610 research outputs found
TiOCl, an orbital-ordered system?
We present first principles density functional calculations and downfolding
studies of the electronic and magnetic properties of the layered quantum spin
system
TiOCl. We discuss explicitely the nature of the exchange pathes and attempt
to clarify the concept of orbital ordering in this material. An analysis of the
electronic structure of slightly distorted structures according to the phononic
modes allowed in this material suggests that this system is subject to large
orbital fluctuations driven by the electron-phonon coupling. Based on these
results, we propose a microscopic explanation of the behavior of TiOCl near the
phase transition to a spin-gapped system.Comment: Some figures are compressed, for higher quality please contact the
author
Anomalous electronic Raman scattering in Na_xCoO_2 H_2O
Raman scattering experiments on Na_{x}CoO_2 yH_2O single crystals show a
broad electronic continuum with a pronounced peak around 100 cm-1 and a cutoff
at approximately 560 cm-1over a wide range of doping levels. The electronic
Raman spectra in superconducting and non-superconducting samples are similar at
room temperature, but evolve in markedly different ways with decreasing
temperature. For superconducting samples, the low-energy spectral weight is
depleted upon cooling below T* sim 150K, indicating a opening of a pseudogap
that is not present in non-superconducting materials. Weak additional phonon
modes observed below T* suggest that the pseudogap is associated with charge
ordering.Comment: 5 pages, 4 figures, for further information see www.peter-lemmens.d
Collective Singlet Excitations and Evolution of Raman Spectral Weights in the 2D Spin Dimer Compound SrCu2(BO3)2
We present a Raman light scattering study of the two-dimensional quantum spin
system SrCu2(BO3)2 and show that the magnetic excitation spectrum has a rich
structure, including several well-defined bound state modes at low temperature,
and a scattering continuum and quasielastic light scattering contributions at
high temperature. The key to the understanding of the unique features of
SrCu2(BO3)2 is the presence of strong interactions between well-localized
triplet excitations in the network of orthogonal spin dimers realized in this
compound. Based on our analysis of the Heisenberg model relevant for this
material, we argue that the collective excitations involving two and
three-particle singlet bound states have large binding energies and are
observed as well-defined peaks in the Raman spectrum.Comment: 5 pages, 2 figures. Revised version, to appear in Phys. Rev. Lett.
(2000
Evidence for local lattice distortions in giant magnetocapacitive CdCr2S4
Raman scattering experiments on CdCr2S4 single crystals show pronounced
anomalies in intensity and frequency of optical phonon modes with an onset
temperature T*=130 K that coincides with the regime of giant magnetocapacitive
effects. A loss of inversion symmetry and Cr off-centering are deduced from the
observation of longitudinal optical and formerly infrared active modes for
T<T_c=84 K. The intensity anomalies are attributed to the enhanced electronic
polarizability of displacements that modulate the Cr-S distance and respective
hybridization. Photo doping leads to an annihilation of the symmetry reduction.
Our scenario of multiferroic effects is based on the near degeneracy of polar
and nonpolar modes and the additional low energy scale due to hybridization.Comment: 4 pages, 6 figure
Microscopic Evidence of Spin State Order and Spin State Phase Separation in Layered Cobaltites RBaCo2O5.5 with R=Y, Tb, Dy, and Ho
We report muon spin relaxation measurements on the magnetic structures of
RBaCo_2O_5.5 with R=Y, Tb, Dy, and Ho. Three different phases, one
ferrimagnetic and two antiferromagnetic, are identified below 300 K. They
consist of different ordered spin state arrangements of high-, intermediate-,
and low-spin Co^3+ of CoO_6 octahedra. Phase separation into well separated
regions with different spin state order is observed in the antiferromagnetic
phases. The unusual strongly anisotropic magnetoresistance and its onset at the
FM-AFM phase boundary is explained.Comment: 4 pages, accepted for publication in Phys. Rev. Let
Interplay of Spin and Lattice Degrees of Freedom in the Frustrated Antiferromagnet CdCr_2O_4: High-field and Temperature Induced Anomalies of the Elastic Constants
Temperature and magnetic field studies of the elastic constants of the
chromium spinel CdCr_2O_4 show pronounced anomalies related to strong
spin-phonon coupling in this frustrated antiferromagnet. A detailed comparison
of the longitudinal acoustic mode propagating along the [111] direction with
theory based on an exchange-striction mechanism leads to an estimate of the
strength of the magneto-elastic interaction. The derived spin-phonon coupling
constant is in good agreement with previous determinations based on infrared
absorption. Further insight is gained from intermediate and high magnetic field
experiments in the field regime of the magnetization plateau. The role of the
antisymmetric Dzyaloshinskii-Moriya interaction discussed and we compare the
spin-phonon coupling in CdCr_2O_4 in both the ordered and disordered states.Comment: 12 pages, 8 figures; Appendix added,To appear in Phys Rev.
Magnetism of a tetrahedral cluster spin-chain
We discuss the magnetic properties of a dimerized and completely frustrated
tetrahedral spin-1/2 chain. Using a combination of exact diagonalization and
bond-operator theory the quantum phase diagram is shown to incorporate a
singlet-product, a dimer, and a Haldane phase. In addition we consider one-,
and two-triplet excitations in the dimer phase and evaluate the magnetic Raman
cross section which is found to be strongly renormalized by the presence of a
two-triplet bound state. The link to a novel tellurate materials is clarified.Comment: 8 pages, 8 figure
Spin gap behavior and charge ordering in \alpha^{\prime}-NaV_2O_5 probed by light scattering
We present a detailed analysis of light scattering experiments performed on
the quarter-filled spin ladder compound -NaVO for
the temperature range 5 KT300 K. This system undergoes a phase
transition into a singlet ground state at T=34 K accompanied by the formation
of a super structure. For T34 K several new modes were detected. Three of
these modes are identified as magnetic bound states. Experimental evidence for
charge ordering on the V sites is detected as an anomalous shift and splitting
of a V-O vibration at 422 cm for temperatures above 34 K. The smooth and
crossover-like onset of this ordering at T= 80 K is accompanied by
pretransitional fluctuations both in magnetic and phononic Raman scattering. It
resembles the effect of stripe order on the super structure intensities in
LaNiO.Comment: 36 pages, 11 figures, accepted for publication in PRB (sept.99
Magnetic bound states in the quarter-filled ladder system }
Raman scattering in the quarter-filled spin ladder system alpha'-NaV_2O_5
shows in the dimerized singlet ground state () an unexpected
sequence of three magnetic bound states. Our results suggest that the recently
proposed mapping onto an effective spin chain for has to be given
up in favor of the full topology and exchange paths of a ladder in the
dimerized phase for . As the new ground state we propose a dynamic
superposition of energetically nearly degenerate dimer configurations on the
ladder.Comment: 5 pages, 4 figures, to be published in PRB, brief reports, Dec. 199
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