1,499 research outputs found
The Effect of Ordinary Portland Cement on Nuclear Waste Glass Dissolution
AbstractTo evaluate the durability of the glass matrix and to identify the key mechanisms responsible for glass alteration in the cementitious environment imposed by the Supercontainer design, glass leach tests were conducted at 30°C under Ar atmosphere in suspensions of Ordinary Portland Cement and synthetic young cement water with the high pH of 13.5. The cement appears to trigger the glass dissolution by consumption of glass matrix components leading to a fast glass dissolution at a constant rate with the formation of a porous gel layer on the glass. The key mechanism driving the long-term glass dissolution is secondary phase formation with Si and Al from the glass matrix. The two main reactions are the reaction of Si released by the glass with portlandite, leading to the formation of Calcium Silicate Hydrate (C-S-H) phases, and the further conversion of C-S-H phases with Al from the glass to form Calcium Aluminum Silicate Hydroxide (C-A-S-H) phases. After consumption of the portlandite, the glass alteration rate is expected to decrease
Relation between Kitaev magnetism and structure in -RuCl
Raman scattering has been employed to investigate lattice and magnetic
excitations of the honeycomb Kitaev material -RuCl and its
Heisenberg counterpart CrCl. Our phonon Raman spectra give evidence for a
first-order structural transition from a monoclinic to a rhombohedral structure
for both compounds. Significantly, only -RuCl features a large
thermal hysteresis, consistent with the formation of a wide phase of
coexistence. In the related temperature interval of K, we observe a
hysteretic behavior of magnetic excitations as well. The stronger magnetic
response in the rhombohedral compared to the monoclinic phase evidences a
coupling between the crystallographic structure and low-energy magnetic
response. Our results demonstrate that the Kitaev magnetism concomitant with
fractionalized excitations is susceptible to small variations of bonding
geometry.Comment: 9 pages, 8 figures, To appear in PR
Investigation of the oxohalogenide Cu4Te5O12Cl4 with weakly coupled Cu(II) tetrahedra
The crystal structure of the copper(II) tellurium(IV) oxochloride
CuTeOCl (Cu-45124) is composed of weakly coupled
tetrahedral Cu clusters and shows crystallographic similarities with the
intensively investigated compound CuTeOX, with X~=~Cl,
Br (Cu-2252). It differs from the latter by a larger separation of the
tetrahedra within the crystallographic ab plane, that allows a more direct
assignment of important inter-tetrahedra exchange paths and the existence of an
inversion center. Magnetic susceptibility and specific heat evidence
antiferromagnetic, frustrated correlations of the Cu spin moments and long
range ordering with =13.6 K. The entropy related to the transition is
reduced due to quantum fluctuations. In Raman scattering a well structured low
energy magnetic excitation is observed at energies of 50K
(35cm. This energy scale is reduced as compared to Cu-2252.Comment: 11 pages, 9 figures, further information see
http://www.peter-lemmens.d
Longitudinal magnon in the tetrahedral spin system Cu2Te2O5Br2 near quantum criticality
We present a comprehensive study of the coupled tetrahedra-compound
Cu2Te2O5Br2 by theory and experiments in external magnetic fields. We report
the observation of a longitudinal magnon in Raman scattering in the ordered
state close to quantum criticality. We show that the excited
tetrahedral-singlet sets the energy scale for the magnetic ordering temperature
T_N. This energy is determined experimentally. The ordering temperature T_N has
an inverse-log dependence on the coupling parameters near quantum criticality
Electronic Raman scattering of Tl-2223 and the symmetry of the supercon- ducting gap
Single crystalline Tl2Ba2Ca2Cu3O10 was studied using electronic Raman
scattering. The renormalization of the scattering continuum was investigated as
a function of the scattering geometry to determine the superconducting energy
gap 2Delta(k). The A1g- and B2g-symmetry component show a linear frequency
behaviour of the scattering intensity with a peak related to the energy gap,
while the B1g-symmetry component shows a characteristic behaviour at higher
frequencies. The observed frequency dependencies are consistent with a
dx^2-y^2-wave symmetry of the gap and yield a ratio of 2Delta/k_BT_c=7.4. With
the polarization of the scattered and incident light either parallel or
perpendicular to the CuO2-planes a strong anisotropy due to the layered
structure was detected, which indicates an almost 2 dimensional behaviour of
this system.Comment: 2 pages, Postscript-file including 2 figures. Accepted for
publication in the Proceedings of the M^2SHTSC IV Conference, Grenoble
(France), 5-9 July 1994. Proceedings to be published in Physica C. Contact
address: [email protected]
Giant phonon anomalies in the pseudo-gap phase of TiOCl
We report infrared and Raman spectroscopy results of the spin-1/2 quantum
magnet TiOCl. Giant anomalies are found in the temperature dependence of the
phonon spectrum, which hint to unusual coupling of the electronic degrees of
freedom to the lattice. These anomalies develop over a broad temperature
interval, suggesting the presence of an extended fluctuation regime. This
defines a pseudo-gap phase, characterized by a local spin-gap. Below 100 K a
dimensionality cross-over leads to a dimerized ground state with a global
spin-gap of about 2~430 K.Comment: 4 pages, 3 figures, for further information see
http://www.peter-lemmens.d
Revealing the correlation between real-space structure and chiral magnetic order at the atomic scale
We image simultaneously the geometric, electronic and magnetic structure of a
buckled iron bilayer film that exhibits chiral magnetic order. We achieve this
by combining spin-polarized scanning tunneling microscopy and magnetic exchange
force microscopy (SPEX), to independently characterize the geometric as well as
the electronic and magnetic structure of non-flat surfaces. This new SPEX
imaging technique reveals the geometric height corrugation of the
reconstruction lines resulting from strong strain relaxation in the bilayer,
enabling the decomposition of the real-space from the eletronic structure at
the atomic level, and the correlation with the resultant spin spiral ground
state. By additionally utilizing adatom manipulation, we reveal the chiral
magnetic ground state of portions of the unit cell that were not previously
imaged with SP-STM alone. Using density functional theory (DFT), we investigate
the structural and electronic properties of the reconstructed bilayer and
identify the favorable stoichiometry regime in agreement with our experimental
result
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