114 research outputs found
Coexistence of pressure-induced structural phases in bulk black phosphorus: a combined x-ray diffraction and Raman study up to 18 GPa
We report a study of the structural phase transitions induced by pressure in
bulk black phosphorus by using both synchrotron x-ray diffraction for pressures
up to 12.2 GPa and Raman spectroscopy up to 18.2 GPa. Very recently black
phosphorus attracted large attention because of the unique properties of
fewlayers samples (phosphorene), but some basic questions are still open in the
case of the bulk system. As concerning the presence of a Raman spectrum above
10 GPa, which should not be observed in an elemental simple cubic system, we
propose a new explanation by attributing a key role to the non-hydrostatic
conditions occurring in Raman experiments. Finally, a combined analysis of
Raman and XRD data allowed us to obtain quantitative information on presence
and extent of coexistences between different structural phases from ~5 up to
~15 GPa. This information can have an important role in theoretical studies on
pressure-induced structural and electronic phase transitions in black
phosphorus
Single-crystal diffraction at the high-pressure Indo-Italian beamline Xpress at Elettra, Trieste
In this study the first in situ high-pressure single-crystal X-ray diffraction experiments at Xpress, the Indo-Italian beamline of the Elettra synchrotron, Trieste (Italy), are reported. A description of the beamline experimental setup and of the procedures for single-crystal centring, data collection and processing, using diamond anvil cells, are provided. High-pressure experiments on a synthetic crystal of clinoenstatite (MgSiO3), CaCO3 polymorphs and a natural sample of leucophoenicite [Mn7Si3O12(OH)2] validated the suitability of the beamline experimental setup to: (i) locate and characterize pressure-induced phase transitions; (ii) solve ab initio the crystal structure of high-pressure polymorphs; (iii) perform fine structural analyses at the atomic scale as a function of pressure; (iv) disclose complex symmetry and structural features undetected using conventional X-ray sources
Non-intubated surgical lung biopsies in elderly and frail adults-one shot, two targets: a case report
Does morbid obesity influence perioperative outcomes after video-assisted thoracic surgery (VATS) lobectomy for non-small cell lung cancer? Analysis of the Italian VATS group registry
High-temperature and high-pressure behavior of carbonates in the ternary diagram CaCO3-MgCO3-FeCO3
We report the thermal expansion and the compressibility of carbonates in the ternary compositional diagram CaCO3-MgCO3-FeCO3, determined by in situ X-ray powder and single-crystal diffraction. High-temperature experiments were performed by high-resolution X-ray synchrotron powder diffraction from ambient to decarbonation temperatures (25-850 \ub0C). Single-crystal synchrotron X ray diffraction experiments were performed in a variable pressure range (0-100 GPa), depending on the stability field of the rhombohedral structure at ambient temperature, which is a function of the carbonate composition. The thermal expansion increases from calcite, CaCO3, \u3b10 = 4.10(7)
710-5 K-1, to magnesite, MgCO3, \u3b10 = 7.04(2)
710-5 K-1. In the magnesite-siderite (FeCO3) join, the thermal expansion decreases as iron content increases, with an experimental value of \u3b10 = 6.44(4)
710-5 K-1 for siderite. The compressibility in the ternary join is higher (i.e., lower bulk modulus) in calcite and Mg-calcite [K0 = 77(3) GPa for Ca0.91Mg0.06Fe0.03(CO3)] than in magnesite, K0 = 113(1) GPa, and siderite, K0 = 125(1) GPa. The analysis of thermal expansion and compressibility variation in calcite-magnesite and calcite-iron-magnesite joins clearly shows that the structural changes associated to the order-disorder transitions [i.e., R3c calcite-type structure vs. R3 CaMg(CO3)2 dolomite-type structure] do not affect significantly the thermal expansion and compressibility of carbonate. On the contrary, the chemical compositions of carbonates play a major role on their thermo-elastic properties. Finally, we use our P-V-T equation of state data to calculate the unit-cell volume of a natural ternary carbonate, and we compare the calculated volumes to experimental observations, measured in situ at elevated pressure and temperatures, using a multi-anvil device. The experimental and calculated data are in good agreement demonstrating that the equation of state here reported can describe the volume behavior with the accuracy needed, for example, for a direct chemical estimation of carbonates based on experimental unit-cell volume data of carbonates at high pressures and temperatures
Three-year findings of an early lung cancer detection feasibility study with low-dose spiral computed tomography in heavy smokers
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