Visible-light-driven Ag/Bi3O4Cl nanocomposite photocatalyst with enhanced photocatalytic activity for degradation of tetracycline

In this study, a novel Ag/Bi3O4Cl photocatalyst has been synthesized by a facile photodeposition process. Its photocatalytic performance was evaluated from the degradation of tetracycline (TC) under visible light irradiation (λ > 420 nm). The 1.0 wt% Ag/Bi3O4Cl photocatalyst could significantly enhance the degradation of TC compared with pure Bi3O4Cl, with the degradation level reaching 94.2% in 120 minutes. The enhancement of photocatalytic activity could be attributed to the synergetic effect of the photogenerated electrons (e−) of Bi3O4Cl and the surface plasmon resonance (SPR) caused by Ag nanoparticles, which could improve the absorption capacity of visible light and facilitate the separation of photogenerated electron–hole pairs. In addition, electron spin resonance (ESR) analysis and trapping experiments demonstrated that the superoxide radicals (˙O2−), hydroxyl radicals (˙OH) and holes (h+) played crucial roles in the photocatalytic process of TC degradation. The present work provides a promising approach for the development of highly efficient photocatalysts to address current environmental pollution, energy issues and other related areas

A Typha Angustifolia-like MoS2/carbon nanofiber composite for high performance Li-S batteries

A Typha Angustifolia-like MoS2/carbon nanofiber composite as both a chemically trapping agent and redox conversion catalyst for lithium polysulfides has been successfully synthesized via a simple hydrothermal method. Cycling performance and coulombic efficiency have been improved significantly by applying the Typha Angustifolia-like MoS2/carbon nanofiber as the interlayer of a pure sulfur cathode, resulting in a capacity degradation of only 0.09% per cycle and a coulombic efficiency which can reach as high as 99%

Interfacial Interaction Enhanced Rheological Behavior in PAM/CTAC/Salt Aqueous Solution—A Coarse-Grained Molecular Dynamics Study

Interfacial interactions within a multi-phase polymer solution play critical roles in processing control and mass transportation in chemical engineering. However, the understandings of these roles remain unexplored due to the complexity of the system. In this study, we used an efficient analytical method—a nonequilibrium molecular dynamics (NEMD) simulation—to unveil the molecular interactions and rheology of a multiphase solution containing cetyltrimethyl ammonium chloride (CTAC), polyacrylamide (PAM), and sodium salicylate (NaSal). The associated macroscopic rheological characteristics and shear viscosity of the polymer/surfactant solution were investigated, where the computational results agreed well with the experimental data. The relation between the characteristic time and shear rate was consistent with the power law. By simulating the shear viscosity of the polymer/surfactant solution, we found that the phase transition of micelles within the mixture led to a non-monotonic increase in the viscosity of the mixed solution with the increase in concentration of CTAC or PAM. We expect this optimized molecular dynamic approach to advance the current understanding on chemical–physical interactions within polymer/surfactant mixtures at the molecular level and enable emerging engineering solutions

Chemically Ordered Pt–Co–Cu/C as Excellent Electrochemical Catalyst for Oxygen Reduction Reaction

This paper reveals the ordered structure and composition effect to electrochemical catalytic activity towards oxygen reduction reaction (ORR) of ternary metallic Pt–Co–Cu/C catalysts. Bimetallic Pt-Co alloy nanoparticles (NPs) represent an emerging class of electrocatalysts for ORR, but practical applications, e.g. in fuel cells, have been hindered by low catalytic performances owning to crystal phase and atomic composition. Cu is introduced into Pt-Co/C lattices to form PtCoxCu1−x/C (x = 0.25, 0.5 and 0.75) ternary-face-centered tetragonal (fct) ordered ternary metallic NPs. The chemically ordered Pt–Co–Cu/C catalysts exhibit excellent performance of 1.31 A mg−1 Pt in mass activity and 0.59 A cm−2 Pt in specific activity which are significantly higher than Pt-Co/C and commercial Johnson Matthey (JM) Pt/C catalysts, because of the ordered crystal phase and composition control modified the Pt-Pt atoms distance and the surface electronic properties. The presence of Cu improves the surface electronic structure, as well as enhances the stability of catalysts

MPSN: Motion-aware Pseudo Siamese Network for Indoor Video Head Detection in Buildings

Head detection in the indoor video is an essential component of building occupancy detection. While deep models have achieved remarkable progress in general object detection, they are not satisfying enough in complex indoor scenes. The indoor surveillance video often includes cluttered background objects, among which heads have small scales and diverse poses. In this paper, we propose Motion-aware Pseudo Siamese Network (MPSN), an end-to-end approach that leverages head motion information to guide the deep model to extract effective head features in indoor scenarios. By taking the pixel-wise difference of adjacent frames as the auxiliary input, MPSN effectively enhances human head motion information and removes the irrelevant objects in the background. Compared with prior methods, it achieves superior performance on the two indoor video datasets. Our experiments show that MPSN successfully suppresses static background objects and highlights the moving instances, especially human heads in indoor videos. We also compare different methods to capture head motion, which demonstrates the simplicity and flexibility of MPSN. Finally, to validate the robustness of MPSN, we conduct adversarial experiments with a mathematical solution of small perturbations for robust model selection. Code is available at https://github.com/pl-share/MPSN

Petunia nectar proteins have ribonuclease activity

Plants requiring an insect pollinator often produce nectar as a reward for the pollinator's visitations. This rich secretion needs mechanisms to inhibit microbial growth. In Nicotiana spp. nectar, anti-microbial activity is due to the production of hydrogen peroxide. In a close relative, Petunia hybrida, limited production of hydrogen peroxide was found; yet petunia nectar still has anti-bacterial properties, suggesting that a different mechanism may exist for this inhibition. The nectar proteins of petunia plants were compared with those of ornamental tobacco and significant differences were found in protein profiles and function between these two closely related species. Among those proteins, RNase activities unique to petunia nectar were identified. The genes corresponding to four RNase T2 proteins from Petunia hybrida that show unique expression patterns in different plant tissues were cloned. Two of these enzymes, RNase Phy3 and RNase Phy4 are unique among the T2 family and contain characteristics similar to both S- and S-like RNases. Analysis of amino acid patterns suggest that these proteins are an intermediate between S- and S-like RNases, and support the hypothesis that S-RNases evolved from defence RNases expressed in floral parts. This is the first report of RNase activities in nectar

Evolution mechanism of principal modes in climate dynamics

Eigen analysis has been a powerful tool to distinguish multiple processes into different simple principal modes in complex systems. For a non-equilibrium system, the principal modes corresponding to the non-equilibrium processes are usually evolving with time. Here, we apply the eigen analysis into the complex climate systems. In particular, based on the daily surface air temperature in the tropics (30? S–30? N, 0? E–360? E) between 1979-01-01 and 2016-12-31, we uncover that the strength of two dominated intra-annual principal modes represented by the eigenvalues significantly changes with the El Niño/southern oscillation from year to year. Specifically, according to the ‘regional correlation’ introduced for the first intra-annual principal mode, we find that a sharp positive peak of the correlation between the El Niño region and the northern (southern) hemisphere usually signals the beginning (end) of the El Niño. We discuss the underlying physical mechanism and suppose that the evolution of the first intra-annual principal mode is related to the meridional circulations; the evolution of the second intra-annual principal mode responds positively to the Walker circulation. Our framework presented here not only facilitates the understanding of climate systems but also can potentially be used to study the dynamical evolution of other natural or engineering complex systems. © 2020 The Author(s)

A study on improving the current density performances of CO2 electrolysers

Electrochemical CO2 reduction reaction (CO2RR) technology can reduce CO2 emission with converting excess electrical energy to high-value-added chemicals, which however needs further improvement on the electrolyser cell performance. In this work, extensive factors were explored in continuous CO2 electrolysers. Gold, one of the benchmark materials for CO2RR to produce CO, was used as the catalyst. Electrolyser configurations and membrane types have significant influences on cell performance. Compact MEA-constructed gas-phase electrolyser showed better catalytic performance and lower energy consumption. The gas diffusion electrode with a 7:1 mass ratio of total-catalyst-to-polytetrafluoroethylene (PTFE) ionomer exhibited the best performance. At a low total cell voltage of 2.2 V, the partial current density of CO production achieved 196.8 mA cm-2, with 90.6% current efficiency and 60.4% energy efficiency for CO producing respectively. Higher CO selectivity can be achieved using anion exchange membranes, while higher selectivity for hydrogen and formate products can be achieved with cation exchange membranes. This research has pointed out a way on how to improve the CO2RR catalytic performance in flow cells, leaving aside the characteristics of the catalyst itself

Sucrose derived microporous–mesoporous carbon for advanced lithium–sulfur batteries

A microporous–mesoporous carbon has been successfully prepared via carbonization of sucrose followed by heat treatment process. The obtained porous carbon possesses abundant micropores and mesopores, which can effectively increase the sulfur loading. The composite exhibited a remarkable initial capacity of 1185 mAh g‒1 at 0.2 A g‒1 and maintained at 488 mAh g‒1 after 200 cycles, when employed for lithium‒sulfur batteries. Moreover, the composite displayed enhanced rate capabilities of 1124, 914 and 572 mAh g‒1 at 0.2, 0.5 and 1.0 A g‒1. The outstanding electrochemical capabilities and facile low‒cost preparation make the new microporous–mesoporous carbon as an excellent candidate for lithium sulfur batteries