4 research outputs found
[(4R,5R)-(2,2-Dimethyl-1,3-dioxolane-4,5-diÂyl)bisÂ(diphenylÂmethanoÂlato)-κ2 O:O′]bis(N-methylÂmethanaminÂato)titanium(IV)
In the title four-coordinate complex, [Ti(C2H6N)2(C31H28O4)], two symmetry-independent molÂecules are present in the asymmetric unit. The TiIV atom displays a distorted tetraÂhedral geometry, with Ti—O bond lengths ranging from 1.805 (3) to 1.830 (3) Å and O—Ti—O ligand bite angles of 100.16 (12) and 101.36 (12)°. The short Ti—N bond distances, ranging from 1.877 (4) to 1.905 (4) Å, indicate strong bonding between the TiIV atom and the dimethylÂamide ligands