3D non-LTE iron abundances in FG-type dwarfs

Spectroscopic measurements of iron abundances are prone to systematic modelling errors. We present 3D non-LTE calculations across 32 STAGGER-grid models with effective temperatures from 5000 K to 6500 K, surface gravities of 4.0 dex and 4.5 dex, and metallicities from $-$3 dex to 0 dex, and study the effects on 171 Fe I and 12 Fe II optical lines. In warm metal-poor stars, the 3D non-LTE abundances are up to 0.5 dex larger than 1D LTE abundances inferred from Fe I lines of intermediate excitation potential. In contrast, the 3D non-LTE abundances can be 0.2 dex smaller in cool metal-poor stars when using Fe I lines of low excitation potential. The corresponding abundance differences between 3D non-LTE and 1D non-LTE are generally less severe but can still reach $\pm$0.2 dex. For Fe II lines the 3D abundances range from up to 0.15 dex larger, to 0.10 dex smaller, than 1D abundances, with negligible departures from 3D LTE except for the warmest stars at the lowest metallicities. The results were used to correct 1D LTE abundances of the Sun and Procyon (HD 61421), and of the metal-poor stars HD 84937 and HD 140283, using an interpolation routine based on neural networks. The 3D non-LTE models achieve an improved ionisation balance in all four stars. In the two metal-poor stars, they remove excitation imbalances that amount to 250 K to 300 K errors in effective temperature. For Procyon, the 3D non-LTE models suggest [Fe/H] = 0.11 $\pm$ 0.03, which is significantly larger than literature values based on simpler models. We make the 3D non-LTE interpolation routine for FG-type dwarfs publicly available, in addition to 1D non-LTE departure coefficients for standard MARCS models of FGKM-type dwarfs and giants. These tools, together with an extended 3D LTE grid for Fe II from 2019, can help improve the accuracy of stellar parameter and iron abundance determinations for late-type stars.Comment: 17 pages, 11 figures, 5 tables; arXiv abstract abridged; accepted for publication in Astronomy & Astrophysic

Impact of Escherichia coli on Urine Citrate and Urease-Induced Crystallization

Escherichia coli (E. coli) is usually not a urease producer. It is, however, often cultured in urinary phosphate containing calculi including ammonium magnesium phosphate stones. This suggests the possibility that E. coli might be involved in stone forming process. The effect of E. coli on urine citrate and urease-induced crystallization in human urine has been studied in vitro. E. coli was found to strongly reduce urine citrate (after 48 hours). In the E. coli inoculated samples, the urease-induced crystallization was increased. There was a strong correlation, r = 0.8, between the citrate decrease and the increase in calcium precipitation. The results indicate that E. coli and the reduced urine citrate influences urease-induced crystallization in vitro

Thin liquid water clouds: their importance and our challenge

Many clouds important to the Earth’s energy balance contain small amounts of liquid water, yet despite many improvements, large differences in retrievals of their liquid water amount and particle size still must be resolved

Radiotherapy for early stage favourable breast cancers

British Journal of Cancer (2002) 86, 309–310. DOI: 10.1038/sj/bjc/6600004 www.bjcancer.co

Strategy Plan A Methodology to Predict the Uniformity of Double-Shell Tank Waste Slurries Based on Mixing Pump Operation

This document presents an analysis of the mechanisms influencing mixing within double-shell slurry tanks. A research program to characterize mixing of slurries within tanks has been proposed. The research program presents a combined experimental and computational approach to produce correlations describing the tank slurry concentration profile (and therefore uniformity) as a function of mixer pump operating conditions. The TEMPEST computer code was used to simulate both a full-scale (prototype) and scaled (model) double-shell waste tank to predict flow patterns resulting from a stationary jet centered in the tank. The simulation results were used to evaluate flow patterns in the tank and to determine whether flow patterns are similar between the full-scale prototype and an existing 1/12-scale model tank. The flow patterns were sufficiently similar to recommend conducting scoping experiments at 1/12-scale. Also, TEMPEST modeled velocity profiles of the near-floor jet were compared to experimental measurements of the near-floor jet with good agreement. Reported values of physical properties of double-shell tank slurries were analyzed to evaluate the range of properties appropriate for conducting scaled experiments. One-twelfth scale scoping experiments are recommended to confirm the prioritization of the dimensionless groups (gravitational settling, Froude, and Reynolds numbers) that affect slurry suspension in the tank. Two of the proposed 1/12-scale test conditions were modeled using the TEMPEST computer code to observe the anticipated flow fields. This information will be used to guide selection of sampling probe locations. Additional computer modeling is being conducted to model a particulate laden, rotating jet centered in the tank. The results of this modeling effort will be compared to the scaled experimental data to quantify the agreement between the code and the 1/12-scale experiment. The scoping experiment results will guide selection of parameters to be varied in the follow-on experiments. Data from the follow-on experiments will be used to develop correlations to describe slurry concentration profile as a function of mixing pump operating conditions. This data will also be used to further evaluate the computer model applications. If the agreement between the experimental data and the code predictions is good, the computer code will be recommended for use to predict slurry uniformity in the tanks under various operating conditions. If the agreement between the code predictions and experimental results is not good, the experimental data correlations will be used to predict slurry uniformity in the tanks within the range of correlation applicability

Control of Fruit Patterning in Arabidopsis by INDEHISCENT

AbstractThe Arabidopsis seedpod opens through a spring-loaded mechanism known as pod shatter, which is essential for dispersal of the seeds. Here, we identify INDEHISCENT (IND), an atypical bHLH protein, that is necessary for fruit opening and is involved in patterning each of the three fruit cell types required for seed dispersal. Previous studies suggested that FRUITFULL (FUL), a member of the MADS-domain transcription factor family, is required for fruit growth since ful mutant fruit fail to undergo the dramatic enlargement that normally occurs after fertilization. Here we show, however, that FUL is not directly required for fruit elongation and instead is required to prevent ectopic activity of IND. Our molecular and genetic studies suggest a model for the regulatory interactions among the genes that control fruit development and the mechanism that results in the expression of IND in a narrow stripe of cells

Final Report One-Twelfth-Scale Mixing Experiments to Characterize Double-Shell Tank Slurry Uniformity

The objectives of these 1/12-scale scoping experiments were to Determine which of the dimensionless parameters discussed in Bamberger and Liljegren (1994) affect the maximum concentration that can be suspended during jet mixer pump operation in the full-scale double-shell tanks Develop empirical correlations to predict the nozzle velocity required for jet mixer pumps to suspend the contents of full-scale double-shell tanks Apply the models to predict the nozzle velocity required to suspend the contents of Tank 241 AZ-101 Obtain experimental concentration data to compare with the TEMPEST( )(Trent and Eyler 1989) computational modeling predictions to guide further code development Analyze the effects of changing nozzle diameter on exit velocity (U0) and U0D0 (the product of the exit velocity and nozzle diameter) required to suspend the contents of a tank. The scoping study experimentally evaluated uniformity in a 1/12-scale experiment varying the Reynolds number, Froude number, and gravitational settling parameter space. The initial matrix specified only tests at 100% U0D0 and 25% U0D0. After initial tests were conducted with small diameter, low viscosity simulant this matrix was revised to allow evaluation of a broader range of U0D0s. The revised matrix included full factorial test between 100% and 50% U0D0 and two half-factorial tests at 75% and 25% U0D0. Adding points at 75% U0D0 and 50% U0D0 allowed evaluation curvature. Eliminating points at 25% U0D0 decreased the testing time by several weeks. Test conditions were achieved by varying the simulant viscosity, the mean particle size, and the jet nozzle exit velocity. Concentration measurements at sampling locations throughout the tank were used to assess the degree of uniformity achieved during each test. Concentration data was obtained using a real time ultrasonic attenuation probe and discrete batch samples. The undissolved solids concentration at these locations was analyzed to determine whether the tank contents were uniform ( ±10% variation about mean) in concentration. Concentration inhomogeneity was modeled as a function of dimensionless groups. The two parameters that best describe the maximum solids volume fraction that can be suspended in a double-shell tank were found to be 1) the Froude number (Fr) based on nozzle velocity (U0) and tank contents level (H) and 2) the dimensionless particle size (dp/D0). The dependence on the Reynolds number (Re) does not appear to be statistically significant

High-Capacity Conductive Nanocellulose Paper Sheets for Electrochemically Controlled Extraction of DNA Oligomers

Highly porous polypyrrole (PPy)-nanocellulose paper sheets have been evaluated as inexpensive and disposable electrochemically controlled three-dimensional solid phase extraction materials. The composites, which had a total anion exchange capacity of about 1.1 mol kg−1, were used for extraction and subsequent release of negatively charged fluorophore tagged DNA oligomers via galvanostatic oxidation and reduction of a 30–50 nm conformal PPy layer on the cellulose substrate. The ion exchange capacity, which was, at least, two orders of magnitude higher than those previously reached in electrochemically controlled extraction, originated from the high surface area (i.e. 80 m2 g−1) of the porous composites and the thin PPy layer which ensured excellent access to the ion exchange material. This enabled the extractions to be carried out faster and with better control of the PPy charge than with previously employed approaches. Experiments in equimolar mixtures of (dT)6, (dT)20, and (dT)40 DNA oligomers showed that all oligomers could be extracted, and that the smallest oligomer was preferentially released with an efficiency of up to 40% during the reduction of the PPy layer. These results indicate that the present material is very promising for the development of inexpensive and efficient electrochemically controlled ion-exchange membranes for batch-wise extraction of biomolecules