2,393 research outputs found
Cooperative Carbon Dioxide Adsorption in Alcoholamine- and Alkoxyalkylamine-Functionalized Metal-Organic Frameworks.
A series of structurally diverse alcoholamine- and alkoxyalkylamine-functionalized variants of the metal-organic framework Mg2 (dobpdc) are shown to adsorb CO2 selectively via cooperative chain-forming mechanisms. Solid-state NMR spectra and optimized structures obtained from van der Waals-corrected density functional theory calculations indicate that the adsorption profiles can be attributed to the formation of carbamic acid or ammonium carbamate chains that are stabilized by hydrogen bonding interactions within the framework pores. These findings significantly expand the scope of chemical functionalities that can be utilized to design cooperative CO2 adsorbents, providing further means of optimizing these powerful materials for energy-efficient CO2 separations
Fast Neutron Detector for Fusion Reactor KSTAR Using Stilbene Scintillator
Various neutron diagnostic tools are used in fusion reactors to evaluate
different aspects of plasma performance, such as fusion power, power density,
ion temperature, fast ion energy, and their spatial distributions. The stilbene
scintillator has been proposed for use as a neutron diagnostic system to
measure the characteristics of neutrons from the Korea Superconducting Tokamak
Advanced Research (KSTAR) fusion reactor. Specially designed electronics are
necessary to measure fast neutron spectra with high radiation from a gamma-ray
background. The signals from neutrons and gamma-rays are discriminated by the
digital charge pulse shape discrimination (PSD) method, which uses total to
partial charge ratio analysis. The signals are digitized by a flash
analog-to-digital convertor (FADC). To evaluate the performance of the
fabricated stilbene neutron diagnostic system, the efficiency of 10 mm
soft-iron magnetic shielding and the detection efficiency of fast neutrons were
tested experimentally using a 252Cf neutron source. In the results, the
designed and fabricated stilbene neutron diagnostic system performed well in
discriminating neutrons from gamma-rays under the high magnetic field
conditions during KSTAR operation. Fast neutrons of 2.45 MeV were effectively
measured and evaluated during the 2011 KSTAR campaign.Comment: 15 pages, 14 figures, conferenc
STK295900, a Dual Inhibitor of Topoisomerase 1 and 2, Induces G<inf>2</inf> Arrest in the Absence of DNA Damage
STK295900, a small synthetic molecule belonging to a class of symmetric bibenzimidazoles, exhibits antiproliferative activity against various human cancer cell lines from different origins. Examining the effect of STK295900 in HeLa cells indicates that it induces G2 phase arrest without invoking DNA damage. Further analysis shows that STK295900 inhibits DNA relaxation that is mediated by topoisomerase 1 (Top 1) and topoisomerase 2 (Top 2) in vitro. In addition, STK295900 also exhibits protective effect against DNA damage induced by camptothecin. However, STK295900 does not affect etoposide-induced DNA damage. Moreover, STK295900 preferentially exerts cytotoxic effect on cancer cell lines while camptothecin, etoposide, and Hoechst 33342 affected both cancer and normal cells. Therefore, STK295900 has a potential to be developed as an anticancer chemotherapeutic agent. © 2013 Kim et al
ZFIRE: Measuring Electron Density with [OII] as a function of environment at z = 1.62
The global star formation rates (SFR) of galaxies at fixed stellar masses
increase with redshift and are known to vary with environment unto z~2. We
explore here whether the changes in the star formation rates can also apply to
the electron densities of the inter-stellar medium (ISM) by measuring the [OII]
(3727A/3729A) ratio for cluster and field galaxies at z~2. We measure a median
electron density of ne = 366+/-84 cm-3 for six galaxies (with 1-sigma scatter =
163 cm-3) in the UDS proton-cluster at z=1.62. We find that the median electron
density of galaxies in the UDS photo-cluster environment is three times higher
compared to the median electron density of field galaxies (ne = 113+/- 63 cm-3
and 1-sigma scatter = 79 cm-3) at comparable redshifts, stellar mass and SFR.
However, we note that a sample of six photo-cluster galaxies is insufficient to
reliably measure the electron density in the average porto-cluster environment
at z~2. We conclude that the electron density increases with redshift in both
cluster and field environments up to z~2 (ne = 30 +/- 1 cm-3 for z ~ 0 to ne
=254+/- 76 cm-3 for z~1.5). We find tentative evidence (~2.6 sigma ) for a
possible dependence of electron density on environment, but the results require
confirmation with larger sample sizes.Comment: 18 Pages, 6 figures, 3 tables, Accepted for publication in
Astrophysical Journa
Exceptionally Slow Rise in Differential Reflectivity Spectra of Excitons in GaN: Effect of Excitation-induced Dephasing
Femtosecond pump-probe (PP) differential reflectivity spectroscopy (DRS) and
four-wave mixing (FWM) experiments were performed simultaneously to study the
initial temporal dynamics of the exciton line-shapes in GaN epilayers. Beats
between the A-B excitons were found \textit{only for positive time delay} in
both PP and FWM experiments. The rise time at negative time delay for the
differential reflection spectra was much slower than the FWM signal or PP
differential transmission spectroscopy (DTS) at the exciton resonance. A
numerical solution of a six band semiconductor Bloch equation model including
nonlinearities at the Hartree-Fock level shows that this slow rise in the DRS
results from excitation induced dephasing (EID), that is, the strong density
dependence of the dephasing time which changes with the laser excitation
energy.Comment: 8 figure
Single Spin Asymmetries of Inclusive Hadrons Produced in Electron Scattering from a Transversely Polarized He Target
We report the first measurement of target single-spin asymmetries (A) in
the inclusive hadron production reaction,
+, using a transversely polarized
He target. The experiment was conducted at Jefferson Lab in Hall A using a
5.9-GeV electron beam. Three types of hadrons (,
and proton) were detected in the transverse hadron momentum range 0.54
0.74 GeV/c. The range of for pions was -0.29 -0.23 and for kaons
-0.25 -0.18. The observed asymmetry strongly depends on the type of
hadron. A positive asymmetry is observed for and . A
negative asymmetry is observed for . The magnitudes of the asymmetries
follow . The K and proton
asymmetries are consistent with zero within the experimental uncertainties. The
and asymmetries measured for the He target and
extracted for neutrons are opposite in sign with a small increase observed as a
function of .Comment: Updated version, submitted to Phys. Rev.
Double Spin Asymmetries of Inclusive Hadron Electroproductions from a Transversely Polarized Target
We report the measurement of beam-target double-spin asymmetries
() in the inclusive production of identified hadrons,
+, using a longitudinally
polarized 5.9 GeV electron beam and a transversely polarized
target. Hadrons (, and proton) were detected at
16 with an average momentum =2.35 GeV/c and a transverse
momentum () coverage from 0.60 to 0.68 GeV/c. Asymmetries from the
target were observed to be non-zero for production
when the target was polarized transversely in the horizontal plane. The
and asymmetries have opposite signs, analogous to the
behavior of in semi-inclusive deep-inelastic scattering.Comment: Published in PRC (92.015207), nuclear experiment, high-energy
experimen
Single Spin Asymmetries in Charged Kaon Production from Semi-Inclusive Deep Inelastic Scattering on a Transversely Polarized Target
We report the first measurement of target single spin asymmetries of charged
kaons produced in semi-inclusive deep inelastic scattering of electrons off a
transversely polarized target. Both the Collins and Sivers
moments, which are related to the nucleon transversity and Sivers
distributions, respectively, are extracted over the kinematic range of
0.10.4 for and production. While the Collins and
Sivers moments for are consistent with zero within the experimental
uncertainties, both moments for favor negative values. The Sivers
moments are compared to the theoretical prediction from a phenomenological fit
to the world data. While the Sivers moments are consistent with the
prediction, the results differ from the prediction at the 2-sigma
level.Comment: 6 pages, 3 figure
Free induction signal from biexcitons and bound excitons
A theory of the free induction signal from biexcitons and bound excitons is
presented. The simultaneous existence of the exciton continuum and a bound
state is shown to result in a new type of time dependence of the free
induction. The optically detected signal increases in time and oscillates with
increasing amplitude until damped by radiative or dephasing processes.
Radiative decay is anomalously fast and can result in strong picosecond pulses.
The expanding area of a coherent exciton polarization (inflating antenna),
produced by the exciting pulse, is the underlying physical mechanism. The
developed formalism can be applied to different biexciton transients.Comment: RevTeX, 20 p. + 2 ps fig. To appear in Phys. Rev. B1
Measurement of pretzelosity asymmetry of charged pion production in Semi-Inclusive Deep Inelastic Scattering on a polarized He target
An experiment to measure single-spin asymmetries in semi-inclusive production
of charged pions in deep-inelastic scattering on a transversely polarized
He target was performed at Jefferson Lab in the kinematic region of
and . The pretzelosity asymmetries on
He, which can be expressed as the convolution of the
transverse momentum dependent distribution functions and the Collins
fragmentation functions in the leading order, were measured for the first time.
Using the effective polarization approximation, we extracted the corresponding
neutron asymmetries from the measured He asymmetries and cross-section
ratios between the proton and He. Our results show that for both
on He and on the neutron the pretzelosity asymmetries are
consistent with zero within experimental uncertainties.Comment: 6 pages, 3 figures; enlarged the legends in Fig.3; added 3 citation
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