Sequence of phase formation in planar metal-Si reaction couples

A correlation is found between the sequence of phase formation in thin-film metal-Si interactions and the bulk equilibrium phase diagram. After formation of the first silicide phase, which generally follows the rule proposed by Walser and Bené, the next phase formed at the interface between the first phase and the remaining element (Si or metal) is the nearest congruently melting compound richer in the unreacted element. If the compounds between the first phase and the remaining element are all noncongruently melting compounds (such as peritectic or peritectoid phases), the next phase formed is that with the smallest temperature difference between the liquidus curve and the peritectic (or peritectoid) point

Shuttle Return-to-Flight IH-108 Aerothermal Test at CUBRC - Flow Field Calibration and CFD

This paper discusses one specific aspect of the Shuttle Retrun-To-Flight IH-108 Aerothermal Test at Calspan-University of Buffalo Research Center (CUBRC), the test flow field calibration. It showed the versatility of the CUBRC Large Energy National Shock Tunnel (LENS) II wind tunnel for an aerothermal test with unique and demanding requirements. CFD analyses were used effectively to extend the test range at the low end of the Mach range. It demonstrated how ground test facility and CFD synergy can be utilitzed iteratively to enhance the confidence in the fedility of both tools. It addressed the lingering concerns of the aerothermal community on use of inpulse facility and CFD analysis. At the conclusion of the test program, members from the NASA Marshall (MSFC), CUBRC and USA (United Space Alliance) Consultants (The Grey Beards) were asked to independently verify the flight scaling data generated by Boeing for flight certification of the re-designed external tank (ET) components. The blind test comparison showed very good results

Potential Predictability of the Monsoon Subclimate Systems

While El Nino/Southern Oscillation (ENSO) phenomenon can be predicted with some success using coupled oceanic-atmospheric models, the skill of predicting the tropical monsoons is low regardless of the methods applied. The low skill of monsoon prediction may be either because the monsoons are not defined appropriately or because they are not influenced significantly by boundary forcing. The latter characterizes the importance of internal dynamics in monsoon variability and leads to many eminent chaotic features of the monsoons. In this study, we analyze results from nine AMIP-type ensemble experiments with the NASA/GEOS-2 general circulation model to assess the potential predictability of the tropical climate system. We will focus on the variability and predictability of tropical monsoon rainfall on seasonal-to-interannual time scales. It is known that the tropical climate is more predictable than its extratropical counterpart. However, predictability is different from one climate subsystem to another within the tropics. It is important to understand the differences among these subsystems in order to increase our skill of seasonal-to-interannual prediction. We assess potential predictability by comparing the magnitude of internal and forced variances as defined by Harzallah and Sadourny (1995). The internal variance measures the spread among the various ensemble members. The forced part of rainfall variance is determined by the magnitude of the ensemble mean rainfall anomaly and by the degree of consistency of the results from the various experiments

Electron beam ablation of materials

The channelspark, a low accelerating voltage, high current electron beam accelerator, has been used for ablation of materials applied to thin film deposition. The channelspark operates at accelerating voltages of 10 to 20 kV with ∼1500 A beam currents. The electron beam ionizes a low-pressure gas fill (10–20 mTorr Ar or N2)N2) to compensate its own space charge, allowing ion focused transport. Ablation of TiN, Si, and fused silica has been studied through several plasma diagnostics. In addition, thin films of SiO2SiO2 have been deposited and analyzed. Strong optical emission from ionized species, persisting for several microseconds, was observed in the electron beam ablated plumes. Free electron temperatures were inferred from relative emission intensities to be between 1.1 and 1.2 eV. Dye-laser-resonance-absorption photography showed Si atom plume expansion velocities from 0.38 to 1.4 cm/μs for several pressures of Ar or N2N2 background gas. A complex, multilobed plume structure was also observed, yielding strong indications that an electron beam instability is occurring, which is dependent upon the conductivity of the target. Nonresonant interferometry yielded line-averaged electron densities from 1.6 to 3.7×1023 m−33.7×1023m−3 near the target surface. Resonant UV interferometry performed on Si neutral atoms generated in the ablation plumes of fused silica targets measured line integrated densities of up to 1.6×1016 cm−2,1.6×1016cm−2, with the total number of ablated silicon neutrals calculated to be in the range 2.0×10152.0×1015 to 5.0×1013.5.0×1013. Electron beam deposited films of fused silica were microscopically rough, with a thickness variation of 7%. The average SiO2SiO2 deposition rate was found to be about 0.66 nm/shot. The electron beam-deposited fused silica films had accurately maintained stoichiometry. Ablated particulate had an average diameter near 60 nm, with a most probable diameter between 40 and 60 nm. For SiO2SiO2 targets, the mass of material ablated in the form of particulate made up only a few percent of the deposited film mass, the remainder being composed of atomized and ionized material. © 1999 American Institute of Physics.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/70186/2/JAPIAU-86-12-7129-1.pd

Variability in size and characteristics of primary care networks in England

Background General practices in England have been encouraged by national policy to work together on a larger scale by creating primary care networks (PCNs). Policy guidance recommended that they should serve populations of 30 000-50 000 people to perform effectively. Aim To describe variation in the size and characteristics of PCNs and their populations. Design and setting Cross-sectional analysis in England. Method Using published information from January 2020, PCNs were identified that contained <30 000, between 30 000-50 000, and >50 000 people. Percentiles were calculated to describe variation in size and population characteristics. PCN composition within each commissioning region was also examined. Results In total, 6758 practices had formed 1250 PCNs. Seven hundred and twenty-six (58%) PCNs had the recommended population of 30 000-50 000 people. Eighty-four (7%) PCNs contained <30 000 people. Four hundred and forty (35%) PCNs contained >50 000 people. Thirty-four (3%) PCNs comprised just one practice and 77 (6%) PCNs contained >10 practices. Some PCNs contained more than double the proportions of older people and people with chronic conditions compared to other PCNs. More than half of the population were from very socioeconomically deprived areas in 172 (14%) PCNs. Only six (4%) of the 135 commissioning regions ensured all PCNs were in the recommended population range. All practices had joined a single PCN in three (2%) commissioning regions. Conclusion More than 40% of the PCNs were not of the recommended size, and there was substantial variation in their composition and characteristics. This high variability between PCNs is a risk to their future performance

Dynamics of electron beam ablation of silicon dioxide measured by dye laser resonance absorption photography

The dynamics of electron beam ablation plumes have been characterized through the application of dye laser resonance absorption photography. The ablation of fused silica by a channelspark electron beam was studied by probing the near-ground state, 3p2 1D−4s 1P03p21D−4s1P0 neutral Si transition at 288.158 nm. Necessary background gases (Ar or N2)N2) were tested at pressures of 15 or 30 mTorr. A two-lobed, Si atom plume shape was discovered that is hydrodynamically more complex than laser ablation plumes. These plumes merge into a single-lobed plume at about 400 ns after the e-beam current pulse rise. Plume front expansion velocities of Si atoms were measured at nearly 1 cm/μs, and are comparable to the expansion of laser ablated metal atom plumes with laser fluences of a few J/cm2. © 1998 American Institute of Physics.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/70034/2/APPLAB-73-18-2576-1.pd

Using Positive Youth Development Constructs to Design a Money Management Curriculum for Junior Secondary School Students in Hong Kong

This paper aims to discuss the relationships between the selected positive youth development constructs and the enhancement of Hong Kong junior secondary school students' money management skills, values, and attitudes. Various issues of money management of adolescents are reviewed. These issues include the need for money management programs for adolescents, the content and coverage of an appropriate money management program, and its relationships with the selected positive youth development constructs. The curriculum units for secondary 3 students are taken as examples to illustrate the design of the program. It is believed that promoting cognitive competence, self-efficacy, and spirituality could be an effective way to enhance students' money management skills, values, and attitudes, thus preparing them better for facing the finance-related issues in life