Control of mercury emissions using unburned carbon from combustion by-products

Mercury emission from a flue gas such as that generated by a coal fired power plant is controlled by injecting into the flue gas unburned carbon purified from ash such as fly ash or wood ash. The unburned carbon adsorbs the mercury and is later removed from the flue gas by a particle separator. The unburned carbon collected from ash is significantly lower in cost compared to activated carbon presently used in such a process. The unburned carbon is concentrated in the sorbent by one or more separation processes used to remove noncarbon particles from the fly ash. These processes include gravity separation, electrostatic separation, froth flotation, magnetic separation and size classification. Mercury adsorption is further increased by oxidation of the carbon surface.https://digitalcommons.mtu.edu/patents/1066/thumbnail.jp

Different evolutionary patterns between young duplicate genes in the human genome

BACKGROUND: Following gene duplication, two duplicate genes may experience relaxed functional constraints or acquire different mutations, and may also diverge in function. Whether the two copies will evolve in different patterns remains unclear, however, because previous studies have reached conflicting conclusions. In order to resolve this issue, by providing a general picture, we studied 250 independent pairs of young duplicate genes from the whole human genome. RESULTS: We showed that nearly 60% of the young duplicate gene pairs have evolved at the amino-acid level at significantly different rates from each other. More than 25% of these gene pairs also showed significantly different ratios of nonsynonymous to synonymous rates (K(a)/K(s )ratios). Moreover, duplicate pairs with different rates of amino-acid substitution also tend to differ in the K(a)/K(s )ratio, with the fast-evolving copy tending to have a slightly higher K(s )than the slow-evolving one. Lastly, a substantial portion of fast-evolving copies have accumulated amino-acid substitutions evenly across the protein sequences, whereas most of the slow-evolving copies exhibit uneven substitution patterns. CONCLUSIONS: Our results suggest that duplicate genes tend to evolve in different patterns following the duplication event. One copy evolves faster than the other and accumulates amino-acid substitutions evenly across the sequence, whereas the other copy evolves more slowly and accumulates amino-acid substitutions unevenly across the sequence. Such different evolutionary patterns may be largely due to different functional constraints on the two copies

Temporal higher-order interactions facilitate the evolution of cooperation

Motivated by the vital progress of modeling higher-order interactions by hypernetworks, where a link connects more than two individuals, we study the evolution of cooperation on temporal hypernetworks. We find that temporal hypernetworks may promote cooperation compared with their static counterparts. Our results offer new insights into the impact of network temporality in higher-order interactions on understanding the evolution of cooperation, suggesting traditional networks based on pairwise or static interactions may underestimate the potential of local interactions to foster cooperation.Comment: 6 pages, 4 figure

The Influence of Shanghai’s Population Structure on City’s Housing Demand and the Solution for Housing Supply

In a city like Shanghai, where one of the biggest and fastest growing of both the population and quantity of housing demand and supply in the world exists, the need to estimate the influence of population transition on housing demand becomes a vital task. This research presented the characteristics of Shanghai’s population transition in future and then housing demand in future is forecasted; finally, the strategy to control the housing market is presented. The results revealed that the population characteristics, the housing demand and the control strategy has interaction relationship with each other: the population characteristics and trend such as population quantity and structure lay in five points, which decides the housing demand in six ways and then it will decide the six strategies needed to control the housing market in Shanghai; while the latter ones will adapt to the variation of the former ones.Key words: Influence; Population transition; Housing demand and supply; Housing market; Shangha

The immunomodulatory effect of IL-4 accelerates bone substitute material-mediated osteogenesis in aged rats via NLRP3 inflammasome inhibition

BackgroundBone defect repair by implanting bone substitute materials has been a common clinical treatment. With the understanding of substance–immune system interactions and increasing evidence indicating that the post-implantation immune response determines the fate of bone substitute materials, active modulation of host macrophage polarization is considered a promising strategy. However, whether the same regulatory effects exist when an individual immune system is altered with aging is unclear. MethodsIn this study, we mechanistically investigated the effect of immunosenescence on the active regulation of macrophage polarization by establishing a cranial bone defect model in young and aged rats implanted with Bio-Oss®. Forty-eight young and 48 aged specific pathogen-free (SPF) male SD rats were randomly divided into two groups. In the experimental group, 20 μL of IL-4 (0.5 μg/mL) was injected locally on the third to seventh postoperative days, while an equal volume of PBS was injected in the control group. Specimens were collected at 1, 2, 6, and 12 weeks postoperatively, and bone regeneration at the defect site was evaluated by micro-CT, histomorphometry, immunohistochemistry, double-labeling immunofluorescence, and RT–qPCR.ResultsThe application of exogenous IL-4 reduced activation of NLRP3 inflammasomes by promoting the polarization of M1 macrophages to M2 macrophages, thus promoting bone regeneration at the site of bone defects in aged rats. However, this effect was gradually weakened after the IL-4 intervention was discontinued.ConclusionOur data confirmed that a strategy to regulate macrophage polarization is also feasible under conditions of immunosenescence, i.e., the local inflammatory microenvironment can be regulated by reducing M1-type macrophages. However, further experiments are needed to determine an exogenous IL-4 intervention that can maintain a more sustained effect

Propagating Surface Plasmon Polaritons: Towards Applications for Remote-Excitation Surface Catalytic Reactions

Plasmonics is a well-established field, exploiting the interaction of light and metals at the nanoscale; with the help of surface plasmon polaritons, remote-excitation can also be observed by using silver or gold plasmonic waveguides. Recently, plasmonic catalysis was established as a new exciting platform for heterogeneous catalytic reactions. Recent reports present remote-excitation surface catalytic reactions as a route to enhance the rate of chemical reactions, and offer a pathway to control surface catalytic reactions. In this review, we focus on recent advanced reports on silver plasmonic waveguide for remote-excitation surface catalytic reactions. First, the synthesis methods and characterization techniques of sivelr nanowire plasmonic waveguides are summarized, and the properties and physical mechanisms of plasmonic waveguides are presented in detail. Then, the applications of plasmonic waveguides including remote excitation fluorescence and SERS are introduced, and we focus on the field of remote-excitation surface catalytic reactions. Finally, forecasts are made for possible future applications for the remote-excitation surface catalysis by plasmonic waveguides in living cells

A “built-up” composite film with synergistic functionalities on Mg–2Zn–1Mn bioresorbable stents improves corrosion control effects and biocompatibility

Control of premature corrosion of magnesium (Mg) alloy bioresorbable stents (BRS) is frequently achieved by the addition of rare earth elements. However, limited long-term experience with these elements causes concerns for clinical application and alternative methods of corrosion control are sought after. Herein, we report a “built-up” composite film consisting of a bottom layer of MgF2 conversion coating, a sandwich layer of a poly (1, 3-trimethylene carbonate) (PTMC) and 3-aminopropyl triethoxysilane (APTES) co-spray coating (PA) and on top a layer of poly (lactic-co-glycolic acid) (PLGA) ultrasonic spray coating to decorate the rare earth element-free Mg–2Zn–1Mn (ZM21) BRS for tailoring both corrosion resistance and biological functions. The developed “built-up” composite film shows synergistic functionalities, allowing the compression and expansion of the coated ZM21 BRS on an angioplasty balloon without cracking or peeling. Of special importance is that the synergistic corrosion control effects of the “built-up” composite film allow for maintaining the mechanical integrity of stents for up to 3 months, where complete biodegradation and no foreign matter residue were observed about half a year after implantation in rabbit iliac arteries. Moreover, the functionalized ZM21 BRS accomplished re-endothelialization within one month