that the optimal cooling procedures (slow cooling of -0.2 K/h or annealing for 3 days in the region of T_G) needed to establish the ground state, depend critically on the sample origin indicating different relaxation times of terminal ethylene groups. We show that, in the ground state, the behavior observed for nominally pure single crystals from both syntheses is consistent with unconventional d-wave order parameter. The in-plane penetration depth lambda_in(T) is strongly linear, whereas the out-of-plane component lambda_out(T) varies as T^2. In contrast, the behavior of single crystals with long relaxation times observed after slow (-0.2 K/h) cooling is as expected for a d-wave superconductor with impurities (i.e. lambda_in(T) propto lambda_out(T) propto T^2) or might be also reasonably well described by the s-wave model. Our results might reconcile the contradictory findings previously reported by different authors.Comment: 13 pages, 10 figures, submitted to Phys. Rev.

The Dependence of the Superconducting Transition Temperature of Organic Molecular Crystals on Intrinsically Non-Magnetic Disorder: a Signature of either Unconventional Superconductivity or Novel Local Magnetic Moment Formation

We give a theoretical analysis of published experimental studies of the effects of impurities and disorder on the superconducting transition temperature, T_c, of the organic molecular crystals kappa-ET_2X and beta-ET_2X (where ET is bis(ethylenedithio)tetrathiafulvalene and X is an anion eg I_3). The Abrikosov-Gorkov (AG) formula describes the suppression of T_c both by magnetic impurities in singlet superconductors, including s-wave superconductors and by non-magnetic impurities in a non-s-wave superconductor. We show that various sources of disorder lead to the suppression of T_c as described by the AG formula. This is confirmed by the excellent fit to the data, the fact that these materials are in the clean limit and the excellent agreement between the value of the interlayer hopping integral, t_perp, calculated from this fit and the value of t_perp found from angular-dependant magnetoresistance and quantum oscillation experiments. If the disorder is, as seems most likely, non-magnetic then the pairing state cannot be s-wave. We show that the cooling rate dependence of the magnetisation is inconsistent with paramagnetic impurities. Triplet pairing is ruled out by several experiments. If the disorder is non-magnetic then this implies that l>=2, in which case Occam's razor suggests that d-wave pairing is realised. Given the proximity of these materials to an antiferromagnetic Mott transition, it is possible that the disorder leads to the formation of local magnetic moments via some novel mechanism. Thus we conclude that either kappa-ET_2X and beta-ET_2X are d-wave superconductors or else they display a novel mechanism for the formation of localised moments. We suggest systematic experiments to differentiate between these scenarios.Comment: 18 pages, 5 figure

Pairing Symmetry Competition in Organic Superconductors

A review is given on theoretical studies concerning the pairing symmetry in organic superconductors. In particular, we focus on (TMTSF)$_2$X and $\kappa$-(BEDT-TTF)$_2$X, in which the pairing symmetry has been extensively studied both experimentally and theoretically. Possibilities of various pairing symmetry candidates and their possible microscopic origin are discussed. Also some tests for determining the actual pairing symmtery are surveyed.Comment: 16 pages, 8 figures, to be published in J. Phys. Soc. Jpn., special issue on "Organic Conductors

Tetrabenzoporphyrin and -mono-, - Cis -di- and tetrabenzotriazaporphyrin derivatives: Electrochemical and spectroscopic implications of meso CH Group replacement with nitrogen

Nonperipherally hexyl-substituted metal-free tetrabenzoporphyrin (2H-TBP, 1a) tetrabenzomonoazaporphyrin (2H-TBMAP, 2a), tetrabenzo-cis-diazaporphyrin (2H-TBDAP, 3a), tetrabenzotriazaporphyrin (2H-TBTAP, 4a), and phthalocyanine (2H-Pc, 5a), as well as their copper complexes (1b-5b), were synthesized. As the number of meso nitrogen atoms increases from zero to four, Îmax of the Q-band absorption peak becomes red-shifted by almost 100 nm, and extinction coefficients increased at least threefold. Simultaneously the blue-shifted Soret (UV) band substantially decreased in intensity. These changes were related to the relative electron-density of each macrocycle expressed as the group electronegativity sum of all meso N and CH atom groups, âχR. X-ray photoelectron spectroscopy differentiated between the three different types of macrocyclic nitrogen atoms (the Ninner, (NH)inner, and Nmeso) in the metal-free complexes. Binding energies of the Nmeso and Ninner,Cu atoms in copper chelates could not be resolved. Copper insertion lowered especially the cathodic redox potentials, while all four observed redox processes occurred at larger potentials as the number of meso nitrogens increased. Computational chemical methods using density functional theory confirmed 1b to exhibit a Cu(II) reduction prior to ring-based reductions, while for 2b, Cu(II) reduction is the first reductive step only if the nonperipheral substituents are hydrogen. When they are methyl groups, it is the second reduction process; when they are ethyl, propyl, or hexyl, it becomes the third reductive process. Spectro-electrochemical measurements showed redox processes were associated with a substantial change in intensity of at least two main absorbances (the Q and Soret bands) in the UV spectra of these compounds