MESSENGER observations of the dayside low‐latitude boundary layer in Mercury’s magnetosphere

Observations from MErcury Surface Space ENvironment GEochemistry, and Ranging (MESSENGER)’s Magnetometer and Fast Imaging Plasma Spectrometer instruments during the first orbital year have resulted in the identification of 25 magnetopause crossings in Mercury’s magnetosphere with significant low‐latitude boundary layers (LLBLs). Of these crossings 72% are observed dawnside and 65% for northward interplanetary magnetic field. The estimated LLBL thickness is 450 ± 56 km and increases with distance to noon. The Na+ group ion is sporadically present in 14 of the boundary layers, with an observed average number density of 22 ± 11% of the proton density. Furthermore, the average Na+ group gyroradii in the layers is 220 ± 34 km, the same order of magnitude as the LLBL thickness. Magnetic shear, plasma β and reconnection rates have been estimated for the LLBL crossings and compared to those of a control group (non‐LLBL) of 61 distinct magnetopause crossings which show signs of nearly no plasma inside the magnetopause. The results indicate that reconnection is significantly slower, or even suppressed, for the LLBL crossings compared to the non‐LLBL cases. Possible processes that form or impact the LLBL are discussed. Protons injected through the cusp or flank may be important for the formation of the LLBL. Furthermore, the opposite asymmetry in the Kelvin‐Helmholtz instability (KHI) as compared to the LLBL rules out the KHI as a dominant formation mechanism. However, the KHI and LLBL could be related to each other, either by the impact of sodium ions gyrating across the magnetopause or by the LLBL preventing the growth of KH waves on the dawnside.Key PointsInvestigation, characterization, and observation of the low‐latitude boundary layer of MercuryIs there a relation between the Kelvin‐Helmholtz instability and the low‐latitude boundary layerInvestigate for what surrounding conditions the low‐latitude boundary layer occursPeer Reviewedhttps://deepblue.lib.umich.edu/bitstream/2027.42/136336/1/jgra52122_am.pdfhttps://deepblue.lib.umich.edu/bitstream/2027.42/136336/2/jgra52122.pd

Candida antarctica Lipase A-Based Enantiorecognition of a Highly Strained 4-Dibenzocyclooctynol (DIBO) Used for PET Imaging

The enantiomers of aromatic 4-dibenzocyclooctynol (DIBO), used for radiolabeling and subsequent conjugation of biomolecules to form radioligands for positron emission tomography (PET), were separated by kinetic resolution using lipase A from Candida antarctica (CAL-A). In optimized conditions, (R)-DIBO [(R)-1, ee 95%] and its acetylated (S)-ester [(S)-2, ee 96%] were isolated. In silico docking results explained the ability of CAL-A to differentiate the enantiomers of DIBO and to accommodate various acyl donors. Anhydrous MgCl2 was used for binding water from the reaction medium and, thus, for obtaining higher conversion by preventing hydrolysis of the product (S)-2 into the starting material. Since the presence of hydrated MgCl2·6H2O also allowed high conversion or effect on enantioselectivity, Mg2+ ion was suspected to interact with the enzyme. Binding site predictions indicated at least two sites of interest; one in the lid domain at the bottom of the acyl binding pocket and another at the interface of the hydrolase and flap domains, just above the active site.</p

The kinetics and mechanism of the organo-iridium catalysed racemisation of amines

The dimeric iodo-iridium complex [IrCp*I2 ]2 (Cp*=pentamethylcyclopentadiene) is an efficient catalyst for the racemisation of secondary and tertiary amines at ambient and higher temperatures with a low catalyst loading. The racemisation occurs with pseudo-first-order kinetics and the orresponding four rate constants were obtained by monitoring the time dependence of the concentrations of the (R) and (S) enantiomers starting with either pure (R) or (S) and show a first-order dependence on catalyst concentration. Low temperature 1H NMR data is consistent with the formation of a 1:1 complex with the amine coordinated to the iridium and with both iodide anions still bound to the metal-ion, but at the higher temperatures used for kinetic studies binding is weak and so no saturation zero-order kinetics are observed. A cross-over experiment with isotopically labelled amines demonstrates the intermediate formation of an imine which can dissociate from the iridium complex. Replacing the iodides in the catalyst by other ligands or having an amide substituent in Cp* results in a much less effective catalysts for the racemisation of amines. The rate constants for a deuterated amine yield a significant primary kinetic isotope effect kH/kD = 3.24 ndicating that hydride transfer is involved in the rate-limiting step

Skeletal Morphology of Opius dissitus and Biosteres carbonarius (Hymenoptera: Braconidae), with a Discussion of Terminology

The Braconidae, a family of parasitic wasps, constitute a major taxonomic challenge with an estimated diversity of 40,000 to 120,000 species worldwide, only 18,000 of which have been described to date. The skeletal morphology of braconids is still not adequately understood and the terminology is partly idiosyncratic, despite the fact that anatomical features form the basis for most taxonomic work on the group. To help address this problem, we describe the external skeletal morphology of Opius dissitus Muesebeck 1963 and Biosteres carbonarius Nees 1834, two diverse representatives of one of the least known and most diverse braconid subfamilies, the Opiinae. We review the terminology used to describe skeletal features in the Ichneumonoidea in general and the Opiinae in particular, and identify a list of recommend terms, which are linked to the online Hymenoptera Anatomy Ontology. The morphology of the studied species is illustrated with SEM-micrographs, photos and line drawings. Based on the examined species, we discuss intraspecific and interspecific morphological variation in the Opiinae and point out character complexes that merit further study