The effect of nanoparticle softness on the interfacial dynamics of a model polymer nanocomposite

The introduction of soft organic nanoparticles (NPs) into polymer melts has recently expanded the material design space for polymer nanocomposites, compared to traditional nanocomposites that utilize rigid NPs, such as silica, metallic NPs, and other inorganic NPs. Despite advances in the fabrication and characterization of this new class of materials, the effect of NP stiffness on the polymer structure and dynamics has not been systematically investigated. Here, we use molecular dynamics to investigate the segmental dynamics of the polymer interfacial region of isolated NPs of variable stiffness in a polymer matrix. When the NP-polymer interactions are stronger than the polymer-polymer interactions, we find that the slowing of segmental dynamics in the interfacial region is more pronounced for stiff NPs. In contrast, when the NP-polymer interaction strength is smaller than the matrix interaction, the NP stiffness has relatively little impact on the changes in the polymer interfacial dynamics. We also find that the segmental relaxation time τα of segments in the NP interfacial region changes from values lower than to higher than the bulk material when the NP-polymer interaction strength is increased beyond a "critical"strength, reminiscent of a binding-unbinding transition. Both the NP stiffness and the polymer-surface interaction strength can thus greatly influence the relative segmental relaxation and interfacial mobility in comparison to the bulk material

An inventory of active rock glaciers in the northern Tien Shan of China compiled using satellite SAR interferometry

Rock glaciers are widespread in the Tien Shan. However, rock glaciers in the Chinese part of the Tien Shan have not been systematically investigated for more than two decades. In this study, we propose a new method that combines SAR interferometry and optical images from Google Earth to map active rock glaciers (ARGs) in the Northern Tien Shan (NTS) of China. We compiled an inventory that includes 261 ARGs and quantitative information about their locations, geomorphic parameters, and down-slope velocities. Our inventory shows that most of the ARGs are moraine-derived (69 %) and facing northeast (56 %). The altitude distribution of ARGs in the western NTS is significantly different from those located in the eastern part. The down-slope velocities of the ARGs vary significantly in space, with a maximum of about 114 cm/yr and a mean of about 37 cm/yr. Using the ARG locations as a proxy for the extent of alpine permafrost, our inventory suggests that the lowest altitudinal limit for the presence of permafrost in the NTS is about 2500-2800 m, a range determined by the lowest ARG in the entire inventory and by a statistics-based estimation. The successful application of the proposed method would facilitate effective and robust efforts to map rock glaciers over mountain ranges globally. And this study provides an important dataset to improve mapping and modeling permafrost occurrence in vast western China