Exploiting Nanoparticles to Improve the Properties of Bitumens and Asphalts: At What Extent Is It Really Worth It?

Asphalt concretes are materials used worldwide. It is well-known that in such materials the minor component, the bitumen, plays the most important role since it binds the high fraction (>95%) of inorganic macrometer-sized particles ensuring a coherent material fit for uses in road pavement. Additives can be used to increase the overall rheological properties, with high benefits in terms of resistance to mechanical stress and to ageing. Among these, nanoparticles have recently been considered as very effective additives in increasing the overall performance, increasing the viscosity, the rutting parameter and the recovery from deformation. However, they are expensive, so a delicate equilibrium between costs and benefits must be found for large-scale uses. In this framework, we furnish our critical analysis of the state-of-the art technologies used for improving the bitumen performances by means of nanoparticles with an eye to eventual added-values (like anti-oxidant effect, antistripping properties, or UV radiation screening which avoids radiation-induced ageing…). We will critically consider the costs involved in their use and we will give our opinion about vanguard techniques which can be fit for the analysis of nanoparticles-containing bitumens and asphalts. Interesting perspectives will be also given for future research and applications

Polysaccharides-Reinforced Bitumens: Specificities and Universality of Rheological Behavior

The rheological properties of bitumens can be modified by the addition of specific chemical additives. Taking into account the molecular complex aggregation pattern, we hypothesized that macromolecules characterized by long, flexible, and hydrophilic chains can establish soft bridges connecting the different polar aggregates of asphaltenes, strengthening their overall hierarchical supra-structures, and consequently increasing rheological performance at higher temperatures. Here, we propose the use of low cost and high availability polysaccharides as chemical additives to improve the rheological characteristics of a bitumen and to strengthen its thermal resistance. Fourteen different low-cost and high-availability polysaccharides, (flours, gums, and extracts from vegetable products) have been tested. While alghae euchemae have proved to be the most effective additive, corn and 00 flours are the least effective. Attempts to explain their differences have been made considering their chemical interactions with the polar molecules of asphaltenes within the complex framework of their supramolecular hierarchical structures. Through Arrhenius analysis, a correlation between activation energy and preexponential factor has been found, which can be useful for practical purposes, together with an unexpected consistency with the behavior of simple liquids, despite the striking differences in structure. Furthermore, a qualitative model has been suggested. The added value of this work is the focus on polysaccharides constituting low-cost, high availability materials which are sometimes even found as waste in industrial processes, all factors which, together with the environmental issues connected with their use, can be considered for large-scale applications

Reinforcement of Polylactic Acid / Poly Butylene Adipate-co-Terephthalate blends by starch addition: a coupled computational and experimental study

Poly Lactic Acid / Poly Butylene Adipate-co-Terephthalate blends are used as packaging green materials since they constitute hydrophilic and biodegradable plastic. With the aim of improving the mechanical characteristics of such blends as biodegradable packaging materials for food products the addition of starch has been considered. In silico test performed by classical molecular dynamics highlighted that the addition of starch can reinforce the polymeric structure via starch-polymer interactions, suggesting that starch can be a suitable material to be added to the Poly Lactic Acid / Poly Butylene Adipate-co-Terephthalate blend to obtain more resistant packaging materials. Experimental analysis of the mechanical properties of the polymeric blend containing different amounts of starch confirmed what foreseen by MD, highlighting an increase of Young modulus and glass transition as a function of added starch. The coupled theoretical/experimental approach constitutes added value of the present work, furnishing important data on the reinforcement of the packaging material performances and a molecule-based interpretation and comprehension of the observed phenomenon

Exploiting Nanoparticles to Improve the Properties of Bitumens and Asphalts: At What Extent Is It Really Worth It?

Asphalt concretes are materials used worldwide. It is well-known that in such materials the minor component, the bitumen, plays the most important role since it binds the high fraction (>95%) of inorganic macrometer-sized particles ensuring a coherent material fit for uses in road pavement. Additives can be used to increase the overall rheological properties, with high benefits in terms of resistance to mechanical stress and to ageing. Among these, nanoparticles have recently been considered as very effective additives in increasing the overall performance, increasing the viscosity, the rutting parameter and the recovery from deformation. However, they are expensive, so a delicate equilibrium between costs and benefits must be found for large-scale uses. In this framework, we furnish our critical analysis of the state-of-the art technologies used for improving the bitumen performances by means of nanoparticles with an eye to eventual added-values (like anti-oxidant effect, antistripping properties, or UV radiation screening which avoids radiation-induced ageing…). We will critically consider the costs involved in their use and we will give our opinion about vanguard techniques which can be fit for the analysis of nanoparticles-containing bitumens and asphalts. Interesting perspectives will be also given for future research and applications

A Review on Bitumen Rejuvenation: Mechanisms, Materials, Methods and Perspectives

This review aims to explore the state of the knowledge and the state-of-the-art regarding bitumen rejuvenation. In particular, attention was paid to clear things up about the rejuvenator mechanism of action. Frequently, the terms rejuvenator and flux oil, or oil (i.e., softening agent) are used as if they were synonymous. According to our knowledge, these two terms refer to substances producing different modifications to the aged bitumen: they can decrease the viscosity (softening agents), or, in addition to this, restore the original microstructure (real rejuvenators). In order to deal with the argument in its entirety, the bitumen is investigated in terms of chemical structure and microstructural features. Proper investigating tools are, therefore, needed to distinguish the different mechanisms of action of the various types of bitumen, so attention is focused on recent research and the use of different investigation techniques to distinguish between various additives. Methods based on organic synthesis can also be used to prepare ad-hoc rejuvenating molecules with higher performances. The interplay of chemical interaction, structural changes and overall effect of the additive is then presented in terms of the modern concepts of complex systems, which furnishes valid arguments to suggest X-ray scattering and Nuclear Magnetic Resonance relaxometry experiments as vanguard and forefront tools to study bitumen. Far from being a standard review, this work represents a critical analysis of the state-of-the-art taking into account for the molecular basis at the origin of the observed behavior. Furnishing a novel viewpoint for the study of bitumen based on the concepts of the complex systems in physics, it constitutes a novel approach for the study of these systems

Bitumen and Bitumen Modification: A Review on Latest Advances

This synthesis explores the state-of-the-knowledge and state-of-the-practice regarding the latest updates on polymer-modified bitumens (PmBs). The information in this study was gathered from a thorough review of the latest papers in the literatures related to modified bituminous materials, technologies, and advances. For this purpose, the paper is presented in two principle sections. In the first part, the bitumen itself is investigated in terms of chemical structure and microstructural systems. In the second part, the paper focuses on bitumen modification from different aspects for assessing the effectiveness of the introduced additives and polymers for enhancing the engineering properties of bitumen in both paving and industrial applications. In conclusion, the knowledge obtained in this study has revealed the importance of the chemical composition of base bitumen for its modification. It can be declared that while some polymers/additives can improve one or some aspects of neat bitumen properties, they can lead to compatibility problems in storage and production. In this respect, several studies showed the effectiveness of waxes for improving the compatibility of polymers with bitumen in addition to some benefits regarding warm mix asphalt (WMA) production

NMR Diffusiometry Spectroscopy, a Novel Technique for Monitoring the Micro-Modifications in Bitumen Ageing

In the past three decades, several conventional methods have been employed for characterizing the bitumen ageing phenomenon, such as rheological testing, ultraviolet testing, gel permeation chromatography (GPC), gas chromatography (GC), atomic force microscopy (AFM), X-ray scattering, and Fourier transform infrared spectroscopy (FTIR). Nevertheless, these techniques can provide only limited observations of the structural micro-modifications occurring during bitumen ageing. In this study, Fourier transform nuclear magnetic resonance self-diffusion coefficient (FT-NMR-SDC) spectroscopy, as a novel method, was employed to investigate and compare the microstructural changes between virgin bitumen (pristine bitumen) and aged bitumen. The virgin bitumen was aged artificially using two standard ageing tests: Rolling Thin-Film Oven Test (RTFOT) and Pressure Ageing Vessel (PAV). For a comprehensive comparison and an assessment of the validity of this method, the generated samples were studied using various methods: rheological test, atomic force microscopy, and optical microscopy. Significant differences were obtained between the structure and ageing patterns of virgin and aged bitumen. The results indicate that the modification of maltenes to asphaltenes is responsible for the ageing character. When compared with the other methods’ findings, FT-NMR-SDC observations confirm that the asphaltene content increases during ageing processes

The Role of Additives in Warm Mix Asphalt Technology: An Insight into Their Mechanisms of Improving an Emerging Technology

The asphalt industry’s incentive to reduce greenhouse gas emissions has increased since the 1990s due to growing concerns on environmental issues such as global warming and carbon footprint. This has stimulated the introduction of Warm Mix Asphalt (WMA) and its technologies which serve the purpose of reducing greenhouse gas emissions by reducing the mixing and compaction temperatures of asphalt mix. WMA gained popularity due to the environmental benefit it offers without compromising the properties, performance and quality of the asphalt mix. WMA is produced at significantly lower temperatures (slightly above 100 °C) and thus results in less energy consumption, fewer emissions, reduced ageing, lower mixing and compaction temperatures, cool weather paving and better workability of the mix. The latter of these benefits is attributed to the incorporation of additives into WMA. These additives can also confer even better performance of WMA in comparison to conventional Hot Mix Asphalt (HMA) methods. Even though there are recommended dosages of several WMA additives, there is no general standardized mixture design procedure and this makes it challenging to characterize the mechanism(s) of action of these additives in the warm mix. The effects of the addition of additives into WMA are known to a reasonable extent but not so much is known about the underlying interactions and phenomena which bring about the mechanism(s) by which these additives confer beneficial features into the warm mix. Additives in a certain way are being used to bridge the gap and minimize or even nullify the effect of the mixing temperature deficit involved in WMA processes while improving the general properties of the mix. This review presents WMA technologies such as wax, chemical additives and foaming processes and the mechanisms by which they function to confer desired characteristics and improve the durability of the mix. Hybrid techniques are also briefly mentioned in this paper in addition to a detailed description of the specific modes of action of popular WMA technologies such as Sasobit, Evotherm and Advera. This paper highlights the environmental and technical advantages of WMA over the conventional HMA methods and also comprehensively analyzes the mechanism(s) of action of additives in conferring desirable characteristics on WMA, which ultimately improves its durability

Preliminary Study on New Alternative Binders through Re-Refined Engine Oil Bottoms (REOBs) and Industrial By-Product Additives

Recent studies have worked towards addressing environmental issues such as global warming and greenhouse gas emissions due to the increasing awareness of the depletion of natural resources. The asphalt industry is seeking to implement measures to reduce its carbon footprint and to promote sustainable operations. The reuse of several wastes and by-products is an example of a more eco-friendly activity that fulfils the circular economy principle. Among all possible solutions, the road pavement sector encourages, on one hand, the use of recycled materials as a partial replacement of the virgin lithic skeleton; on the other hand, it promotes the use of recycled materials to substituting for a portion of the petroleum bituminous binder. This study aims to use Re-refined Engine Oil Bottoms (REOBs) as a main substitute and additives from various industrial by-products as a full replacement for virgin bitumen, producing high-performing alternative binders. The REOBs have been improved by utilizing additives in an attempt to improve their specific properties and thus to bridge the gap between REOBs and traditional bituminous binders. An even larger amount of virgin and non-renewable resources can be saved using these new potential alternative binders together with the RAP aggregates. Thus, the reduction in the use of virgin materials is applied at the binder and the asphalt mixture levels. Rheological, spectroscopic, thermogravimetric, and mechanical analysis were used to characterize the properties, composition, and characteristics of the REOBs, REOB-modified binders, and asphalt mixes. Thanks to the rheological investigations of possible alternative binders, 18 blends were selected, since they behaved like an SBS-modified bitumen, and then they were used for producing the corresponding asphalt mixtures. The preliminary mechanical analysis of the asphalt mixtures shows that six mixes have promising responses in terms of stiffness, tensile resistance, and water susceptibility. Nevertheless, the high variability of recycled materials and by-products has to be taken into consideration during the definition of alternative binders and recycled asphalt mixtures. In fact, this study highlights the crucial effects of the chemical composition of the constituents and their compatibility on the behaviour of the final product. This preliminary study represents a first attempt to define alternative binders, which can be used in combination with recycled aggregates for producing more sustainable road materials. However, further analysis is necessary in order to assess the durability and the ageing tendency of the materials