Permeability Structure of the Lava-Dike Transition of 15 My Old Oceanic Crust Formed at the East Pacific Rise

The permeability structure of oceanic crust controls both the spatial and temporal extent of hydrothermal circulation, but the detailed geometry of fractures in seafloor rocks is not well known. We apply an equivalent channel model to veins, joints, faults, and breccias preserved in recovered cores from ODP-IODP Hole 1256D to calculate paleo-permeability. In the ~250 m transition between dikes and lavas, paleo-permeability is 10-13~10-14 m2 with narrow zones of >10-9 m2 that presumably act as conduits for the largest volume of fluids. Most of these high permeability zones are oriented vertically as a result of diking events into a significant thickness of lavas outside of the neovolcanic zone. After an increase in permeability due to off-axis diking events, fluid temperatures drop, pathways are sealed, and the permeability of the upper oceanic crust drops significantly

Primary and authigenic minerals in serpentine soils under temperate climate conditions: source or trap for potentially toxic elements (PTEs)

In this study, we have analysed the mineralogy and the crystal chemistry of serpentine soils from ultramafic rocks of the metaophiolitic Voltri Massif (Liguria, Italy), in order to determine the primary and authigenic mineral species controlling the distribution and the mobility of PTEs during pedogenic processes. These serpentine soils were characterised by PTEs contents commonly exceeding the concentration limits laid down by environmental agencies, particularly for Cr (1200-2500 mg/kg) and Ni (1000-4200 mg/kg). With these hazardous PTEs concentrations, the knowledge of the distribution of PTEs-bearing minerals is of paramount importance for understanding their origin and their fate during the development of serpentine soil profiles and can allow to evaluate their effective bioavailability. All the studied soil profiles were restricted in depth (10-50 cm) and showed a low degree of maturity with weakly developed A-C horizons. Soil samples were subdivided into three aliquots in order to separate the soil skeleton (2 mm-63 \u3bc m) from the silt (63-2 \u3bc m) and clay fraction (<2 \u3bc m). Quantitative mineralogical analyses were performed in all aliquots by using XRPD data collected with synchrotron sources at the MCX beamline (ELETTRA - Synchrotron, Trieste, Italy) and refined with EXP-GUI GSAS software. Trace metals were determined with energy and wavelength electron microscopy. The mineralogy of the coarse and silty fractions was closely related to bedrock mineralogy. The following minerals were detected in decreasing order of abundance: antigorite, chlorite, tremolite, magnetite, Cr-rich spinel, chrysotile, ilmenite, clinopyroxenes, olivine. Allochthonous quartz and albite were always present as minor to trace constituents. The clay fraction was mainly composed by Fe-oxides and -oxyhydroxides (mainly hematite and goethite) with subordinate amounts of mixed-layer clay minerals (chlorite-smectite, chlorite-vermiculite). These authigenic secondary minerals were characterised by poor crystallinity, intimate intergrowths, and fine-scale heterogeneities. PTEs were hosted mainly in the residual primary minerals deriving from the underlying parent material and subordinately in secondary authigenic phases. Cr was mainly contained within spinels (magnetite, Cr-magnetite, ferrichromite, picotite, and hercynite), antigorite, diopside and augite. Nonnegligible amounts of Cr was also present in authigenic hematite (up to 0.1 wt%) and goethite (up to 0.15 wt%). The main Ni-bearing minerals were olivine and antigorite but significant Ni concentration was also detected in authigenic hematite (up to 2.8 wt%) and goethite (up to 4.2 wt%) which thus represented effective traps for Ni leached through mineral weathering to the soils solution. These results are the preliminary step for the evaluation of the role of mineral species in controlling the PTEs mobility during the evolution of serpentine soil profiles. Quantitative mineralogical data will be further used to perform mass balance calculations as well as to interpret and model the results of batch leaching experiments that will be conducted on the different soil fractions

Potentially Toxic Elements in Ultramafic Soils: A Study from Metamorphic Ophiolites of the Voltri Massif (Western Alps, Italy)

Ultramafic soils are characterized by severe edaphic conditions induced by a low content of essential nutrients, an adverse Ca/Mg ratio, a low water-holding capacity, and high contents of geogenic potentially toxic elements (PTEs), in particular Cr, Ni, and Co. These metals commonly exceed the content limits set by environmental agencies and governments, representing serious environmental risks for ecosystems and human health. In alpine environments, ultramafic soils are characterized by modest thickness and poor horizon differentiation. Several studies on ultramafic soils have shown that their properties may be directly related to the characteristics of the parent rocks, but most of these studies deal with soil chemistry, metal availability, isotopic composition, and pedological characterization. The aim of this research is to investigate how much the geotectonic characteristics of ultramafic bedrocks, such as the degree of serpentinization, metamorphic imprint, and deformation, may affect the mineralogical and chemical variations of ultramafic soils, including the occurrence and potential mobility of the PTEs. Using a multiscale and multi-analytical approach, we fully characterize the properties and mineralogical composition of soil profiles with different ultramafic parent rocks, i.e., partially serpentinized peridotite, massive serpentinites, and foliated serpentinites, sampled within the Voltri Massif High Pressure\u2013 Low Temperature (HP\u2013LT) metaophiolite (Western Alps, Italy). Our results, related to soils located at comparable latitude, altitude, landscape position, and pedological environment, outline that the degree of serpentinization, the metamorphic imprint, and the deformation history of the ultramafic parent rocks are key factors influencing soil evolution, mineralogy, and chemistry, as well as PTEs distribution and mobility. Moreover, this study shows that the high content of Cr, Ni, and Co in the studied ultramafic soils has to be considered of geogenic origin and highlights the need for new approaches and methods to obtain indications on the potential contamination of natural or anthropogenic soils

Multi-stage reactive formation of troctolites in slow-spreading oceanic lithosphere (Erro-Tobbio, Italy): a combined field and petrochemical study

partially_open5Many recent studies have investigated the replacive formation of troctolites from mantle protoliths and the compositional evolution of the percolating melt during melt-rock interaction processes. However, strong structural and geochemical constraints for a replacive origin have not yet been established. The Erro-Tobbio impregnated mantle peridotites are primarily associated with a hectometre-size troctolitic body and crosscutting gabbroic dikes, providing a good field control on melt-rock interaction processes and subsequent magmatic intrusions. The troctolitic body exhibits high inner complexity, with a host troctolite (Troctolite A) crosscut by a second generation of troctolitic metre-size pseudo-tabular bodies (Troctolite B). The host Troctolite A is characterized by two different textural types of olivine, corroded deformed millimetre- to centimetre-size olivine and fine-grained rounded undeformed olivine, both embedded in interstitial to poikilitic plagioclase and clinopyroxene. Troctolite A shows melt-rock reaction microstructures indicative of replacive formation after percolation and impregnation of mantle dunites by a reactive melt. The evolution of the texture and Crystallographic Preferred Orientation (CPO) of olivine are correlated and depend on the melt/rock ratio involved in the impregnation process. A low melt/rock ratio allows the preservation of the protolith structure, whereas a high melt/rock ratio leads to the disaggregation of the pre-existing matrix. The mineral compositions in Troctolite A define reactive trends, indicative of the buffering of the melt composition by assimilation of olivine during impregnation. The magmatic Troctolite B bodies are intruded within the pre-existing Troctolite A and are characterized by extreme textural variations of olivine, from decimetre-size dendritic to fine-grained euhedral crystals embedded in poikilitic plagioclase. This textural variability is the result of olivine assimilation during melt-rock reaction and the correlated increase in the degree of undercooling of the percolating melt. In the late gabbroic intrusions, mineral compositions are consistent with the fractional crystallization of melts modified after the reactive crystallization of Troctolites A and B. The Erro-Tobbio troctolitic body has a multi-stage origin, marked by the transition from reactive to fractional crystallization and diffuse to focused melt percolation and intrusion, related to progressive exhumation. During the formation of the troctolitic body, the melt composition was modified and controlled by assimilation and concomitant crystallization reactions occurring at low melt supply. Similar processes have been described in ultra-slow spreading oceanic settings characterized by scarce magmatic activity.openBasch, Valentin; Rampone, Elisabetta; Crispini, Laura; Ferrando, Carlotta; Ildefonse, Benoit; Godard, MargueriteBasch, Valentin; Rampone, Elisabetta; Crispini, Laura; Ferrando, Carlotta; Ildefonse, Benoit; Godard, Marguerit

Potentially toxic elements distribution in the serpentinized and deformed ultramafic rocks from the Voltri Massif (NW, Italy)

The aim of the work is to assess the role of local-scale lithological, textural, and structural factors in the distribution of potentially toxic elements (PTEs) in different ultramafic rocks from the high-pressure ophiolitic Voltri Massif (Central Liguria, NW Italy). The results evidenced that Cr (up to 4183 ppm), Ni (up to 3900 ppm), and Co (up to 334 ppm) are invariably the PTEs with the highest concentrations; in addition, V, Cu, and Zn are systematically found in non-negligible amounts. Spinel-group minerals (chromium spinel, ferrian chromite, chromium magnetite, and magnetite) are by far the main potential source of the PTEs. Nevertheless, several PTEs are also present within serpentines, olivines, pyroxenes, chlorites, as well as within accessory phases (e.g., ilmenite and Ni-sulphides) and within authigenic minerals formed in the early stages of rock weathering (cryptocrystalline to amorphous Fe-oxides and -oxyhydroxides). The result obtained allowed to evidence that the main factors controlling the PTEs distribution within the rocks resulted to be the serpentinization degree and the deformation style and intensity which, in turn, strictly control the mineral assemblages and the mineral chemistry

Geophysical imaging unveils the largest pull-apart basin in East Antarctica

West Antarctica hosts one of the largest continental rift systems on Earth, the West Antarctic Rift System (WARS) that forms the lithospheric cradle for the West Antarctic Ice Sheet. The WARS is known to have experienced several stages of extension starting with distributed/wide mode extension in the Cretaceous, followed by narrower mode and variably oblique extension in the Cenozoic, the latter potentially triggered by the onset of oceanic seafloor spreading in the Adare Basin (Davey et al., 2016, GRL). However, the extent and impact of Cenozoic extension and transtension within the Transantarctic Mountains sector of East Antarctica is much less well understood. Here we present results from a new project (REGGAE) that by analysing aeromagnetic, aerogravity and land-gravity and bedrock topography images and models provides key new geophysical constraints on the form, extent and kinematics of the largest Cenozoic pull-apart basin recognised so far in East Antarctica, the Rennick Graben (RG). Potential field imaging reveals the extent of part of a Jurassic tholeiitic Large Igneous Province preserved within the RG and helps delineate the inherited structural architecture of the underlying Ross-age basement in northern Victoria Land, including highly magnetic arc basement in the northern Wilson Terrane and the subglacial extent of a thrust fault belt located between the western flank of the RG and the eastern margin of Wilkes Subglacial Basin (WSB). We show that the RG is a major composite right-lateral pull-part basin that extends from the Oates Coast to the Southern Cross Mountains crustal block and propose that it is kinematically connected with both the western edge of the WARS and the eastern margin of the WSB. More cryptic evidence for an earlier phase of left-lateral strike slip deformation is also emerging from our recent geological field work in the study region and relatively subtle offsets in aeromagnetic anomaly patterns. Our findings suggest that the RG is part of a distributed region of the continental lithosphere in East Antarctica that was preferentially deformed in response to Cenozoic transtensional stresses that likely also facilitated propagation of accelerated oceanic transform faulting in the adjacent oceanic lithosphere located between southeastern Australia and Tasmania

Mapping Listvenite Occurrences in the Damage Zones of Northern Victoria Land, Antarctica Using ASTER Satellite Remote Sensing Data

Listvenites normally form during hydrothermal/metasomatic alteration of mafic and ultramafic rocks and represent a key indicator for the occurrence of ore mineralizations in orogenic systems. Hydrothermal/metasomatic alteration mineral assemblages are one of the significant indicators for ore mineralizations in the damage zones of major tectonic boundaries, which can be detected using multispectral satellite remote sensing data. In this research, Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) multispectral remote sensing data were used to detect listvenite occurrences and alteration mineral assemblages in the poorly exposed damage zones of the boundaries between the Wilson, Bowers and Robertson Bay terranes in Northern Victoria Land (NVL), Antarctica. Spectral information for detecting alteration mineral assemblages and listvenites were extracted at pixel and sub-pixel levels using the Principal Component Analysis (PCA)/Independent Component Analysis (ICA) fusion technique, Linear Spectral Unmixing (LSU) and Constrained Energy Minimization (CEM) algorithms. Mineralogical assemblages containing Fe 2+ , Fe 3+ , Fe-OH, Al-OH, Mg-OH and CO3 spectral absorption features were detected in the damage zones of the study area by implementing PCA/ICA fusion to visible and near infrared (VNIR) and shortwave infrared (SWIR) bands of ASTER. Silicate lithological groups were mapped and discriminated using PCA/ICA fusion to thermal infrared (TIR) bands of ASTER. Fraction images of prospective alteration minerals, including goethite, hematite, jarosite, biotite, kaolinite, muscovite, antigorite, serpentine, talc, actinolite, chlorite, epidote, calcite, dolomite and siderite and possible zones encompassing listvenite occurrences were produced using LSU and CEM algorithms to ASTER VNIR+SWIR spectral bands. Several potential zones for listvenite occurrences were identified, typically in association with mafic metavolcanic rocks (Glasgow Volcanics) in the Bowers Mountains.Comparison of the remote sensing results with geological investigations in the study area demonstrate invaluable implications of the remote sensing approach for mapping poorly exposed lithological units, detecting possible zones of listvenite occurrences and discriminating subpixel abundance of alteration mineral assemblages in the damage zones of the Wilson-Bowers and Bowers-Robertson Bay terrane boundaries and in intra-Bowers and Wilson terranes fault zones with high fluid flow. The satellite remote sensing approach developed in this research is explicitly pertinent to detecting key alteration mineral indicators for prospecting hydrothermal/metasomatic ore minerals in remote and inaccessible zones situated in other orogenic systems around the world

Workshop report: Exploring deep oceanic crust off Hawai‘i

For more than half a century, exploring a complete sequence of the oceanic crust from the seafloor through the Mohorovičić discontinuity (Moho) and into the uppermost mantle has been one of the most challenging missions of scientific ocean drilling. Such a scientific and technological achievement would provide humankind with profound insights into the largest realm of our planet and expand our fundamental understanding of Earth's deep interior and its geodynamic behavior. The formation of new oceanic crust at mid-ocean ridges and its subsequent aging over millions of years, leading to subduction, arc volcanism, and recycling of some components into the mantle, comprise the dominant geological cycle of matter and energy on Earth. Although previous scientific ocean drilling has cored some drill holes into old (> 110 Ma) and young (< 20 Ma) ocean crust, our sampling remains relatively shallow (< 2 km into intact crust) and unrepresentative of average oceanic crust. To date, no hole penetrates more than 100 m into intact average-aged oceanic crust that records the long-term history of seawater–basalt exchange (60 to 90 Myr). In addition, the nature, extent, and evolution of the deep subseafloor biosphere within oceanic crust remains poorly unknown. To address these fundamentally significant scientific issues, an international workshop “Exploring Deep Oceanic Crust off Hawai`i” brought together 106 scientists and engineers from 16 countries that represented the entire spectrum of disciplines, including petrologists, geophysicists, geochemists, microbiologists, geodynamic modelers, and drilling/logging engineers. The aim of the workshop was to develop a full International Ocean Discovery Program (IODP) proposal to drill a 2.5 km deep hole into oceanic crust on the North Arch off Hawai`i with the drilling research vessel Chikyu. This drill hole would provide samples down to cumulate gabbros of mature (∼ 80 Ma) oceanic crust formed at a half spreading rate of ∼ 3.5 cm a−1. A Moho reflection has been observed at ∼ 5.5 km below the seafloor at this site, and the workshop concluded that the proposed 2.5 km deep scientific drilling on the North Arch off Hawai`i would provide an essential “pilot hole” to inform the design of future mantle drilling