Ceramic thermal protective coating withstands hostile environment of rotating turbine blades

Ceramic coatings have low thermal conductivity. They provide potential for increased engine performance, reduced fuel consumption, use of less costly materials or construction procedures, and increased life and durability

Industry tests of NASA ceramic thermal barrier coating

Ceramic thermal barrier coating (TBC) system was tested by industrial and governmental organizations for a variety of aeronautical, marine, and ground-based gas turbine engine applications. This TBC is a two-layer system with a bond coating of nickel-chromium-aluminum-yttrium (Ni-16Cr-6Al-0.6Y, in wt. percent) and a ceramic coating of yttria-stabilized zirconia (ZrO2-12Y2O3, in wt. percent). Seven tests evaluated the system's thermal protection and durability. Five other tests determined thermal conductivity, vibratory fatigue characteristics, and corrosion resistance of the system. The information presented includes test results and photographs of the coated parts. Recommendations are made for improving the coating procedures

Ceramic thermal-barrier coatings for cooled turbines

Coating systems consisting of a plasma sprayed layer of zirconia stabilized with either yttria, magnesia or calcia over a thin alloy bond coat have been developed, their potential was analyzed and their durability and benefits evaluated in a turbojet engine. The coatings on air cooled rotating blades were in good condition after completing as many as 500 two-minute cycles of engine operation between full power at a gas temperature of 1644 K and flameout, or as much as 150 hours of steady state operation on cooled vanes and blades at gas temperatures as high as 1644 K with 35 start and stop cycles. On the basis of durability and processing cost, the yttria stabilized zirconia was considered the best of the three coatings investigated

Potential use of ceramic coating as a thermal insulation on cooled turbine hardware

An analysis was made to determine the potential benefits of using a ceramic thermal insulation coating of calcia-stabilized zirconia on cooled engine parts. The analysis was applied to turbine vanes of a high temperature and high pressure core engine and a moderate temperature and low pressure research engine. Measurements made during engine operation showed that the coating substantially reduced vane metal wall temperatures. Evaluation of the durability of the coating on turbine vanes and blades in a furnace and engine were encouraging

Further industrial tests of ceramic thermal barrier coatings

The NASA Lewis Research Center made technical assistance arrangements (contracts) with several commercial organizations under which Lewis designed plasma-sprayed thermal-barrier coatings (TBC) for their products. Lewis was then furnished with the test conditions and evaluations of coating usefulness. The coating systems were developed and sprayed at Lewis. All of the systems incorporated a two-layer, ceramic-bond coating concept. Coating thickness and chemical composition were varied to fit three applications: the leading edges of first-stage turbine vanes for an advanced gas turbine engine; the flame impingement surfaces of a combustor transition section; and diesel engine valves and head surfaces. The TBC incorporated yytria-stabilized zirconia, which lowered metal temperatures, protected metal parts, and increased metal part life. In some cases metal burning, melting, and warping were eliminated. Additional benefits were realized from these endeavors: hands-on experience with thermal-barrier coatings was provided to industry; the success of these endeavors encourages these and other organizations to accelerate the implementation of TBC technology

Summary of NASA research on thermal-barrier coatings

A durable, two-layer, plasma-sprayed coating consisting of a ceramic layer over a metallic layer was developed that has the potential of insulating hot engine parts and thereby reducing metal temperatures and coolant flow requirements and/or permitting use of less costly and complex cooling configurations and materials. The investigations evaluated the reflective and insulative capability, microstructure, and durability of several coating materials on flat metal specimens, a combustor liner, and turbine vanes and blades. In addition, the effect on the aerodynamic performance of a coated turbine vane was measured. The tests were conducted in furnaces, cascades, hot-gas rigs, an engine combustor, and a research turbojet engine. Summaries of current research related to the coating and potential applications for the coating are included

The True Incidence of Magnetism among Field White Dwarfs

We study the incidence of magnetism in white dwarfs from three large and well-observed samples of hot, cool, and nearby white dwarfs in order to test whether the fraction of magnetic degenerates is biased, and whether it varies with effective temperature, cooling age, or distance. The magnetic fraction is considerably higher for the cool sample of Bergeron, Ruiz, and Leggett, and the Holberg, Oswalt, and Sion sample of local white dwarfs that it is for the generally-hotter white dwarfs of the Palomar Green Survey. We show that the mean mass of magnetic white dwarfs in this survey is 0.93 solar masses or more, so there may be a strong bias against their selection in the magnitude-limited Palomar Green Survey. We argue that this bias is not as important in the samples of cool and nearby white dwarfs. However, this bias may not account for all of the difference in the magnetic fractions of these samples. It is not clear that the magnetic white dwarfs in the cool and local samples are drawn from the same population as the hotter PG stars. In particular, two or threee of the cool sample are low-mass white dwarfs in unresolved binary systems. Moreover, there is a suggestion from the local sample that the fractional incidence may increase with decreasing temperature, luminosity, and/or cooling age. Overall, the true incidence of magnetism at the level of 2 megagauss or greater is at least 10%, and could be higher. Limited studies capable of detecting lower field strengths down to 10 kilogauss suggest by implication that the total fraction may be substantially higher than 10%.Comment: 16 pages, 2 figures, Astronomical Journal in press -- Jan 2003 issu

Non-LTE spectral analyses of the lately discovered DB-gap white dwarfs from the SDSS

For a long time, no hydrogen-deficient white dwarfs have been known that have effective temperature between 30 kK and < 45 kK, i.e. exceeding those of DB white dwarfs and having lower ones than DO white dwarfs. Therefore, this temperature range was long known as the DB-gap. Only recently, the SDSS provided spectra of several candidate DB-gap stars. First analyses based on model spectra calculated under the assumption of local thermodynamic equilibrium (LTE) confirmed that these stars had 30 kK < Teff < 45 kK (Eisenstein et al. 2006). It has been shown for DO white dwarfs that the relaxation of LTE is necessary to account for non local effects in the atmosphere caused by the intense radiation field. Therefore, we calculated a non-LTE model grid and re-analysed the aforementioned set of SDSS spectra. Our results confirm the existence of DB-gap white dwarfs.Comment: 4 pages, 2 figures, to appear in: Proceedings of the 16th European Workshop on White Dwarf

High temperature thermocouple and heat flux gauge using a unique thin film-hardware hot juncture

A special thin film-hardware material thermocouple (TC) and heat flux gauge concept for a reasonably high temperature and high flux flat plate heat transfer experiment was fabricated and tested to gauge temperatures of 911 K. This concept was developed for minimal disturbance of boundary layer temperature and flow over the plates and minimal disturbance of heat flux through the plates. Comparison of special heat flux gauge Stanton number output at steady-state conditions with benchmark literature data was good and agreement was within a calculated uncertainty of the measurement system. Also, good agreement of special TC and standard TC outputs was obtained and the results are encouraging. Oxidation of thin film thermoelements was a primary failure mode after about 5 of operation

Analysis of a Very Massive DA White Dwarf via the Trigonometric Parallax and Spectroscopic Methods

By two different methods, we show that LHS 4033 is an extremely massive white dwarf near its likely upper mass limit for destruction by unstable electron captures. From the accurate trigonometric parallax reported herein, the effective temperature (T=10,900 K) and the stellar radius (R=0.00368 R_sun) are directly determined from the broad-band spectral energy distribution -- the parallax method. The effective temperature and surface gravity are also estimated independently from the simultaneous fitting of the observed Balmer line profiles with those predicted from pure-hydrogen model atmospheres -- the spectroscopic method (T=10,760 K, log g=9.46). The mass of LHS 4033 is then inferred from theoretical mass-radius relations appropriate for white dwarfs. The parallax method yields a mass estimate of 1.310--1.330 M_sun, for interior compositions ranging from pure magnesium to pure carbon, respectively, while the spectroscopic method yields an estimate of 1.318--1.335 M_sun for the same core compositions. This star is the most massive white dwarf for which a robust comparison of the two techniques has been made.Comment: 17 pages, including 4 figures, Accepted for Ap.