Vibrational states and disorder in continuously compressed model glasses

We present in this paper a numerical study of the vibrational eigenvectors of a two-dimensional amorphous material, previously deeply studied from the point of view of mechanical properties and vibrational eigen-frequencies [7-10]. Attention is paid here to the connection between the mechanical properties of this material in term of elastic heterogeneities (EH), and how these inherent heterogeneous structures affect the vibrational eigenvectors and their plane waves decomposition. The systems are analysed for different hydrostatic pressures, and using results from previous studies, a deeper understanding of the boson peak scenario is obtained. The vibrational spectrum of a continuously densified silica glass is also studied, from which it appears that the pulsation associated with the boson peak follows the same pressure dependence trend than that of transverse waves with pulsation associated with the EH characteristic size.Comment: 9 pages, 12 figure

Long-term reliability of photovoltaic c-Si modules - A detailed assessment based on the first Italian BIPV project

Assessing the long-term reliability of PV systems is important for understanding their energy and cost efficiency. Typically, estimates and predictions are based on indoor tests and accelerated ageing. However, fluctuating and differently interacting outdoor factors such as solar radiation, dust, and shadowing in real environment can impact the actual performance. This paper examines alterations related to ageing of c-Si PV modules, firstly by classifying the main factors that affect aged c-Si PV modules and then assessing the impact on their performance degradation by analysing a pilot BIPV system at Politecnico di Milano after 20 years of actual operation. Such system, which is highly representative since is the first public BIPV plant funded in Italy, was carefully and continuously monitored during its operating life. In particular, according to the visual/IR inspection carried out after the 20th year of operation, the main observed alteration in the modules were discoloration of the encapsulant, delamination, and chalking of the backsheet. The I-V characterization shown that all sampled modules had an overall degradation rate of less than 20 %, which is within the warranty limit, although in many cases the degradation rate over time shows a non-linear trend. Only one module experienced a severe fault that caused the complete loss of functionality. Obtained results confirm the reliability of c-Si technology, stressing the importance of a careful monitoring especially after the 15th year, when an increase of the degradation rate might occur

water pvt collectors performance comparison

Abstract Flat plate PVT water based technology presents many advantages in terms of overall performance and space saving than the PV modules and the solar thermal collectors installed separately. However, the electrical and the thermal performances of the PVT technologies are more deeply related to different influences factors, among which: the presence or absence of the air gap formed by the transparent frontal cover, the absorber configuration and the adopted PV technology. For that reasons, the proposed research is aimed to assess, under the energy point of view, a comparison between a covered and an uncovered PVT water collectors, realized with different PV cells coupled to two aluminium roll-bond absorbers characterized also by different channel arrangements. The performance analysis is based on energy simulations carried out with two mathematical models validated on experimental data at the Test Facility of the Politecnico di Milano

Dressed emitters as impurities

Dressed states forming when quantum emitters or atoms couple to a photonic bath underpin a number of phenomena and applications, in particular nonradiating effective interactions occurring within photonic bandgaps. Here, we present a compact formulation of the resolvent-based theory for calculating atom-photon dressed states built on the idea that the atom behaves as an effective impurity. This establishes an explicit connection with the standard impurity problem in condensed matter. Moreover, it allows us to formulate and settle - independently of the bath Hamiltonian - a number of properties previously known only for specific models or not entirely formalized. The framework is next extended to the case of more than one emitter, which is used to derive a general expression of dissipationless effective Hamiltonians explicitly featuring the overlap of single-emitter dressed bound states

Continuum limit of amorphous elastic bodies (III): Three dimensional systems

Extending recent numerical studies on two dimensional amorphous bodies, we characterize the approach of elastic continuum limit in three dimensional (weakly polydisperse) Lennard-Jones systems. While performing a systematic finite-size analysis (for two different quench protocols) we investigate the non-affine displacement field under external strain, the linear response to an external delta force and the low-frequency harmonic eigenmodes and their density distribution. Qualitatively similar behavior is found as in two dimensions. We demonstrate that the classical elasticity description breaks down below an intermediate length scale $\xi$, which in our system is approximately 23 molecular sizes. This length characterizes the correlations of the non-affine displacement field, the self-averaging of external noise with distance from the source and gives the lower wave length bound for the applicability of the classical eigenfrequency calculations. We trace back the "Boson-peak" of the density of eigenfrequencies (obtained from the velocity auto-correlation function) to the inhomogeneities on wave lengths smaller than $\xi$.Comment: 27 pages, 11 figures, submitted to Phys. Rev.

Towards Sustainability Assessment of the Built Environment: A Classification of the Existing Challenges

The application of sustainability assessment in a decision context is associated with various challenges that explain why the transition to action-oriented knowledge still needs to be fulfilled. Therefore, this paper aims to explore the associated challenges in sustainability assessment in the decision context of the built environment. Several publications are reviewed to provide a systemic understanding of the associated complexities. The challenges in sustainability assessment in the built environment are categorized at different levels, from understanding to measurement and implementation. The challenges are further categorized into definition, context, interpretation, data, measurement methods, uncertainties, indicators and indices, results, coordination, conflicts, and action-oriented knowledge. Moreover, according to the nature of each challenge, they are classified into epistemological, methodological, and procedural challenges. The novelty of this review is that it reviews and reports almost all fragmentedly reported challenges in sustainability assessment of the built environment in the literature within a holistic framework that provides a clear understanding of the state of the art and second discusses them within an integrated framework (the Sustainability Assessment Network) including the position of active-role players to resolve them, including strategists, scientist, and stakeholders

Plastic Response of a 2D Lennard-Jones amorphous solid: Detailed analysis of the local rearrangements at very slow strain-rate

We analyze in details the atomistic response of a model amorphous material submitted to plastic shear in the athermal, quasistatic limit. After a linear stress-strain behavior, the system undergoes a noisy plastic flow. We show that the plastic flow is spatially heterogeneous. Two kinds of plastic events occur in the system: quadrupolar localized rearrangements, and shear bands. The analysis of the individual motion of a particle shows also two regimes: a hyper-diffusive regime followed by a diffusive regime, even at zero temperature

Microscopic elasticity of complex systems

Lecture Notes for the Erice Summer School 2005 Computer Simulations in Condensed Matter: from Materials to Chemical Biology. Perspectives in celebration of the 65th Birthday of Mike Klein organized by Kurt Binder, Giovanni Ciccotti and Mauro Ferrari

Stress response inside perturbed particle assemblies

The effect of structural disorder on the stress response inside three dimensional particle assemblies is studied using computer simulations of frictionless sphere packings. Upon applying a localised, perturbative force within the packings, the resulting {\it Green's} function response is mapped inside the different assemblies, thus providing an explicit view as to how the imposed perturbation is transmitted through the packing. In weakly disordered arrays, the resulting transmission of forces is of the double-peak variety, but with peak widths scaling linearly with distance from the source of the perturbation. This behaviour is consistent with an anisotropic elasticity response profile. Increasing the disorder distorts the response function until a single-peak response is obtained for fully disordered packings consistent with an isotropic description.Comment: 8 pages, 7 figure captions To appear in Granular Matte

Continuum limit of amorphous elastic bodies: A finite-size study of low frequency harmonic vibrations

The approach of the elastic continuum limit in small amorphous bodies formed by weakly polydisperse Lennard-Jones beads is investigated in a systematic finite-size study. We show that classical continuum elasticity breaks down when the wavelength of the sollicitation is smaller than a characteristic length of approximately 30 molecular sizes. Due to this surprisingly large effect ensembles containing up to N=40,000 particles have been required in two dimensions to yield a convincing match with the classical continuum predictions for the eigenfrequency spectrum of disk-shaped aggregates and periodic bulk systems. The existence of an effective length scale \xi is confirmed by the analysis of the (non-gaussian) noisy part of the low frequency vibrational eigenmodes. Moreover, we relate it to the {\em non-affine} part of the displacement fields under imposed elongation and shear. Similar correlations (vortices) are indeed observed on distances up to \xi~30 particle sizes.Comment: 28 pages, 13 figures, 3 table