Local Development and Social Capital: The Case of Sotkamo

The paper discusses the role of social capital in the dramatic structural change that has taken place in the rural municipality of Sotkamo in north-eastern Finland. The main approach of this study is to observe the formation and use of social capital in important local events. Earlier definitions of local development have been based on factors such as natural resources, labour force, machines and tools, technology, knowledge and skills. The explanation based on social capital focuses on factors which increase and improve co-operation. Important issues of social capital are the existing rules of behaviour, the networks mediating these rules, and the trust amongst members of society that these rules are respected. In the case of Sotkamo the change has been the rise of tourism. Simultaneously this has meant the rise of Vuokatti as the central place in regional and local development. The paper is based on a questionnaire study and key-person interviews in Sotkamo. The paper discusses the following themes: What kind of actors and networks are participating in local development? Which actors are regarded as trustworthy in local development? What kinds of changes have occurred in the local identity and image? What kinds of struggles and coalitions of local power can be recognised? Results are analysed in the framework of social capital and local development. The study concludes that 'balanced' local development may take place, if the locality has the capacity of building networks that can meet the challenges of the future. Such networks should unite actors using both traditional local resources and new resources from outside of the locality. An important challenge is to balance the demands of economic restructuring and those of local community cohesion. This paper is based on the Finnish national study RESTRIM (Restructuring in Marginal Rural Areas: the role of social capital in rural development), a project that is funded by the European Union (for more, see http://www.abdn.ac.uk/arkleton/RESTRIM/).

Local Development and Social Capital: The Case of Sotkamo

The paper discusses the role of social capital in the dramatic structural change that has taken place in the rural municipality of Sotkamo in north-eastern Finland. The main approach of this study is to observe the formation and use of social capital in important local events. Earlier definitions of local development have been based on factors such as natural resources, labour force, machines and tools, technology, knowledge and skills. The explanation based on social capital focuses on factors which increase and improve co-operation. Important issues of social capital are the existing rules of behaviour, the networks mediating these rules, and the trust amongst members of society that these rules are respected. In the case of Sotkamo the change has been the rise of tourism. Simultaneously this has meant the rise of Vuokatti as the central place in regional and local development. The paper is based on a questionnaire study and key-person interviews in Sotkamo. The paper discusses the following themes: What kind of actors and networks are participating in local development? Which actors are regarded as trustworthy in local development? What kinds of changes have occurred in the local identity and image? What kinds of struggles and coalitions of local power can be recognised? Results are analysed in the framework of social capital and local development. The study concludes that 'balanced' local development may take place, if the locality has the capacity of building networks that can meet the challenges of the future. Such networks should unite actors using both traditional local resources and new resources from outside of the locality. An important challenge is to balance the demands of economic restructuring and those of local community cohesion. This paper is based on the Finnish national study RESTRIM (Restructuring in Marginal Rural Areas: the role of social capital in rural development), a project that is funded by the European Union (for more, see http://www.abdn.ac.uk/arkleton/RESTRIM/)

Effect of potassium for cesium replacement in atomic level structure of potassium cobalt hexacyanoferrate(II)

Potassium cobalt hexacyanoferrate(II) [K2CoFe(CN)(6)] is an extremely selective ion exchanger for cesium ions. To examine the atomic level background for the selectivity a computational structural study using DFT modelling was carried out for K2CoFe(CN)(6) and for products where Cs has replaced K in the elemental cube cages closest to the surface. In the K-form compound the potassium ions are not in the center of the Co-Fe-CN elementary cube cages closest to the surface but locate about 140 pm from the cube center towards the surface. When cesium ions are exchanged to these potassium ions they locate much deeper from the surface, being only about 70 pm upwards from the cube center. 'Ibis apparently leads to much stronger bonding of cesium compared to potassium. Once taken up into the outermost cube cages on the surface of the crystallites cesium ions are not able to penetrate further since they are much larger than the electron window between the cubes. Furthermore, they are not able to return to the solution phase either leading to a practically irreversible sorption.Peer reviewe

Batch sorption experiments of cesium and strontium on crushed rock and biotite for the estimation of distribution coefficients on intact crystalline rock

The distribution coefficient (Kd) of radionuclides on bedrock is one of the key parameters used in the safety analysis of spent nuclear fuel repositories. Typically, distribution coefficients have been determined using crushed rock. However, recent studies have shown that crushing of the rock increases considerably the distribution coefficient compared with the values of intact rock. This study aimed to test if batch sorption experiments using different grain sizes (i.e. mean diameter of grains) can be used to evaluate the Kd of strontium (Sr) and cesium (Cs) on intact crystalline rock, which would decrease the needed experimental time compared with transport experiments. Here we report the results of the batch sorption experiments with crushed rocks and compare the results with those from a recent study performed using electromigration experiments with intact drill core samples (Puukko et al., 2018). The batch sorption experiments were done for rock samples from Olkiluoto, Finland, as a function of grain size and of Cs and Sr concentration. Furthermore, the specific surface areas of the same rock samples with different grain sizes were determined. It was shown that Cs distribution coefficients correlate with specific surface areas of the studied rocks and biotite, the correlation coefficient being 0.95. The Cs distribution coefficient was highest for biotite at about 0.1 m3/kg at 10−4 M cesium concentration and increased systematically to about 1 m3/kg at 10−8 M. Distribution coefficients for rocks were up to about two orders of magnitude lower, being lowest with the rock with the lowest biotite content (3.3%). The distribution coefficient of Sr varied from 0.04 m3/kg to 0.007 m3/kg and behaved in a different manner: it remained constant in two out of three studied rocks in the concentration range of 10−8-10−4 M and only in the case of one rock a decreasing trend was seen at the higher concentration range. It was also shown that batch sorption experiments overestimate the distribution coefficient in respect to intact rock. The decrease of the distribution coefficient as a function of grain size can be estimated using a power law function. It was also shown that estimation of distribution coefficients of Cs and Sr for intact rock by extrapolation of distribution coefficients determined for different grain sizes is not possible without increasing grain size, but in that case diffusion into the grains would also affect the results. A new method was developed for estimating the fraction of the inner surface area of the total surface area of crushed grains. For the mean grain sizes of 0.25 mm and 0.75 mm the fraction of the inner surface was found to be 35–70% and 60–90%, respectively. The inner specific surface area was highest with biotite at 1.2 m2/g and lowest with the rock with lowest biotite content (3.3%) at 0.07 m2/g. The surface area analysis revealed that crushing creates and/or allows access to additional inner surface area that is not measured in intact rock. Furthermore, it was demonstrated that sorption of Cs on crushed rock was dominated by mica minerals in multiple concentrations while the effect of mica minerals on the Kd of Sr was not as straightforward.Peer reviewe

Sorption of inorganic radiocarbon on iron oxides

The sorption of inorganic radiocarbon on goethite, hematite and magnetite was studied as a function of carbon concentration, pH and ionic strength. It was discovered that the sorption of radiocarbon on magnetite was negligible in all studied conditions. The distribution coefficients of radiocarbon on hematite and goethite decreased with increasing pH whereas the ionic strength had only a slight decreasing effect on radiocarbon sorption. The sorption on goethite and hematite was modelled with PhreeqC using a generalized double-layer surface complexation model.Peer reviewe

Electromigration experiments for studying transport parameters and sorption of cesium and strontium on intact crystalline rock

This study aims to determine upscaling factors for the radionuclides' distribution coefficients (Kd) on crushed rocks to intact rock for the safety analysis of radionuclide migration from spent nuclear fuel in bedrock towards biosphere. Here we report the distribution coefficients for intact rock determined by electromigration sorption experiments and compare the results with those from recently performed batch sorption experiments. In total 34 rock samples, representing three typical rock types from Olkiluoto Finland, were studied in order to determine distribution coefficients, effective diffusion coefficients and porosities using the electromigration sorption experiments, formation factor experiments and porosity measurement. The parameters determined represent the three main parameters of geosphere used in the safety assessment of spent nuclear fuel disposal. The distribution coefficients of cesium and strontium on intact rock varied between (0.12–26.2) × 10−3 m3/kg and (1.4–13.3) × 10−3 m3/kg, respectively, whereas recent results for crushed rock varied between (2–57) × 10−3 m3/kg and (17–40) × 10−3 m3/kg, respectively. This implies that crushing increases the distribution coefficient significantly and upscaling factors from 3 to 33 were determined for scaling the distribution coefficients of crushed rock to ones of intact rock. The determined distribution coefficients of cesium and strontium for intact rock can be directly applied in the safety assessment whereas the upscaling factors can be used to convert distribution coefficients determined for crushed rock into ones for intact rock. Based on the results for porosities and effective diffusion coefficients it was concluded that they do not seem to correlate with sorption parameters. However, an alteration state, heterogeneity and mineral content seem to be important factors affecting the distribution coefficients and upscaling factors.Peer reviewe

Removal of Radionuclides from Fukushima Daiichi Waste Effluents

This paper describes the processes used at the Fukushima Daiichi plant, Japan, to purify the waste effluents generated in the cooling of damaged reactors. These include primary cesium removal with the Kurion zeolite system and the SARRY system utilizing silicotitanate to remove radiocesium from water recirculated to reactors for cooling. Another process is the ALPS system to purify the retentates of the reverse osmosis plant to further purify the water from radionuclides after primary cesium separation. In ALPS, a major role is played by the transition metal hexacyanoferrate product CsTreat and sodium titanate SrTreat in the removal of radiocesium and radiostrontium, respectively. The performance of these four exchangers (zeolite, silicotitanate, hexacyanoferrate, and sodium titanate) is critically analyzed with respect to processing capacities and the decontamination factors obtained in the processes. Furthermore, general information on preparation, structure and ion exchange of these ion-exchanger categories is given with additional information on their use in nuclear waste effluent treatment processes. Finally, the importance of selectivity and associated factors are discussed.Peer reviewe

Eteisvärinäpotilaan aivohalvauksen esto

Teema : eteisvärinä. English summaryPeer reviewe