Instability of the one-texture universe

The one-texture universe, introduced by Davis in 1987, is a homogeneous mapping of a scalar field with an S^3 vacuum into a closed universe. It has long been known to mathematicians that such solutions, although static, are unstable. We show by explicit construction that there are four degenerate lowest modes which are unstable, corresponding to collapse of the texture towards a single point, in the case where gravitational back reaction is neglected. We discuss the instability time scale in both static and expanding space-times; in the latter case it is of order of the present age of the universe, suggesting that, though unstable, the one-texture universe could survive to the present. The cosmic microwave background constrains the initial magnitude of this unstable perturbation to be less than ∼10^-3

Detecting and distinguishing topological defects in future data from the CMBPol satellite

The proposed CMBPol mission will be able to detect the imprint of topological defects on the CMB provided the contribution is sufficiently strong. We quantify the detection threshold for cosmic strings and for textures, and analyze the satellite's ability to distinguish between these different types of defects. We also assess the level of danger of misidentification of a defect signature as from the wrong defect type or as an effect of primordial gravitational waves. A 0.002 fractional contribution of cosmic strings to the CMB temperature spectrum at multipole ten, and similarly a 0.001 fractional contribution of textures, can be detected and correctly identified at the 3 level. We also confirm that a tensor contribution of r=0.0018 can be detected at over 3, in agreement with the CMBPol mission concept study. These results are supported by a model selection analysis

Axion Cosmology and the Energy Scale of Inflation

We survey observational constraints on the parameter space of inflation and axions and map out two allowed windows: the classic window and the inflationary anthropic window. The cosmology of the latter is particularly interesting; inflationary axion cosmology predicts the existence of isocurvature fluctuations in the CMB, with an amplitude that grows with both the energy scale of inflation and the fraction of dark matter in axions. Statistical arguments favor a substantial value for the latter, and so current bounds on isocurvature fluctuations imply tight constraints on inflation. For example, an axion Peccei-Quinn scale of 10^16 GeV excludes any inflation model with energy scale > 3.8*10^14 GeV (r > 2*10^(-9)) at 95% confidence, and so implies negligible gravitational waves from inflation, but suggests appreciable isocurvature fluctuations.Comment: 10 PRD pages, 4 figs, V3: updated to match published versio

Manipulating Self-Assembly in Silver(I) Complexes of 1,3-Di-\u3cem\u3eN\u3c/em\u3e-pyrazolylorganyls

Three di-N-pyrazolylorganyls with different conformational flexibilities in the three-atom organyl spacers have been prepared, and the self-assembly properties with AgBF4 have been studied both in solution and in the solid state. All ligands give low-coordinate silver(I) centers that are capable of participating in multiple noncovalent interactions, but only the rigid 1,8-dipyrazolylnaphthalene ligand promotes very short Ag−Ag contacts

Ligand-Promoted Solvent-Dependent Ionization and Conformational Equilibria of Re(CO)\u3csub\u3e3\u3c/sub\u3eBr[CH\u3csub\u3e2\u3c/sub\u3e(\u3cem\u3eS\u3c/em\u3e-tim)\u3csub\u3e2\u3c/sub\u3e] (tim = 1-methylthioimidazolyl). Crystal Structures of Re(CO)\u3csub\u3e3\u3c/sub\u3eBr[CH\u3csub\u3e2\u3c/sub\u3e(\u3cem\u3eS\u3c/em\u3e-tim)\u3csub\u3e2\u3c/sub\u3e] and {Re(CO)\u3csub\u3e3\u3c/sub\u3e(CH\u3csub\u3e3\u3c/sub\u3eCN)[CH\u3csub\u3e2\u3c/sub\u3e(S-tim)\u3csub\u3e2\u3c/sub\u3e]}(PF\u3csub\u3e6\u3c/sub\u3e)

The compounds Re(CO)3Br[CH2(S-tim)2] (1) and {Re(CO)3(CH3CN)[CH2(S-tim)2]}(PF6) (2), where tim is 1-methylthioimidazolyl, were prepared in high yields and characterized both in the solid state and in solution. The solid-state structures show that the ligand acts in a chelating binding mode where the eight-member chelate ring adopts twist-boat conformations in both compounds. A comparison of both solid-state IR data for CO stretching frequencies and the solution-phase voltammetric measurements for the Re1+/2+ couples between 1, 2, and related N,N-chelates of the rhenium tricarbonyl moiety indicate that the CH2(S-tim)2 ligand is a stronger donor than even the ubiquitous dipyridyl ligands. A combination of NMR spectroscopic studies and voltammetric studies revealed that compound 1 undergoes spontaneous ionization to form {Re(CO)3(CH3CN)[CH2(S-tim)2]+}(Br-) in acetonitrile. Ionization does not occur in solvents such as CH2Cl2 or acetone that are less polar and Lewis basic (less coordinating). The equilibrium constant at 293 K for the ionization of 1 in CH3CN is 4.3 × 10-3. The eight-member chelate rings in each 1 and 2 were found to be conformationally flexible in all solvents, and boat-chair conformers could be identified. Variable-temperature NMR spectroscopic studies were used to elucidate the various kinetic and thermodynamic parameters associated with the energetically accessible twist-boat to twist-boat and twist-boat to boat-chair interconversions

Ground-based detections of thermal emission from CoRoT-1b and WASP-12b

We report a new detection of the H-band thermal emission of CoRoT-1b and two confirmation detections of the Ks-band thermal emission of WASP-12b at secondary eclipses. The H-band measurement of CoRoT-1b shows an eclipse depth of 0.145%\pm0.049% with a 3-{\sigma} percentile between 0.033% - 0.235%. This depth is consistent with the previous conclusions that the planet has an isother- mal region with inefficient heat transport from dayside to nightside, and has a dayside thermal inversion layer at high altitude. The two Ks band detections of WASP-12b show a joint eclipse depth of 0.299%\pm0.065%. This result agrees with the measurement of Croll & collaborators, providing independent confirmation of their measurement. The repeatability of the WASP-12b measurements also validates our data analysis method. Our measurements, in addition to a number of previous results made with other telescopes, demonstrate that ground-based observations are becoming widely available for characterization of atmospheres of hot Jupiters.Comment: 20 pages, including 8 figures and 1 table. Accepted for publication in Ap

Narnian Virtues - Year 3 Qualitative Data

This dataset follows a Fouth Generation Evaluation methodology. Focus groups with students (years 7 to 9) and teachers were carried out, to understand the impact of the Narnian Virtues Character Education Curriculu

Carbohydrate-derived iminium salt organocatalysts for the asymmetric epoxidation of alkenes

A new family of carbohydrate-based dihydroisoquinolinium salts has been prepared and tested for potential as asymmetric catalysts for the epoxidation of unfunctionalized alkene substrates, providing up to 57% ee in the product epoxides

Can topological defects mimic the BICEP2B-mode signal?

We show that the B-mode polarization signal detected at low multipoles by BICEP2 cannot be entirely due to topological defects. This would be incompatible with the high-multipole B-mode polarization data and also with existing temperature anisotropy data. Adding cosmic strings to a model with tensors, we find that B modes on their own provide a comparable limit on the defects to that already coming from Planck satellite temperature data. We note that strings at this limit give a modest improvement to the best fit of the B-mode data, at a somewhat lower tensor-to-scalar ratio of r ≃ 0.15