Origin of Superconductivity in Boron-doped Diamond

Superconductivity of boron-doped diamond, reported recently at T_c=4 K, is investigated exploiting its electronic and vibrational analogies to MgB2. The deformation potential of the hole states arising from the C-C bond stretch mode is 60% larger than the corresponding quantity in MgB2 that drives its high Tc, leading to very large electron-phonon matrix elements. The calculated coupling strength \lambda ~ 0.5 leads to T_c in the 5-10 K range and makes phonon coupling the likely mechanism. Higher doping should increase T_c somewhat, but effects of three dimensionality primarily on the density of states keep doped diamond from having a T_c closer to that of MgB2.Comment: Four pages with two embedded figures, corrected fig1. (To appear in Physical Review Letters(2004)

A Multi-Factor Analysis of AREIT Returns

Since 1990, the Australian Real Estate Investment Trust (AREIT) sector has experienced substantial growth and popularity. While the AREIT sector had benefit from the increased flow of funds from institutional investors during the 1997 Asian financial crisis, the recent impact of the 2008 global financial crisis has been a negative one. In this paper, we examine the sensitivities of annualised AREIT returns against a set of seven firm-specific variables and four market-wide risk variables. Balanced and unbalanced panel regressions are conducted on three sub-periods during 1990 - 2008 corresponding to the major phases in evolution of the AREIT sector. Our regression results find that size has a negative impact on returns, and this effect has been diminishing over time. Overall market risk was also found to be significant and positive only since 2003, suggesting that recently AREITs behave more like stocks and less like defensive assets. The relationship with exchange rate risk has been positive in recent years, due to more AREITs choosing to diversify internationally, particularly in the U.S. property markets. Our findings on the relationship between market-to-book ratios and AREIT returns depart from standard finance literature. In comparison to REITs in other countries, AREITs have shifted their preferences away from property-type diversification and into more specialised investment strategies. We also find contrasting evidence on the impact of international diversification, and that domestic AREITs provide better returns than internationally diversified counterparts. The relationship between returns and short term interest rates was found to be positive and significant prior to 2002, and the relationship with long-term interest rates was found to be negative and significant since 2003, suggesting that AREITs exhibit less bond-like characteristics in the past five years.AREITs, AREIT returns, Property-type diversification, International diversification, Panel regressions

Are We That Map?

The aim of Are We That Map? was to co-develop participatory map-making workshops that actively includes and engages children and young people with a lived experience of learning disabilities/difficulties (LD/D). The project was a partnership between Newham based Rosetta Arts, purpleSTARS, RIX Centre, University of East London (UEL) and Living Maps Network. Employing a creative, iterative approach we developed workshops that would be explorative and happy to embrace the unknown. We aimed to develop a series of exercises that could ‘wake us up’ to notice how our bodies' sensory experiences create our own unique experience of the world and how we could share this making a map. This work feeds into Living Maps Young Citizens Atlas. Working together in a unique collaboration, we devised, delivered, reviewed and refined a Map Making workshop package in which people with the lived experience of Learning Difficulties and Differences LD/D developed and facilitated, working to their strengths alongside other expert artists and educators. A co-production approach was used, that included people with a lived experience of a LD/D during the development workshops and as facilitators during workshops in school. Following a robust series of development workshops, we carefully designed, prepared and identified possible activities to include in the Map Making workshop package. We invited members from the Tower Project that supports people with LD/D in Tower Hamlets London to help develop and test our Map Making workshop activities to see what would work and what would not

Aging to Equilibrium Dynamics of SiO2

Molecular dynamics computer simulations are used to study the aging dynamics of SiO2 (modeled by the BKS model). Starting from fully equilibrated configurations at high temperatures T_i =5000K/3760K the system is quenched to lower temperatures T_f=2500K, 2750K, 3000K, 3250K and observed after a waiting time t_w. Since the simulation runs are long enough to reach equilibrium at T_f, we are able to study the transition from out-of-equilibrium to equilibrium dynamics. We present results for the partial structure factors, for the generalized incoherent intermediate scattering function C_q(t_w, t_w+t), and for the mean square displacement msd(t_w,t_w+t). We conclude that there are three different t_w regions: (I) At very short waiting times, C_q(t_w, t_w+t) decays very fast without forming a plateau. Similarly msd(t_w,t_w+t) increases without forming a plateau. (II) With increasing t_w a plateau develops in C_q(t_w, t_w+t) and msd(t_w,t_w+t). For intermediate waiting times the plateau height is independent of t_w and T_i. Time superposition applies, i.e. C_q=C_q(t/t_r) where t_r=t_r(t_w) is a waiting time dependent decay time. Furthermore C_q=C(q,t_w,t_w+t) scales as C_q=C(q,z(t_w,t) where z is a function of t_w and t only, i.e. independent of q. (III) At large t_w the system reaches equilibrium, i.e. C_q(t_w,t_w+t) and msd(t_w,t_w+t) are independent of t_w and T_i. For C_q(t_w,t_w+t) we find that the time superposition of intermediate waiting times (II) includes the equilibrium curve (III).Comment: 9 pages, 11 figures, submission to PR

Advanced ceramic coating development for industrial/utility gas turbine applications

The effects of ceramic coatings on the lifetimes of metal turbine components and on the performance of a utility turbine, as well as of the turbine operational cycle on the ceramic coatings were determined. When operating the turbine under conditions of constant cooling flow, the first row blades run 55K cooler, and as a result, have 10 times the creep rupture life, 10 times the low cycle fatigue life and twice the corrosion life with only slight decreases in both specific power and efficiency. When operating the turbine at constant metal temperature and reduced cooling flow, both specific power and efficiency increases, with no change in component lifetime. The most severe thermal transient of the turbine causes the coating bond stresses to approach 60% of the bond strengths. Ceramic coating failures was studied. Analytic models based on fracture mechanics theories, combined with measured properties quantitatively assessed both single and multiple thermal cycle failures which allowed the prediction of coating lifetime. Qualitative models for corrosion failures are also presented

Cryogenic-coolant He-4-superconductor interaction

The thermodynamic and thermal interaction between a type 2 composite alloy and cryo-coolant He4 was studied with emphasis on post quench phenomena of formvar coated conductors. The latter were investigated using a heater simulation technique. Overall heat transfer coefficients were evaluated for the quench onset point. Heat flux densities were determined for phenomena of thermal switching between a peak and a recovery value. The study covered near saturated liquid, pressurized He4, both above and below the lambda transition, and above and below the thermodynamic critical pressure. In addition, friction coefficients for relative motion between formvar insulated conductors were determined

AREIT returns from 1990-2008: A multi-factor approach

Australian Real Estate Investment Trusts (AREITs) have experienced substantial growth and popularity since 1993. Amongst the major themes surrounding this sector during this time, were the increased attention from institutional investors, the trend towards and away from property-type diversification, significant merger and acquisition activities which led to increased trust size, the debate between internally versus externally managed trust structures, increased gearing levels, and the focus towards diversification into international property assets. While the AREIT sector had benefit from the increased flow of funds from institutional investors during the 1997 Asian financial crisis, the recent impact of the 2008 global financial crisis has been a negative one, as increased credit margins meant that AREITs found it harder to access capital. Our paper aims to study the sensitivities of annualised AREIT returns from 1990 – 2008 towards a set of seven firm-specific variables and five market-wide risk variables. In particular, we examine the time-varying and cross-sectional differences between the impact of firm size, the degree of leverage, market-to-book ratios, property-type diversification, international diversification, the proportion of institutional investment, and management structure. Our set of market time-varying market risk indicators include, overall Australian market conditions proxied using the S&P/ASX200 Index, yields on 90-day bank Treasury Notes to represent the short-term interest rate, yields on10-year Treasury Bonds to represent the long-term interest rate, and changes to the USD/AUD exchange rate to represent exchange rate risk components. We apply panel regressions for fixed and group effects onto balanced and unbalanced panels, categorised according to three sub-periods to study the major phases of the evolution of the AREIT sector. Our regression results find that the size effect has had a negative impact of returns, but this effect has been diminishing over time. Overall market risk was found to be significant and positive only since 2003, suggesting that more recently, AREITs behave more like stocks and less like defensive assets. Additionally, the relationship with exchange rate risks has been positive in recent years, due to more AREITs choosing to diversify internationally, particularly in the U.S. property markets. Our findings on the relationship between market-to-book ratios and AREIT returns depart from standard finance literature. It appears that the market places a premium on AREITs with higher market-to-book ratios. Compared to REITs in other countries, earlier preference for AREITs diversified across property types have appears to shift towards greater specialisation. We also find contrasting evidence on the impact of international diversification, and that domestic AREITs provided better returns than internationally diversified counterparts. This may be largely due to the fact that the AREITs classified as internationally diversified, primarily held assets in the U.S. rather than from a range of countries. We suggest that perhaps the difficulties in accessing economies of scale in the management of such off-shore properties have precluded these AREITs from holding a more geographically diversified property portfolio. The sensitivities of AREIT returns towards short-term and long-term interest rates also warrant further investigation. Our results are similar to another recent Australian study, but inconsistent with much of the existing literature. The relationship between returns and short term interest rates was found to be positive and significant before 2002, and the relationship with long-term interest rates was found to be negative and significant since 2003, indicating that AREITs exhibit less bond-like characteristics in the past five years

Sympatric prey responses to lethal top-predator control: predator manipulation experiments

Introduction: Many prey species around the world are suffering declines due to a variety of interacting causes such as land use change, climate change, invasive species and novel disease. Recent studies on the ecological roles of top-predators have suggested that lethal top-predator control by humans (typically undertaken to protect livestock or managed game from predation) is an indirect additional cause of prey declines through trophic cascade effects. Such studies have prompted calls to prohibit lethal top-predator control with the expectation that doing so will result in widespread benefits for biodiversity at all trophic levels. However, applied experiments investigating in situ responses of prey populations to contemporary top-predator management practices are few and none have previously been conducted on the eclectic suite of native and exotic mammalian, reptilian, avian and amphibian predator and prey taxa we simultaneously assess. We conducted a series of landscape-scale, multi-year, manipulative experiments at nine sites spanning five ecosystem types across the Australian continental rangelands to investigate the responses of sympatric prey populations to contemporary poison-baiting programs intended to control top-predators (dingoes) for livestock protection. Results: Prey populations were almost always in similar or greater abundances in baited areas. Short-term prey responses to baiting were seldom apparent. Longer-term prey population trends fluctuated independently of baiting for every prey species at all sites, and divergence or convergence of prey population trends occurred rarely. Top-predator population trends fluctuated independently of baiting in all cases, and never did diverge or converge. Mesopredator population trends likewise fluctuated independently of baiting in almost all cases, but did diverge or converge in a few instances. Conclusions: These results demonstrate that Australian populations of prey fauna at lower trophic levels are typically unaffected by top-predator control because top-predator populations are not substantially affected by contemporary control practices, thus averting a trophic cascade. We conclude that alteration of current top-predator management practices is probably unnecessary for enhancing fauna recovery in the Australian rangelands. More generally, our results suggest that theoretical and observational studies advancing the idea that lethal control of top-predators induces trophic cascades may not be as universal as previously supposed

Diffuse flow environments within basalt- and sediment-based hydrothermal vent ecosystems harbor specialized microbial communities

Hydrothermal vents differ both in surface input and subsurface geochemistry. The effects of these differences on their microbial communities are not clear. Here, we investigated both alpha and beta diversity of diffuse flow-associated microbial communities emanating from vents at a basalt-based hydrothermal system along the East Pacific Rise (EPR) and a sediment-based hydrothermal system, Guaymas Basin. Both Bacteria and Archaea were targeted using high throughput 16S rRNA gene pyrosequencing analyses. A unique aspect of this study was the use of a universal set of 16S rRNA gene primers to characterize total and diffuse flow-specific microbial communities from varied deep-sea hydrothermal environments. Both surrounding seawater and diffuse flow water samples contained large numbers of Marine Group I (MGI) Thaumarchaea and Gammaproteobacteria taxa previously observed in deep-sea systems. However, these taxa were geographically distinct and segregated according to type of spreading center. Diffuse flow microbial community profiles were highly differentiated. In particular, EPR dominant diffuse flow taxa were most closely associated with chemolithoautotrophs, and off axis water was dominated by heterotrophic-related taxa, whereas the opposite was true for Guaymas Basin. The diversity and richness of diffuse flow-specific microbial communities were strongly correlated to the relative abundance of Epsilonproteobacteria, proximity to macrofauna, and hydrothermal system type. Archaeal diversity was higher than or equivalent to bacterial diversity in about one third of the samples. Most diffuse flow-specific communities were dominated by OTUs associated with Epsilonproteobacteria, but many of the Guaymas Basin diffuse flow samples were dominated by either OTUs within the Planctomycetes or hyperthermophilic Archaea. This study emphasizes the unique microbial communities associated with geochemically and geographically distinct hydrothermal diffuse flow environments