Calculation and Analysis of Two Level Traps Model in Polymeric Materials

Space charge formation in polymeric materials can cause some serious concern for design engineers as the electric field may severely be distorted, leading to part of the material being overstressed, resulting in material degradation and possibly premature failure at the worst. It is therefore important to understand charge generation, trapping, and detrapping processes in the material. Trap depths and concentration of materials are important as they are potentially related to microstructure of the material. Changes in these parameters may reflect aging taken place in the material. In the present paper, characteristics of charge trapping and detrapping in low density polyethylene (LDPE) under dc electric field have been investigated using the pulsed electroacoustic (PEA) technique. A simple trapping and detrapping model based on two trapping levels has been used to qualitatively explain the observation. Numerical simulation based on the above model has been carried out to extract parameters related to the material. It has been found that trap depths and concentration of both shallow and deep traps show significant differences for the sample with different periods of electric field application. Besides, the trap energy levels of these shallow and deep traps are compared with the values in literature to evaluate the model. The results indicate that trap depths and concentration of both shallow and deep traps may be used as aging markers as changes in the material will certainly affect trapping characteristics (trap depth and concentration)

Effect of thermally aged oil on space charge dynamics in oil/paper insulation system

The formation of space charge in oil/paper insulation system can lead to material degradation in the high electrical field region and affect system reliability. Therefore, it is important to understand factors that affect space charge formation in oil/paper insulation system. In the present study the effect of thermally aged oil on space charge dynamics in oil/paper insulation system has been investigated using the pulsed electroacoustic (PEA) technique under different dc electrical fields at room temperature. The condition of oil was characterised. The ultraviolet/visible (UV/Vis) spectrum of oil shifts to visible wavelength and the oil acidity increased as the ageing time increased. It has been found that oil property has a significant effect on the space charge distribution of oil/paper insulation system. The more the deterioration of the oil and the higher the applied voltage, the larger the amount of negative charge injected into the paper near to the cathode and the positive charge accumulated at the paperpaper interface near to the cathode. The maximum electric field strength for oil/paper sample with seriously aged oil under 4kV and 6kV is more than 20% higher than its average electric field strength

A Novel Nanomodified Cellulose Insulation Paper for Power Transformer

A novel cellulose insulation paper handsheet has successfully been modified with various contents of montmorillonite (MMT). Relative permittivity and breakdown strength were investigated. The microstructure of MMT in Kraft paper was observed with scanning electron microscopy (SEM) and X-ray diffraction. The relative permittivity of the immersed oil Kraft-MMT handsheets (K-MMT) initially decreased with the increasing amount of MMT. For MMT concentration of 9 wt%, K-9% MMT possessed the lowest relative permittivity of approximately 2.3 at 50 Hz. The breakdown voltage of the paper-oil-paper composite insulation system increased from 50.3 kV to 56.9 kV. The tensile strength of the paper handsheet was also measured

A Comparative Study of Physicochemical, Dielectric and Thermal Properties of Pressboard Insulation Impregnated with Natural Ester and Mineral Oil

Natural ester is considered to be a substitute of mineral oil in the future. To apply natural ester in large transformers safely, natural ester impregnated solid insulation should be proved to have comparable dielectric strength and thermal stability to mineral oil impregnated solid insulation. This paper mainly focuses on a comparative study of physicochemical, ac breakdown strength and thermal stability behavior of BIOTEMP natural ester/pressboard insulation and Karamay 25# naphthenic mineral oil/pressboard insulation after long term thermal ageing. The physicochemical and dielectric parameters including moisture, acids and the ac breakdown strength of these two oil/pressboard insulation systems at different ageing status were compared. The permittivity and ac breakdown strength of these two oil/pressboard insulation systems at different temperatures were also investigated. And a comparative result of the thermal stability behavior of these two oil/pressboard insulation systems with different ageing status was provided at last. Results show that though natural ester has higher absolute humidity and acidity during the long ageing period, the lower relative humidity of natural ester helps to keep its ac breakdown strength higher than mineral oil. The pressboard aged in natural ester also has higher ac breakdown strength than that aged in mineral oil. The lower relative permittivity ratio of natural ester impregnated paper to natural ester is beneficial to its dielectric strength. Using natural ester in transformer, the resistance to thermal decomposition of the oil/pressboard insulation system could be also effectively improved

Influence of High Voltage Electrostatic Field (HVEF) on Vigour of Aged Rice (Oryza sativa L.) Seeds

The vigour restoration of aged rice seeds is of great significance in agriculture. This paper studied the biological effects of high voltage electrostatic field (HVEF) on aged rice seeds, including dry seeds and wet seeds soaked in sterile deionized water for 24 hours. The results showed that HVEF slightly affected the vigour of the aged dry rice seeds while the seed vigour and seedling growth of the aged wet rice seeds were significantly improved. The germination rate and germination potentiality also showed moderate improvement after exposure to HVEF with electric intensity less than t 450 kV•m-1. Compared to control, the vigour index of aged wet rice seeds was increased 31.96%. No significant effects of HVEF on dry aged rice seeds were found

The Insulation Properties of Oil-Impregnated Insulation Paper Reinforced with Nano-TiO 2

Oil-impregnated insulation paper has been widely used in transformers because of its low cost and desirable physical and electrical properties. However, research to improve the insulation properties of oil-impregnated insulation paper is rarely found. In this paper, nano-TiO2 was used to stick to the surface of cellulose which was used to make insulation paper. After oil-impregnated insulation paper reinforced by nano-TiO2 was prepared, the tensile strength, breakdown strength, and dielectric properties of the oil-impregnated insulation paper were investigated to determine whether the modified paper had a better insulation performance. The results show that there were no major changes in tensile strength, and the value of the breakdown strength was greatly improved from 51.13 kV/mm to 61.78 kV/mm. Also, the values of the relative dielectric constant, the dielectric loss, and conductivity declined. The discussion reveals that nano-TiO2 plays a major role in the phenomenon. Because of the existence of nano-TiO2, the contact interface of cellulose and oil was changed, and a large number of shallow traps were produced. These shallow traps changed the insulation properties of oil-impregnated insulation paper. The results show that the proposed solution offers a new method to improve the properties of oil-impregnated insulation paper

Effect of different drying techniques on the volatile compounds, morphological characteristics and thermal stability of Stevia rebaudiana Bertoni leaf

Purpose: To examine the volatile compounds, thermal stability and morphological characteristics of stevia (Stevia rebaudiana Bertoni) leaves after sun, oven and microwave drying.Methods: Gas chromatography-mass spectrometry with a spectral analysis manager was used to separate the volatile compounds. Dried stevia leaf powder was characterized morphologically by scanning electron microscopy while thermal properties were determined by differential scanning calorimetry (DSC).Results: The plant material contained large amounts of spathulenol and caryophyllene oxide. The main compounds were 1-docosanol and hexanoic acid; trans-β-ionone, 5-methylundecane, 2,5,6-trimethyldecane, (+) spathulenol, propanoic acid and 1-chlorononadecane. The surface of the dried leaf powder varied with the treatment applied. Following microwave drying, the particles were even, regular, and compact while the sun- and oven dried particles resembled angular bricks. All samples exhibited a strong endothermic response, indicating stability up to 150 °C; from 150 to 200 °C, thermal decomposition occurred.Conclusion: Drying method has a significant effect on the structure, thermal stability and volatile compounds contents of stevia leaves. All drying methods examined in this study have potential applications in the preparation of stevia as a functional ingredient for the food and pharmaceutical industries.Keywords: Differential scanning calorimetry, Drying techniques, Stevia rebaudiana, Pharmaceuticals, Scanning electron microscopy, Volatile compound

Improved Electric Strength and Space Charge Characterization in LDPE Composites with Montmorillonite Fillers

Space charge distribution and breakdown strength were investigated in composites of low density polyethylene (LDPE) and various contents of montmorillonite (MMT). The disperse performance of MMT in LDPE was observed with scanning electron microscopy (SEM) and X-ray diffraction. For MMT concentration of 1 wt%, the better intercalation of LDPE into MMT interlayers and the tighter interface structure between polymer-filler were observed, relative to MMT concentration of 3 and 5 wt%. Space charge profiles were obtained using the pulsed electroacoustic (PEA) method. Less space charge accumulated in the LDPE/MMT with MMT content of 1 wt% than that in pure LDPE, and space charge in the central of LDPE/MMT was much more uniformly. On the other hand, when MMT concentration was up to 3 and 5 wt%, large amounts of heterocharges were accumulated in the sample bulk. In MMT doped samples the dielectric strength increased up to a maximum at 1 wt% loading, and then decreases at 3 and 5 wt%