35 research outputs found
Novel chemoenzymatic oxidation of amines into oximes based on hydrolase-catalysed peracid formation
Get PDFFirst Regioselective Enzymatic Alkoxycarbonylation of Primary Amines. Synthesis of Novel 5'- and 3'-Carbamates of Pyrimidine 3',5'-Diaminonucleoside Derivatives Including BVDU Analogues
Get PDFBut-2-ene-1,4-diamine and But-2-ene-1,4-diol as Donors for Thermodynamically Favored Transaminase and Alcohol Dehydrogenase-Catalyzed Processes
Get PDFFinancial support from MICINN (Project CTQ2013- 44153-P) and the Principado de Asturias (Project FC-15-GRUPIN14-002
Baeyer-Villiger monooxygenase-catalyzed desymmetrizations of cyclobutanones. Application to the synthesis of valuable spirolactones
Get PDFStereoselective amination of racemic sec-alcohols through sequential application of laccases and transaminases
Get PDFSimple and quick preparation of a-thiocyanate ketones in hydroalcoholic media. Access to 5-aryl-2-imino-1,3-oxathiolanes
Get PDFNovel and efficient chemoenzymatic synthesis of D-glucose 6-phosphate and molecular modeling studies on the selective biocatalysis
Get PDFExpanding the regioselective enzymatic repertoire: oxidative mono-cleavage of dialkenes catalyzed by Trametes hirsuta
Get PDFThe first report of a biocatalytic regioselective oxidative monocleavage of dialkenes was successfully achieved employing a cellfree enzyme preparation from Trametes hirsuta at the expense of molecular oxygen. Selected reactions were performed on a preparative scale affording high to excellent conversions and chemoselectivitie
Novel and efficient regioselective enzymatic approach to 3′-, 5′- and 3′,5′-di-O-crotonyl 2′-deoxynucleoside derivatives
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