Chemical analysis by X-ray spectroscopy near phase transitions in the solid state

The methods discussed in this work show that the types of changes which may be observed, by precise XAS measurements of Absorbance A versus temperature, across a phase transition are: the changes in the relaxation time of the final states due to fluctuations near a phase transition; the detection of the anomalous Bragg condition coupled to phonon modes XAS enhancement that identifies the temperature interval where the phonon modes are active, the symmetry changes which introduce new allowed transitions to finite states below an element edge, near Tc indicate what symmetry changes occur, and the method of XTDAFST0 = XAFS(T) - XAFS(T0), allows the precise measurement of the progressive changes in the Debye-Waller factor versus T near a phase transition, and identify (when no other structural changes occur, except in the vibrational modes of a specific bond) the bond responsible for the transition. The methods have been applied to the superconducting transition in layer cuprates and the metal to insulator transition in NiS2-xSex

Description of ρ(1700)\rho (1700) as a ρKKˉ\rho K \bar{K} system with the fixed center approximation

We study the $\rho K\bar{K}$ system with an aim to describe the $\rho (1700)$ resonance. The chiral unitary approach has achieved success in a description of systems of the light hadron sector. With this method, the $K \bar{K}$ system in the isospin sector $I=0$, is found to be a dominant component of the $f_0 (980)$ resonance. Therefore, by regarding the $K\bar{K}$ system as a cluster, the $f_0 (980)$ resonance, we evaluate the $\rho K\bar{K}$ system applying the fixed center approximation to the Faddeev equations. We construct the $\rho K$ unitarized amplitude using the chiral unitary approach. As a result, we find a peak in the three-body amplitude around 1739 MeV and a width of about 227 MeV. The effect of the width of $\rho$ and $f_0 (980)$ is also discussed. We associate this peak to the $\rho (1700)$ which has a mass of $1720 \pm 20$ MeV and a width of $250 \pm 100$ MeV

Baryon states with open charm in the extended local hidden gauge approach

In this paper we examine the interaction of $D N$ and $D^* N$ states, together with their coupled channels, by using an extension of the local hidden gauge formalism from the light meson sector, which is based on heavy quark spin symmetry. The scheme is based on the use of the impulse approximation at the quark level, with the heavy quarks acting as spectators, which occurs for the dominant terms where there is the exchange of a light meson. The pion exchange and the Weinberg-Tomozawa interactions are generalized and with this dynamics we look for states generated from the interaction, with a unitary coupled channels approach that mixes the pseudoscalar-baryon and vector-baryon states. We find two states with nearly zero width which are associated to the $\Lambda_c(2595)$ and $\Lambda_c(2625)$. The lower state, with $J^P = 1/2^-$, couples to $D N$ and $D^* N$, and the second one, with $J^P = 3/2^-$, to $D^* N$. In addition to these two $\Lambda_c$ states, we find four more states with $I=0$, one of them nearly degenerate in two states of $J=1/2,\ 3/2$. Furthermore we find three states in $I=1$, two of them degenerate in $J=1/2, 3/2$.Comment: v3: version to appear in Eur.Phys.J.

The Value of “Bespoke”: Demand Learning, Preference Learning, and Customer Behavior

“Bespoke,” or mass customization strategy, combines demand learning and preference learning. We develop an analytical framework to study the economic value of bespoke systems and investigate the interaction between demand learning and preference learning. We find that it is possible for demand learning and preference learning to be either complements or substitutes, depending on the customization cost and the demand uncertainty profile. They are generally complements when the personalization cost is low and the probability of having high demand is large. Contrary to usual belief, we show that higher demand uncertainty does not necessarily yield more complementarity benefits. Our numerical study shows that the complementarity benefit becomes weaker when customers are more strategic. Interestingly, the substitute loss can occur when the personalization cost is small and the probability of having high demand is large, when customers are strategic.postprin

Comparison between the Torquato-Rintoul theory of the interface effect in composite media and elementary results

We show that the interface effect on the properties of composite media recently proposed by Torquato and Rintoul (TR) [Phys. Rev. Lett. 75, 4067 (1995)] is in fact elementary, and follows directly from taking the limit in the dipolar polarizability of a coated sphere: the TR ``critical values'' are simply those that make the dipolar polarizability vanish. Furthermore, the new bounds developed by TR either coincide with the Clausius-Mossotti (CM) relation or provide poor estimates. Finally, we show that the new bounds of TR do not agree particularly well with the original experimental data that they quote.Comment: 13 pages, Revtex, 8 Postscript figure