Fault slippage and its permeability evolution during supercritical CO2 fracturing in layered formation

International audienceUnderstanding the hydromechanical responses of faults during supercritical CO2 fracturing is important for reservoir management and the design of energy extraction systems. As small faults are widespread in Chang 7 member of the Yanchang Formation, Ordos Basin, China, supercritical CO2 fracturing operation has the potential to reactive these undetected small faults and leads to unfavorable fracking fluid migrate. In this work, we examined the role of fault slippage and permeability evolution along a small fault connecting the pay zone and the confining formation during the whole process of fracturing and production. A coupled hydromechanical model conceptualized from actual engineering results was introduced to address the main concerns of this work, including, (1) whether the existence of a undetected small fault would effectively constrain the hydraulic fracture height evolution, (2) what the magnitude of the induced microseismic events would be and (3) whether the permeability change along the fault plane would affect the vertical conductivity of the confining formation and thus increase the risk for the fracturing fluid to leak. Our results have shown that the initial hydrofracture formed at the perforation and propagated upward, once it merged with the fault surface, the existence of an undetected small fault would effectively constrain the hydraulic fracture height evolution. As fracturing continued, further slippage spread from the permeability increase zone of high permeability to shallower levels, and the extent of this zone was dependent on the magnitude of the fault slippage. At the end of extraction, the slip velocity decreases gradually to zero and the fault slippage finally reaches stabilization. In general, undetected small faults in targeted reservoir may not be the source of large earthquakes. The induced microseismic events could be considered as the sources of acoustic emission events detected while monitoring the fracturing fluid front. Due to the limited fault slippage and lower initial permeability, the CO2 fracturing operation near undetected small faults could not conduct preferential pathway for upward CO2 leakage or contaminate overlying shallower potable aquifers

Prediction of mechanical parameters for low-permeability gas reservoirs in the Tazhong Block and its applications

 A longitudinal distribution profile of the mechanical properties of the formations is important for the safe drilling, successful completion, and development of oil and gas reservoirs. However, the mechanical profile of the carbonate formations from the low-permeability gas reservoirs in the Tazhong (TZ) Block is hard to achieve due to the complex structural and lithological characteristics of the carbonates. In this paper, lab measurements are carried out to determine the physical and mechanical properties of the carbonate rocks of the Yingshan Formation in the TZ Block. Based on this, the relationships among density, the interval transit time and the mechanical parameters of the rocks in the TZ Block are constructed. The constructed relationships are then applied to the well-logging prediction of the mechanical profiles of the carbonate formations. The models are verified through the application to the two wells in the TZ Block, the results show that the relative errors in the predicted mechanical parameters are within 10% indicating the efficiency of the constructed models. The result of this study provides reasonable mechanical parameters for the exploration and development of the carbonate reservoirs in the TZ Block.Cited as: Wan, Y., Zhang, H., Liu, X., Yin, G., Xiong, J., Liang, L. Prediction of mechanical parameters for low-permeability gas reservoirs in the Tazhong Block and its applications. Advances in Geo-Energy Research, 2020, 4(2): 219-228, doi: 10.26804/ager.2020.02.1

Influence of Different Carboxylic Acid Ligands on Luminescent Properties of Eu(Lc) 3

A series of rare earth europium complexes with different carboxylic acid ligands Eu(Lc)3phen (Lc = MAA, AA, BA, SA) were synthesized. The complexes were characterized by FTIR, TG-DSC, XRD, UV absorption spectra, and photoluminescence spectra (PL) to study the structure, thermal stability, the energy absorption, and luminescent properties of the complexes. The results showed that the series complexes are all with good crystallization and relatively high thermal stability. The differences of the luminescent properties of complexes are caused by the different ligand structures. The absorption intensity of the carboxylic acid ligands, BA, was the strongest, followed by the MAA and AA and SA was the weakest. Therefore, the fluorescence intensity of the Eu(BA)3phen was the strongest, followed by the Eu(MAA)3phen and Eu(AA)3phen and the Eu2(SA)3phen2 was the weakest. All complexes showed good luminescence properties

Hybrid acoustic metamaterial as super absorber for broadband low-frequency sound

A hybrid acoustic metamaterial is proposed as a new class of sound absorber, which exhibits superior broadband low-frequency sound absorption as well as excellent mechanical stiffness/strength. Based on the honeycomb-corrugation hybrid core (H-C hybrid core), we introduce perforations on both top facesheet and corrugation, forming perforated honeycomb-corrugation hybrid (PHCH) to gain super broadband low-frequency sound absorption. Applying the theory of micro-perforated panel (MPP), we establish a theoretical method to calculate the sound absorption coefficient of this new kind of metamaterial. Perfect sound absorption is found at just a few hundreds hertz with two-octave 0.5 absorption bandwidth. To verify this model, a finite element model is developed to calculate the absorption coefficient and analyze the viscous-thermal energy dissipation. It is found that viscous energy dissipation at perforation regions dominates the total energy consumed. This new kind of acoustic metamaterials show promising engineering applications, which can serve as multiple functional materials with extraordinary low-frequency sound absorption, excellent stiffness/strength and impact energy absorption

Is routine drainage necessary after thyroid surgery? A randomized controlled trial study

ObjectiveTo evaluate whether no drainage has an advantage over routine drainage in patients with thyroid carcinoma after unilateral thyroid lobectomy and central neck dissection.MethodsA total of 104 patients with thyroid cancer who underwent unilateral thyroid lobectomy and central lymph node dissection were randomly assigned into no drainage tube (n=52) and routine drainage tube (n=52) placement groups. General information of each patient was recorded, including the postoperative drainage volume/residual cavity fluid volume, postoperative complications, incision area comfort, and other data, and the thyroid cancer-specific quality of life questionnaire (THYCA-QoL) and patient and observer scar assessment scale (POSAS) were evaluated after surgery. At the 3–6 month follow-up exam, the differences between the two groups were compared based on univariate analysis.ResultsSignificant differences were not observed in the general and pathological information (including sex, age, body weight, body mass index (BMI), incision length, specimen volume, Hashimoto’s thyroiditis, and number of lymph nodes dissected), operation time, and postoperative complications (postoperative bleeding, incision infection, lymphatic leakage, and temporary hypoparathyroidism) between the two groups. The patients in the non-drainage group had a shorter hospital stay (2.11 ± 0.33 d) than the patients in the drainage group (3.38 ± 0.90 d) (P<0.001). The amount of cervical effusion in patients in the non-drainage group (postoperative 24h: 2.20 ± 1.24 ml/48 h: 1.53 ± 1.07 ml) was significantly less than that in the drainage group (postoperative 24 hours: 22.58 ± 5.81 ml/48 h: 36.15 ± 7.61 ml) (all P<0.001). The proportion of incision exudation and incision numbness in the non-drainage group was lower than that in the drainage group (all P<0.05), and the pain score (VAS) and neck foreign body sensation score (FBST) decreased significantly (P<0.05). During the 3- and 6-month follow-up exams, significant differences were not observed between the THYCA-QoL and drainage groups and the non-drainage group, although the scarring and POSAS values were lower than those in the drainage group. In addition, the length of stay and cost of hospitalization in the non-drainage group were lower than those in the drainage group (P<0.05).ConclusionRoutine drainage tube insertion is not needed in patients with unilateral thyroid lobectomy and central neck dissection

Mutations in the cystic fibrosis transmembrane conductance regulator (CFTR) in Chinese patients with congenital bilateral absence of vas deferens

AbstractBackgroundGenetic testing of the cystic fibrosis transmembrane conductance (CFTR) gene is currently performed in patients with congenital bilateral absence of vas deferens (CBAVD). This study was conducted to investigate the role of mutations in the CFTR gene in CBAVD-dependent male infertility.Methods73 Chinese patients diagnosed with CBAVD were studied. The entire coding regions and splice sites of 27 exons of the CFTR gene were sequenced in 146 chromosomes from the 73 CBAVD patients. Screening was carried out using PCR, gel electrophoresis and DNA sequencing to identify novel variants of the entire coding regions and boundaries of the 27 exons.ResultsFive novel nonsynonymous mutations, three novel splice site mutations and one deletion were identified by sequencing. Apart from the novel variants, we also found 19 previously reported mutations and polymorphism sites. Thirty-four patients (46.57%) had the 5T variant (6 homozygous and 28 heterozygous) and in two of them it was not associated with any detectable mutation of the CFTR gene. All potential pathogenic mutations are not contained in the 1000 Genome Project database. In total, the present study identified 30 potential pathogenic variations in the CFTR gene, 9 of which had not previously been described.ConclusionsMost patients with CBAVD have mutations in the CFTR gene. A mild genotype with one or two mild or variable mutations was observed in all the patients. These findings improve our understanding of the distribution of CFTR alleles in CBAVD patients and will facilitate the development of more sensitive CFTR mutation screening

Studies on the interaction of achiral cationic pseudoisocyanine with chiral metal complexes

The effect of chiral metal complexes ([Co(en)(3)]I(3)center dot H(2)O, cis-[CoBr(NH(3))(en)(2)]Br(2), K[Co(edta)]center dot 2H(2)O and [Ru(phen)(3)](PF(6))(2)) on the polymer-bound J-aggregates in aqueous mixtures of pesudoisocyanine (PIC) iodine and poly(acrylic acid, sodium)(PAAS) have been studied by UV-vis absorption, circular dichroism (CD) and fluorescence spectra. At low concentration, the PIC monomers could self-assemble to form supermolecules by binding to each of the COO(-) groups on the polymer chains through electrostatic interactions. After the addition of chiral metal complexes to the formed PIC-PAAS J-aggregates, we found that only the chiral multiple pi-conjugated phenanthroline metal complexes could transfer their metal-centered chiral information to the formed J-aggregates. The chiral J-aggregates showed a characteristic induced circular dichroism (ICD) in the visible region of J-band chromophore, and the ICD signals depend on the absolute configuration, concentration of the chiral multiple pi-conjugated metal complexes, as well as temperature. More interestingly, the supramolecular chirality of the polymer supported PIC J-aggregates could be memorized even after the addition of an excess opposite chiral complex enantiomers. This is in sharp contrast to the behavior in the high concentrated NaCl induced PIC-J aggregates, in which the optical rotation of a mixture of two enantiomers varies linearly with their ratio.National Natural Science Foundation of China[20773098, 20877099, 20972183]; State Key Laboratory of Natural and Biomimetic Drugs[20080208]; GUCAS (A B); Ministry of Science and Technology of China[2008AA100801]; CAS[2010B090300031]; Guangdong Provinc

The genome and gene editing system of sea barleygrass provide a novel platform for cereal domestication and stress tolerance studies

The tribe Triticeae provides important staple cereal crops and contains elite wild species with wide genetic diversity and high tolerance to abiotic stresses. Sea barleygrass (Hordeum marinum Huds.), a wild Triticeae species, thrives in saline marshlands and is well known for its high tolerance to salinity and waterlogging. Here, a 3.82-Gb high-quality reference genome of sea barleygrass is assembled de novo, with 3.69 Gb (96.8%) of its sequences anchored onto seven chromosomes. In total, 41 045 high-confidence (HC) genes are annotated by homology, de novo prediction, and transcriptome analysis. Phylogenetics, non-synonymous/synonymous mutation ratios (Ka/Ks), and transcriptomic and functional analyses provide genetic evidence for the divergence in morphology and salt tolerance among sea barleygrass, barley, and wheat. The large variation in post-domestication genes (e.g. IPA1 and MOC1) may cause interspecies differences in plant morphology. The extremely high salt tolerance of sea barleygrass is mainly attributed to low Na+ uptake and root-to-shoot translocation, which are mainly controlled by SOS1, HKT, and NHX transporters. Agrobacterium-mediated transformation and CRISPR/Cas9-mediated gene editing systems were developed for sea barleygrass to promote its utilization for exploration and functional studies of hub genes and for the genetic improvement of cereal crops