Control of the Stability, Electron-Transfer Kinetics, and pH-Dependent Energetics of Si/H_2O Interfaces through Methyl Termination of Si(111) Surfaces

Methyl-terminated, n-type, (111)-oriented Si surfaces were prepared via a two-step chlorination-alkylation method. This surface modification passivated the Si surface toward electrochemical oxidation and thereby allowed measurements of interfacial electron-transfer processes in contact with aqueous solutions. The resulting semiconductor/liquid junctions exhibited interfacial kinetics behavior in accord with the ideal model of a semiconductor/liquid junction. In contrast to the behavior of H-terminated Si(111) surfaces, current density vs. potential measurements of CH_3-terminated Si(111) surfaces in contact with an electron acceptor having a pH-independent redox potential (methyl viologen^(2+/+)) were used to verify that the band edges of the modified Si electrode were fixed with respect to changes in solution pH. The results provide strong evidence that the energetics of chemically modified Si interfaces can be fixed with respect to pH and show that the band-edge energies of Si can be tuned independently of pH-derived variations in the electrochemical potential of the solution redox species

CubeSat Measures World's First Ice Cloud Map to Support Climate Research

Virginia Diodes, Inc. received NASA SBIR Awards to fund research and development for a lesser developed region of the electromagnetic spectrumterahertz waves. Their work led to funding from NASA ESTO, and the resulting CubeSat (named IceCube) captured the worlds first ice cloud map, which will contribute to our understanding of Earths climat

Estimates of genetic parameters of distal limb fracture and superficial digital flexor tendon injury in UK Thoroughbred racehorses

A retrospective cohort study of distal limb fracture and superficial digital flexor tendon (SDFT) injury in Thoroughbred racehorses was conducted using health records generated by the British Horseracing Authority (BHA) between 2000 and 2010. After excluding records of horses that had both flat and jump racing starts, repeated records were reduced to a single binary record per horse (<i>n</i> = 66,507, 2982 sires), and the heritability of each condition was estimated using residual maximum likelihood (REML) with animal logistic regression models. Similarly, the heritability of each condition was estimated for the flat racing and jump racing populations separately. Bivariate mixed models were used to generate estimates of genetic correlations between SDFT injury and distal limb fracture. The heritability of distal limb fracture ranged from 0.21 to 0.37. The heritability of SDFT injury ranged from 0.31 to 0.34. SDFT injury and distal limb fracture were positively genetically correlated. These findings suggest that reductions in the risk of the conditions studied could be attempted using targeted breeding strategies

An Application of the Finite Element Method to the Drying of Timber

The finite element method has been used to solve a set of differential equations that govern the transfer of heat and mass in porous bodies. Computed results are presented and are compared with the results of previously published experimental work for timber drying