Turning Brownfields into Jobfields

A handbook for practitioners and citizens on making brownfields development work

Multiconfiguration Time-Dependent Hartree-Fock Treatment of Electronic and Nuclear Dynamics in Diatomic Molecules

The multiconfiguration time-dependent Hartree-Fock (MCTDHF) method is formulated for treating the coupled electronic and nuclear dynamics of diatomic molecules without the Born- Oppenheimer approximation. The method treats the full dimensionality of the electronic motion, uses no model interactions, and is in principle capable of an exact nonrelativistic description of diatomics in electromagnetic fields. An expansion of the wave function in terms of configurations of orbitals whose dependence on internuclear distance is only that provided by the underlying prolate spheroidal coordinate system is demonstrated to provide the key simplifications of the working equations that allow their practical solution. Photoionization cross sections are also computed from the MCTDHF wave function in calculations using short pulses.Comment: Submitted to Phys Rev

Optimization of Advertising Resources over Time: A Strategic Analysis

AMS subject classification: 90B60, 90B50, 90A80.Strategic behaviour has long been a crucial issue for modern corporations. To maximize potential profits and market share, firms are more than willing to invest in sales promotion to boost long term manufacturing output. Knowing that the sales of the firm not only respond to own advertising budgets, but also depend upon rivals’ advertising strategies, oligopolistic firms form part, therefore of a continuous race with reference to non-price competition. Efficient use of investment resources is crucial for business operations and long term strategic success. This paper aims to investigate the key issue of optimization of strategic advertising outlays. By using mathematical modelling techniques, strategic linkages between rival companies are identified and advertising impacts explained. Since advertising influences can persist through time, our discussion extends to explore this fundamental point by constructing a more advanced model to examine into the problems of optimization over time. Empirical data is used to test the predictive power of these models and assess relative efficiencies. All in all, this paper intends to highlight the importance of continuous strategic advertising investment and consequently provides comprehensive insights into the impact of modern advertising functions over time

Conformal invariance in two-dimensional turbulence

Simplicity of fundamental physical laws manifests itself in fundamental symmetries. While systems with an infinity of strongly interacting degrees of freedom (in particle physics and critical phenomena) are hard to describe, they often demonstrate symmetries, in particular scale invariance. In two dimensions (2d) locality often promotes scale invariance to a wider class of conformal transformations which allow for nonuniform re-scaling. Conformal invariance allows a thorough classification of universality classes of critical phenomena in 2d. Is there conformal invariance in 2d turbulence, a paradigmatic example of strongly-interacting non-equilibrium system? Here, using numerical experiment, we show that some features of 2d inverse turbulent cascade display conformal invariance. We observe that the statistics of vorticity clusters is remarkably close to that of critical percolation, one of the simplest universality classes of critical phenomena. These results represent a new step in the unification of 2d physics within the framework of conformal symmetry.Comment: 10 pages, 5 figures, 1 tabl

Electronic structure of the cuprate superconducting and pseudogap phases from spectroscopic imaging STM

We survey the use of spectroscopic imaging scanning tunneling microscopy (SI-STM) to probe the electronic structure of underdoped cuprates. Two distinct classes of electronic states are observed in both the d-wave superconducting (dSC) and the pseudogap (PG) phases. The first class consists of the dispersive Bogoliubov quasiparticle excitations of a homogeneous d-wave superconductor, existing below a lower energy scale E = Delta(0). We find that the Bogoliubov quasiparticle interference (QPI) signatures of delocalized Cooper pairing are restricted to a k-space arc, which terminates near the lines connecting k = +/-(pi/a(0), 0) to k = +/-(0, pi/a(0)). This arc shrinks continuously with decreasing hole density such that Luttinger's theorem could be satisfied if it represents the front side of a hole-pocket that is bounded behind by the lines between k = +/-(pi/a(0), 0) and k = +/-(0, pi/a(0)). In both phases, the only broken symmetries detected for the vertical bar E vertical bar < Delta(0) states are those of a d-wave superconductor. The second class of states occurs proximate to the PG energy scale E = Delta(1). Here the non-dispersive electronic structure breaks the expected 90 degrees-rotational symmetry of electronic structure within each unit cell, at least down to 180 degrees-rotational symmetry. This electronic symmetry breaking was first detected as an electronic inequivalence at the two oxygen sites within each unit cell by using a measure of nematic (C-2) symmetry. Incommensurate non-dispersive conductance modulations, locally breaking both rotational and translational symmetries, coexist with this intra-unit-cell electronic symmetry breaking at E = Delta(1). Their characteristic wavevector Q is determined by the k-space points where Bogoliubov QPI terminates and therefore changes continuously with doping. The distinct broken electronic symmetry states (intra-unit-cell and finite Q) coexisting at E similar to Delta(1) are found to be indistinguishable in the dSC and PG phases. The next challenge for SI-STM studies is to determine the relationship of the E similar to Delta(1) broken symmetry electronic states with the PG phase, and with the E < Delta(0) states associated with Cooper pairing.Publisher PDFPeer reviewe

Strong Spherical Asymptotics for Rotor-Router Aggregation and the Divisible Sandpile

The rotor-router model is a deterministic analogue of random walk. It can be used to define a deterministic growth model analogous to internal DLA. We prove that the asymptotic shape of this model is a Euclidean ball, in a sense which is stronger than our earlier work. For the shape consisting of $n=\omega_d r^d$ sites, where $\omega_d$ is the volume of the unit ball in $\R^d$, we show that the inradius of the set of occupied sites is at least $r-O(\log r)$, while the outradius is at most $r+O(r^\alpha)$ for any $\alpha > 1-1/d$. For a related model, the divisible sandpile, we show that the domain of occupied sites is a Euclidean ball with error in the radius a constant independent of the total mass. For the classical abelian sandpile model in two dimensions, with $n=\pi r^2$ particles, we show that the inradius is at least $r/\sqrt{3}$, and the outradius is at most $(r+o(r))/\sqrt{2}$. This improves on bounds of Le Borgne and Rossin. Similar bounds apply in higher dimensions.Comment: [v3] Added Theorem 4.1, which generalizes Theorem 1.4 for the abelian sandpile. [v4] Added references and improved exposition in sections 2 and 4. [v5] Final version, to appear in Potential Analysi

The Hitting Times with Taboo for a Random Walk on an Integer Lattice

For a symmetric, homogeneous and irreducible random walk on d-dimensional integer lattice Z^d, having zero mean and a finite variance of jumps, we study the passage times (with possible infinite values) determined by the starting point x, the hitting state y and the taboo state z. We find the probability that these passages times are finite and analyze the tails of their cumulative distribution functions. In particular, it turns out that for the random walk on Z^d, except for a simple (nearest neighbor) random walk on Z, the order of the tail decrease is specified by dimension d only. In contrast, for a simple random walk on Z, the asymptotic properties of hitting times with taboo essentially depend on the mutual location of the points x, y and z. These problems originated in our recent study of branching random walk on Z^d with a single source of branching

Fe I Oscillator Strengths for the Gaia-ESO Survey

The Gaia-ESO Public Spectroscopic Survey (GES) is conducting a large-scale study of multi-element chemical abundances of some 100 000 stars in the Milky Way with the ultimate aim of quantifying the formation history and evolution of young, mature and ancient Galactic populations. However, in preparing for the analysis of GES spectra, it has been noted that atomic oscillator strengths of important Fe I lines required to correctly model stellar line intensities are missing from the atomic database. Here, we present new experimental oscillator strengths derived from branching fractions and level lifetimes, for 142 transitions of Fe I between 3526 {\AA} and 10864 {\AA}, of which at least 38 are urgently needed by GES. We also assess the impact of these new data on solar spectral synthesis and demonstrate that for 36 lines that appear unblended in the Sun, Fe abundance measurements yield a small line-by-line scatter (0.08 dex) with a mean abundance of 7.44 dex in good agreement with recent publications.Comment: Accepted for publication in Mon. Not. R. Astron. So

THE IMPACT OF THE 2008 OIL PRICE COLLAPSE ON KUWAIT GDP 2008-2012: AN ESTIMATION BASED ON STOCHASTIC LOGISTICAL METHODS

In this paper we utilize a stochastic differenced logistic process to model the annualized Kuwaiti GNPfor the years2002 to 2012 incorporating the world oil price collapse that occurred in the third quarter of 2008 late 2009 .The fitted stochastic differenced logistic model is then used to investigate the properties and behaviour ofKuwait real GDP given the impact of the 2008 price crash on short run economic growth.The derived stochastic differenced logisticaloutput is shown to be robust in terms of goodness of fit, capturing the jumpeffect of the oil price collapse on the real GDP .This approach is unique in estimating oil price shock effects on the GDP for oil export dependent economies. Finally, the approach delivers robust estimation parameters passing standard diagnostic tests