4 research outputs found
Triphenylphosphine Oxide as Highly Effective Electrolyte Additive for Graphite/NMC811 Lithium Ion Cells
Nickel-rich layered oxide materials (LiNixMnyCo1–x–yO2, x ≥ 0.8, LiNMC) attract great interest for application as positive electrode in lithium ion batteries (LIBs) due to high specific discharge capacities at moderate upper cutoff voltages below 4.4 V vs Li/Li+. However, the comparatively poor cycling stability as well as inferior safety characteristics prevent this material class from commercial application so far. Against this background, new electrolyte formulations including additives are a major prerequisite for a sufficient electrochemical performance of Ni-rich NMC materials. In this work, we introduce triphenylphosphine oxide (TPPO) as electrolyte additive for the application in graphite/LiNi0.8Mn0.1Co0.1O2 (NMC811) cells. The addition of only 0.5 wt % TPPO into a carbonate-based electrolyte (LiPF6 in EC:EMC) significantly increases the first cycle Coulombic efficiency as well as the reversible specific capacity and improves the capacity retention of the LIB full cell cycled between 2.8 and 4.3 V. Electrochemical results indicate that the full cell capacity fade is predominantly caused by active lithium loss at the negative electrode. In this contribution, X-ray photoelectron spectroscopy and inductively coupled plasma-mass spectrometry analysis confirm the participation of the electrolyte additive in the solid electrolyte interphase formation on the negative electrode as well as in the cathode electrolyte interphase formation on the positive electrode, thus, effectively reducing the active lithium loss during cycling. Furthermore, the performance of the TPPO additive is compared to literature known electrolyte additives including triphenylphosphine, vinylene carbonate, and diphenyl carbonate demonstrating the outstanding working ability of TPPO in graphite/NMC811 cells
Adaptive Aggregation of Peptide Model Systems
Jet-cooled
infrared spectra of acetylated glycine, alanine, and
dialanine esters and their dimers are reported in the amide A and
amide I–III regions. They serve as particularly simple peptide
aggregation models and are found to prefer a single backbone conformation
in the dimer that is different from the most stable monomer backbone
conformation. In the case of alanine, evidence for topology-changing
chirality discrimination upon dimer formation is found. The jet spectroscopic
results are compared to gas phase spectra and quantum chemical calculations.
They provide reliable benchmarks for the evaluation of the latter
in the field of peptide interactions
Triphenylphosphine Oxide as Highly Effective Electrolyte Additive for Graphite/NMC811 Lithium Ion Cells
Nickel-rich
layered oxide materials (LiNi<sub><i>x</i></sub>Mn<sub><i>y</i></sub>Co<sub>1–<i>x</i>–<i>y</i></sub>O<sub>2</sub>, <i>x</i> ≥ 0.8, LiNMC)
attract great interest for application as positive
electrode in lithium ion batteries (LIBs) due to high specific discharge
capacities at moderate upper cutoff voltages below 4.4 V vs Li/Li<sup>+</sup>. However, the comparatively poor cycling stability as well
as inferior safety characteristics prevent this material class from
commercial application so far. Against this background, new electrolyte
formulations including additives are a major prerequisite for a sufficient
electrochemical performance of Ni-rich NMC materials. In this work,
we introduce triphenylphosphine oxide (TPPO) as electrolyte additive
for the application in graphite/LiNi<sub>0.8</sub>Mn<sub>0.1</sub>Co<sub>0.1</sub>O<sub>2</sub> (NMC811) cells. The addition of only
0.5 wt % TPPO into a carbonate-based electrolyte (LiPF<sub>6</sub> in EC:EMC) significantly increases the first cycle Coulombic efficiency
as well as the reversible specific capacity and improves the capacity
retention of the LIB full cell cycled between 2.8 and 4.3 V. Electrochemical
results indicate that the full cell capacity fade is predominantly
caused by active lithium loss at the negative electrode. In this contribution,
X-ray photoelectron spectroscopy and inductively coupled plasma-mass
spectrometry analysis confirm the participation of the electrolyte
additive in the solid electrolyte interphase formation on the negative
electrode as well as in the cathode electrolyte interphase formation
on the positive electrode, thus, effectively reducing the active lithium
loss during cycling. Furthermore, the performance of the TPPO additive
is compared to literature known electrolyte additives including triphenylphosphine,
vinylene carbonate, and diphenyl carbonate demonstrating the outstanding
working ability of TPPO in graphite/NMC811 cells