4 research outputs found

    [(4R,5R)-(2,2-Dimethyl-1,3-dioxolane-4,5-di­yl)bis­(diphenyl­methano­lato)-κ2 O:O′]bis(N-methyl­methanamin­ato)titanium(IV)

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    In the title four-coordinate complex, [Ti(C2H6N)2(C31H28O4)], two symmetry-independent mol­ecules are present in the asymmetric unit. The TiIV atom displays a distorted tetra­hedral geometry, with Ti—O bond lengths ranging from 1.805 (3) to 1.830 (3) Å and O—Ti—O ligand bite angles of 100.16 (12) and 101.36 (12)°. The short Ti—N bond distances, ranging from 1.877 (4) to 1.905 (4) Å, indicate strong bonding between the TiIV atom and the dimethyl­amide ligands
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