Paper Session II-B - Insights into the Process of Converging Inter-Agency Government Programs

With the decreased funding available for government programs, many agencies have converged or are contemplating converging their functions and personnel in order to be cost effective and more efficient in their processes. This study provides an overview of the organizational theory related to convergence process and the issues and impacts of creating joint programs from independent, long standing military and civil programs. The management aspects of the convergence process, with an emphasis on human and organizational issues, are presented and lessons learned highlighted. The methodology used to conduct this study included an extensive literature search and survey. The survey was completed by individuals at different levels of management selected from six converged and converging government programs. The results of the study revealed a strong tendency for converged government programs to violate basic organizational theory principles during their convergence experiences. Survey results showed individuals in these converged organizations generally had lower than average morale, were physically separated from key parts of the organization, faced serious bureaucratic roadblocks, and felt that there was a lack of communication within their organizations. Finally, suggestions for conducting successful converged programs are outlined including: establish agreement on mission need and requirements as soon as possible; establish clear chain of command; provide honest, direct and frequent communications; establish equitable management and procedures; articulate a vision; and endeavor to bring all levels of workers together within a common set of goals

The reaction of H 8 Si 8 O 12 with a chromium oxide surface: a model for stainless steel surface modification

Many metal alloys are susceptible to corrosion, particularly after processing steps such as welding. Chemical vapor deposition (CVD) is an effective way to modify metal surfaces and impart specific physical and chemical properties. A hydrophobic, nanosegmented silicon oxide coating derived from the discrete cluster molecule H 8 Si 8 O 12 has been shown to chemisorb to 302 and 304 stainless steel. To understand better how this cluster binds to steel, a comprehensive study of these clusters adsorbed on chromium oxide was undertaken. IR, XPS and valence-band spectroscopies show convincingly that the clusters are chemisorbed intact on this surface. The coating also readily forms on molybdenum, tungsten, iron and nickel oxides, promising general application to a wide variety of metal alloys. Copyright © 1999 John Wiley & Sons, Ltd.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/34739/1/843_ftp.pd

Predicting enhanced absorption of light gases in polyethylene using simplified PC-SAFT and SAFT-VR

International audienceAbsorption of light gases in polyethylene (PE) is studied using two versions of the Statistical Associating Fluid Theory (SAFT): SAFT for chain molecules with attractive potentials of variable range (VR) and simplified perturbed-chain (PC) SAFT. Emphasis is placed on the light gases typically present during ethylene polymerisation in the gas-phase reactor (GPR) process. The two approaches are validated using experimental binary-mixture data for gas absorbed in PE, and predictions are made for mixtures of more components. For most cases studied both SAFT versions perform equally well. For the case of ternary mixtures of two gases with PE, it is predicted that the less-volatile of the two gases acts to enhance the absorption of the more-volatile gas, while the more-volatile gas inhibits the absorption of the less-volatile gas. This general behaviour is also predicted in mixtures containing more gases, such as typical reactor mixtures. The magnitude of the effect may vary considerably, depending on the relative proximity of the gas-mixture saturation pressure to the reactor pressure; for example it is predicted that the absorption of ethylene may be approximately doubled if diluent gases, propane or nitrogen, are partially or completely replaced by less-volatile butane or pentane for a reactor pressure similar to 2 MPa. In the case of a co-polymerisation reaction, it is predicted that increases in absorption of both co-monomers may be obtained in roughly equal proportion. Our findings cast light on the so-called co-monomer effect, in which substantial increases in the rate of ethylene polymerisation are observed in the presence of hexene co-monomer, while suggesting that the effect is more general and not restricted to co-monomer. For example, similar rate increases may be expected in the presence of, e.g., pentane instead of hexene, but without the change in the branch structure of the produced polymer that is inevitable when the amount of co-monomer is increased

Reactivity of a Nickel(II) Bis(amidate) Complex withmeta-Chloroperbenzoic Acid: Formation of a Potent Oxidizing Species

Herein, we report the formation of a highly reactive nickel–oxygen species that has been trapped following reaction of a NiII precursor bearing a macrocyclic bis(amidate) ligand with meta-chloroperbenzoic acid (HmCPBA). This compound is only detectable at temperatures below 250 K and is much more reactive toward organic substrates (i.e., C[BOND]H bonds, C[DOUBLE BOND]C bonds, and sulfides) than previously reported well-defined nickel–oxygen species. Remarkably, this species is formed by heterolytic O[BOND]O bond cleavage of a Ni–HmCPBA precursor, which is concluded from experimental and computational data. On the basis of spectroscopy and DFT calculations, this reactive species is proposed to be a NiIII–oxyl compound

PEACE: Pulsar evaluation algorithm for candidate extraction-a software package for post-analysis processing of pulsar survey candidates

Modern radio pulsar surveys produce a large volume of prospective candidates, the majorityof which are polluted by human-created radio frequency interference or other forms of noise. Typically, large numbers of candidates need to be visually inspected in order to determineif they are real pulsars. This process can be labour intensive. In this paper, we introducean algorithm called Pulsar Evaluation Algorithm for Candidate Extraction (PEACE) whichimproves the efficiency of identifying pulsar signals. The algorithm ranks the candidates basedon a score function. Unlike popular machine-learning-based algorithms, no prior training datasets are required. This algorithm has been applied to data from several large-scale radiopulsar surveys. Using the human-based ranking results generated by students in the AreciboRemote Command Center programme, the statistical performance of PEACE was evaluated. It was found that PEACE ranked 68 per cent of the student-identified pulsars within the top0.17 per cent of sorted candidates, 95 per cent within the top 0.34 per cent and 100 per centwithin the top 3.7 per cent. This clearly demonstrates that PEACE significantly increases thepulsar identification rate by a factor of about 50 to 1000. To date, PEACE has been directlyresponsible for the discovery of 47 new pulsars, 5 of which are millisecond pulsars that maybe useful for pulsar timing based gravitational-wave detection projects. © 2013 The Authors Published by Oxford University Press on behalf of the Royal Astronomical Society

Scale-free static and dynamical correlations in melts of monodisperse and Flory-distributed homopolymers: A review of recent bond-fluctuation model studies

It has been assumed until very recently that all long-range correlations are screened in three-dimensional melts of linear homopolymers on distances beyond the correlation length $\xi$ characterizing the decay of the density fluctuations. Summarizing simulation results obtained by means of a variant of the bond-fluctuation model with finite monomer excluded volume interactions and topology violating local and global Monte Carlo moves, we show that due to an interplay of the chain connectivity and the incompressibility constraint, both static and dynamical correlations arise on distances $r \gg \xi$. These correlations are scale-free and, surprisingly, do not depend explicitly on the compressibility of the solution. Both monodisperse and (essentially) Flory-distributed equilibrium polymers are considered.Comment: 60 pages, 49 figure

Do Market-Level Hospital and Physician Resources Affect Small Area Variation in Hospital Use?

This study evaluates the effect of market-level physician and hospital resources on hospital use. It is anticipated that higher hospital discharges are associated with (1) greater hospital and physician resources, (2) more differentiated hospital and physician resources, and (3) higher levels of teaching intensity in the community. Data on 14 modified diagnostically related groups (DRGs) and 58 hospital market communities in Michigan are analyzed during a 7-year period. Findings indicate that physician resources, hospital resources, differentiation of hospital and physician resources, and teaching intensity contribute only modestly to discharges, holding constant the socioeconomic attributes of the community and adjusting for the variation in hospital use over time. With the inclusion of hospital and physician resource variables, socioeconomic factors remain important determinants of the variation across market communities. Findings are discussed in terms of their implications for health care organizations, managed care programs, and cost control efforts in general.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/68450/2/6.pd