Metal size distribution in rainfall and snowmelt-induced runoff from three urban catchments

The size distribution of metals transported by urban runoff has implications for treatment type and design, predicting their mobility and evaluating their potential impact on receiving waters. There is an urgent need to better understand the distribution of metals between fractions, particularly those in the sub-dissolved fractions. As a contribution to addressing this need, this study characterises the size distribution of Cd, Cr, Cu, Ni, V and Zn using conventional and novel techniques. Data is presented as event mean concentrations (EMC) of a total of 18 rainfall and snowmelt events at three urban sites. For all studied metals in all events and at all sites, the contribution of the truly dissolved fraction made a greater contribution to the total concentrations than the colloidal fraction. Truly dissolved Cd and Zn concentrations contributed (on average) 26% and 28% respectively, of the total EMCs with truly dissolved Cu and Ni contributing (on average) 18%. In contrast, only 1% (V) and 3% (Cr) were identified in the truly dissolved fraction. The greatest contribution of truly dissolved Cd, Cu and Zn concentrations (relative to total oncentrations) were reported during rainfall events. However, no seasonal differences were identified and differences between the sites regarding the EMCs distribution by fractions were not at a statistically significant level (p N 0.05) for any metal or event. The loads of truly dissolved and colloidal metals did not follow the patterns of particulate metal loads indicating particulates are not the main source of subdissolved metals. The data suggests that ultrafiltration as a treatment technique would not efficiently mitigate the risks posed by metals to receiving water cologie

Evaluation of measured dissolved and bio-met predicted bioavailable Cu, Ni and Zn concentrations in runoff from three urban catchments

Urban runoff is a diffuse source of pollution contributing to the poor ecological and chemical status of surface waters. Whilst the EU Priority Hazardous Substances Directive now identifies environmental quality standards for selected metals in relation to the bioavailable metal fraction the relationship between analytically determined metal size fractions transported by urban runoff and the often variably defined concept of bioavailability has not been thoroughly evaluated. This paper provides a review of the terminology used within urban runoff studies to characterise metal fractions and behaviour. Measured dissolved and truly dissolved (determined by ultrafiltration; <3000 molecular weight cutoff) Cu, Ni, and Zn concentrations are also compared to the bioavailable metal fraction (as predicted using Bio-met, a simplified biotic ligand model) in snowmelt and rainfall derived runoff samples from three urban catchments. The study shows that predicted bioavailable concentrations were significantly lower than truly dissolved concentrations for all metals and discusses current bioavailability modelling parameters in relation to rainfall and snowmelt runoff data sets. Statistical analysis of relationships between field and predicted bioavailable data sets indicate that the bioavailable fractions originate from both colloidal and truly dissolved fractions

Synchrotron flaring behaviour of CygnusX-3 during the February-March 1994 and September 2001 outbursts

Aims: In this paper we study whether the shock-in-jet model, widely used to explain the outbursting behaviour of quasars, can be used to explain the radio flaring behaviour of the microquasar Cygnus X-3. Method: We have used a method developed to model the synchrotron outbursts of quasar jets, which decomposes multifrequency lightcurves into a series of outbursts. The method is based on the Marscher & Gear (1985) shock model, but we have implemented the modifications to the model suggested by Bjornsson & Aslaksen (2000), which make the flux density increase in the initial phase less abrupt. We study the average outburst evolution as well as specific characteristics of individual outbursts and physical jet properties of Cyg X-3. Results: We find that the lightcurves of the February-March 1994 and September 2001 outbursts can be described with the modified shock model. The average evolution shows that instead of the expected synchrotron plateau, the flux density is still increasing during the synchrotron stage. We also find that high frequency peaking outbursts are shorter in duration than the ones peaking at lower frequencies. Finally, we show that the method can be used, complementary to radio interferometric jet imaging, for deriving the physical parameters such as the magnetic field strength and the energy density of relativistic electrons in the jet of Cyg X-3.Comment: 8 pages, 3 figures, accepted for publication in Astronomy and Astrophysic

A Kpc-scale Radio Polarization Study of PG BL Lacs with the uGMRT

We present here uGMRT band 4 (~650MHz) polarization images of 8 BL~Lac objects belonging to the Palomar-Green (PG) `blazar' sample. A large fraction of the sources (~63%) reveal core-halo radio structures with most of the polarization detected in the inner core-jet regions. PG1101+385 and PG2254+075 exhibit a `spine-sheath structure' in polarization. The core-halo and `spine-sheath' structures are consistent with the Unified Scheme suggestion that BL~Lacs are the pole-on beamed counterparts of Fanaroff-Riley (FR) type I radio galaxies. PG1418+546 and PG0851+203 (OJ287) show the presence of terminal hotspots similar to FR type II radio galaxies. They were also found to be low-spectrally peaked BL Lacs, supportive of the `blazar envelope' scenario for BL~Lacs and quasars. Fractional polarization ranges from 1-13% in the cores and 2-26% in the inner jets/lobes of the sample BL Lacs. Compared to the varied radio morphology of quasars from the PG `blazar' sample, the BL~Lacs appear to be less diverse. A comparison of the inferred core magnetic (B-) field structures on arcsec- (kpc-) scales w.r.t. the Very Long Baseline Interferometry (VLBI) jet direction does not reveal any preferred orientation, suggesting that if large-scale ordered B-fields exist, they do so on scales smaller than probed by the current observations. However, the presence of polarized emission on arcsec-scales suggests that any mixing of thermal plasma with the synchrotron emitting plasma is insufficient to fully depolarize the emission via the internal depolarization process.Comment: 17 pages; 12 figures; MNRAS accepte

Radiocarpal Injuries : Cone Beam Computed Tomography Arthrography, Magnetic Resonance Arthrography, and Arthroscopic Correlation among 21 Patients

Background and Aims: Patients with acute or chronic wrist pain often undergo wrist arthroscopy for evaluation of chondral and ligamentous abnormalities. The purpose of this study was to compare findings of wrist arthroscopy with cone beam computed tomography arthrography and magnetic resonance arthrography. Materials and Methods: Altogether, 21 patients with wrist pain underwent cone beam computed tomography arthrography, magnetic resonance arthrography, and wrist arthroscopy. Chondral surfaces of the scaphoid, lunate, and radius facing the scaphoid and lunate were evaluated. The scapholunate ligament, the lunotriquetral ligament, and the triangular fibrocartilage complex were classified as either intact or torn. Sensitivity, specificity, positive and negative predictive values, and accuracy with 95% confidence intervals were assessed. Results: For chondral lesions (n=10), cone beam computed tomography arthrograms showed slightly higher specificity than magnetic resonance arthrography. The sensitivity of cone beam computed tomography arthrography was also better for these lesions, except for those on the chondral surface of the lunate. For triangular fibrocartilage complex injuries (n=9), cone beam computed tomography arthrography showed a better specificity and sensitivity than magnetic resonance arthrography. For ligamentous injuries (n=6), cone beam computed tomography arthrograms were more sensitive, but less specific than magnetic resonance arthrography images. However, the number of lesions was very small and the 95% confidence intervals are overlapping. Conclusion: Cone beam computed tomography is an emerging imaging modality that offers several advantages over computed tomography and magnetic resonance imaging. Its usefulness particularly in ligamentous injuries should be further explored in a larger study. Cone beam computed tomography arthrography seems to offer similar sensitivity, specificity, and accuracy compared to magnetic resonance arthrography and therefore serves as a valuable option in evaluating patients with wrist pain.Peer reviewe

The Jet and the Supernova in GRB990712

The optical light curve of the afterglow following the gamma-ray burst GRB990712 is re-examined. Recently published polarization measurements of that source require a collimated outflow geometry that in turn predicts a break in the light curve. We show that the V-band light curve is consistent with such a break and that the post-break light curve evolution is dominated by a supernova contribution

Multiwavelength observation from radio through very-high-energy Gamma-ray of OJ 287 during the 12-year cycle flare in 2007

We performed simultaneous multiwavelength observations of OJ 287 with the Nobeyama Millimeter Array for radio, the KANATA telescope and the KVA telescope for optical, the Suzaku satellite for X-ray and the MAGIC telescope for very high energy (VHE) gamma-ray in 2007. The observations were conducted for a quiescent state in April and in a flaring state in November-December. We clearly observed increase of fluxes from radio to X-ray bands during the flaring state while MAGIC could not detect significant VHE gamma-ray emission from the source. We could derive an upper limit (95% confidence level) of 1.7% of the Crab Nebula flux above 150 GeV from about 41.2 hours of the MAGIC observation. A simple SSC model suggests that the observed flaring activity could be caused by evolutions in the distribution of the electron population rather than changes of the magnetic field strength or Doppler beaming factor in the jet.Comment: Contribution to the 31st ICRC, Lodz, Poland, July 200