94 research outputs found
Optical spectra, crystal-field parameters, and magnetic susceptibility of the new multiferroic NdFe3(BO3)4
We report high-resolution optical absorption spectra for NdFe3(BO3)4 trigonal
single crystal which is known to exhibit a giant magnetoelectric effect below
the temperature of magnetic ordering TN = 33 K. The analysis of the
temperature-dependent polarized spectra reveals the energies and, in some
cases, symmetries and exchange splittings of Nd3+ 84 Kramers doublets. We
perform crystal-field calculations starting from the exchange-charge model,
obtain a set of six real crystal-field parameters, and calculate wave functions
and magnetic g-factors. In particular, the values g(perpendicular) = 2.385,
g(parallel) = 1.376 were found for the Nd3+ ground-state doublet. We obtain
Bloc=7.88 T and |JFN|= 0.48 K for the values of the local effective magnetic
field at liquid helium temperatures at the Nd3+ site and the Nd - Fe exchange
integral, respectively, using the experimentally measured Nd3+ ground-state
splitting of 8.8 cm-1. To check reliability of our set of crystal field
parameters we model the magnetic susceptibility data from literature. A dimer
containing two nearest-neighbor iron ions in the spiral chain is considered to
partly account for quasi-one-dimensional properties of iron borates, and then
the mean-field approximation is used. The results of calculations with the
exchange parameters for Fe3+ ions Jnn = -6.25 K (intra-chain interactions) and
Jnnn = -1.92 K (inter-chain interactions) obtained from fitting agree well with
the experimental data.Comment: 13 pages, 8 figures, 2 table
Vibrational spectroscopy of GdCr3(BO3)4: Quantitative separation of crystalline phases
This work is devoted to the investigation of GdCr3(BO3)4 crystals by the method of infrared spectroscopy. Incongruently melting borate GdCr3(BO3)4 was obtained as a result of spontaneous crystallization. Crystal structures were identified by the method of infrared spectroscopy. Ab initio calculations in the frame of density functional theory enabled us to separate modes belonging to the R32 and C2/c phases and to estimate the ratio of these phases in GdCr3(BO3)4 crystals. We have found that the content of the rhombohedral R32 (non- centrosymmetric) modification is about 85%. © Published under licence by IOP Publishing Ltd
Magnetic Resonance of the Intrinsic Defects of the Spin-Peierls Magnet CuGeO3
ESR of the pure monocrystals of CuGeO3 is studied in the frequency range 9-75
GHz and in the temperature interval 1.2-25 K. The splitting of the ESR line
into several spectral components is observed below 5 K, in the temperature
range where the magnetic susceptibility is suppressed by the spin-Peierls
dimerization. The analysis of the magnetic resonance signals allows one to
separate the signals of the S=1/2- and S=1 defects of the spin-Peierls phase.
The value of g-factor of these signals is close to that of the Cu-ion. The
additional line of the magnetic resonance is characterized by an anomalous
value of the g-factor and by the threshold-like increase of the microwave
susceptibility when the microwave power is increasing. The ESR signals are
supposingly attributed to two types of the planar magnetic defects, arising at
the boundaries of the domains of the spin-Peierls state with the different
values of the phase of the dimerization.Comment: LATEX-text, 12 PS-figures, typos corrected, LATEX-style change
Highly efficient continuous-wave diode-pumped Er, Yb:GdAl3(BO3)4 laser
We report the highly efficient continuous-wave diode-pumped laser operation of Er, Yb:GdAl3 BO3 4 crystal. Absorption and stimulated emission spectra, emission lifetimes, and efficiencies of energy transfer from Yb3 to Er3 ions were determined. A maximal output power of 780 mWwas obtained at 1531 nm at absorbed pump power of 4 W with slope efficiency of 26%
Laser Performance of Er,Yb:YAl3(BO3)4 Crystals with Different Erbium Concentrations
The effect of erbium concentration on the laser performance of Er,Yb:YAl3(BO3)4 crystals was investigated. A maximal output power of 1.6 W in CW and 2.7 W in QCW regimes was obtained at 1522 nm
Folded modes in the infrared spectra of the spin-Peierls phase of CuGeO_3
Polarized far-infrared transmittance spectra of CuGeO_3 single crystals were
measured at different temperatures (6K < T < 300K). Two spectral lines, at
284.2 cm-1 in E||c polarization and at 311.7 cm-1 in E||b polarization, appear
at the temperature of the spin-Peierls transition and grow in intensity with
decreasing temperature. Both of them are, most probably, folded modes of the
dimerized lattice. We discuss a possible role of the spin-phonon interaction in
the formation of the 311.7 cm-1 feature.Comment: 4 pages, 5 figures, 1 table; Submitted to Phys.Rev.B Second revision.
Figures and text were slightly change
Efficient 1 W continuous-wave diode-pumped Er,Yb:YAl3(BO3)4 laser
We report the spectroscopy and high-power continuous-wave (CW) diode-pumped laser operation of Er:Yb:YAl3(BO3)4 crystal. Absorption and stimulated emission spectra, emission lifetimes, and efficiency of energy transfer from Yb3+ to Er3+ ions were determined. A CW Er:Yb:YAB laser emitting at 1602, 1555, and 1531 nm with output power as high as 1 W and slope efficiency up to 35% was demonstrated
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