Optimal conditions and the dynamics of quantum memory for spatial frequency grating resonators

The dynamics of the interaction between microcavities connected to a common waveguide in a multiresonator quantum memory circuit is investigated. Optimum conditions are identified for the use of quantum memory and a dynamic picture of the exchange of energy between different microcavities is obtained

Methodological aspects of fractionation of humus substances

The separation of humus as a nonadditive entity comprising an indefinite multitude of high-molecular substances differing in molecular weight and chemical heterogeneity into homogeneous fractions is discussed, with the developed procedure of fractional dissolution as an example. The problem of humus fractionation is theoretically solvable, but kinetic limitations make it unfeasible under laboratory conditions because of long duration. Epistemological aspects of the problem are discussed. Copyright © 2004 by MAIK "Nauka/Interperiodica" (Russia)

Broadband multiresonator quantum memory-interface

© 2018 The Author(s). In this paper we experimentally demonstrated a broadband scheme of the multiresonator quantum memory-interface. The microwave photonic scheme consists of the system of mini-resonators strongly interacting with a common broadband resonator coupled with the external waveguide. We have implemented the impedance matched quantum storage in this scheme via controllable tuning of the mini-resonator frequencies and coupling of the common resonator with the external waveguide. Proof-of-principal experiment has been demonstrated for broadband microwave pulses when the quantum efficiency of 16.3% was achieved at room temperature. By using the obtained experimental spectroscopic data, the dynamics of the signal retrieval has been simulated and promising results were found for high-Q mini-resonators in microwave and optical frequency ranges. The results pave the way for the experimental implementation of broadband quantum memory-interface with quite high efficiency η > 0.99 on the basis of modern technologies, including optical quantum memory at room temperature

Spectroscopy of cascade multiresonator quantum memory

© 2018, Institution of Russian Academy of Sciences. All rights reserved. We study spectral properties of a cascaded multiresonator microwave quantum memory integrated into a waveguide-resonator system. On the basis of experimental data, we reconstruct the internal parameters of the circuit under study, give estimates of quantum efficiency, and show the possibility of achieving optimal conditions for its realization

EPR, ENDOR and optical spectroscopy of Yb3+ ion in KZnF3 single crystals

© Published by Elsevier Ltd. The paramagnetic center of tetragonal symmetry formed by the Yb3+ ion in the KZnF3 crystal has been studied using methods of EPR, ENDOR and optical spectroscopy. The location of the impurity ion and the structural model of the complex differing from the model of the Yb3+ center in KMgF3 have been established. The empirical scheme of the energy levels of the Yb3+ ion has been found. The parameters of its interaction with the crystal electrostatic field and the hyperfine interaction with ligands of the nearest environment have been determined. The parameters of the crystal field were used for the analysis of the distortions of the crystal lattice in the vicinity of Yb3+. The parameters of the transferred hyperfine interaction have been calculated for the distances between Yb3+ and F- ions of the nearest environment obtained taking into account the found distortions. They are in good agreement with the experimental values

The synthesis of tetracarbonyl derivatives of thiacalix[4]arene in different conformations and their complexation properties towards alkali metal ions

The three conformations of 5,11,17,23-tetra-tert-butyl-25,26,27,28-tetrakis[(benzoyl)methoxy]-2,8,14, 20-tetrathiacalix[4]arene 1: cone, partial cone and 1,3-alternate, were prepared by the treatment of 5,11,17,23-tetra-tert-butyl-2,8,14,20-tetrathiacalix[4]arene-25,26,27,28- tetraol (TCA) with α-bromo acetophenone in the presence of appropriate alkali carbonate M2CO3 (M=Na, K, Cs) as base catalyst in acetonitrile. Structure of the conformers were established by 1H NMR, 1H-1H COSY, 1D NOE, 2D ROESY and X-ray experiments. The alkali cation binding selectivity of the obtained macrocycles was investigated by the ion-pair extraction method. © 2003 Elsevier Science Ltd. All rights reserved

Novel self-assembling system based on resorcinarene and cationic surfactant

Mixed association of calix[4]resorcinarene with ethyl sulfonate groups on the lower rim and dimethylaminomethyl groups on the upper rim (CR) and cationic surfactant 4-aza-1-hexadecyl-azoniabicyclo[2.2.2]octane bromide (DABCO-16) is studied by methods of tensiometry, conductometry, potentiometry and NMR spectroscopy at fixed CR concentration and varied surfactant concentration. Beyond ca. 0.4 mM of DABCO-16, mixed aggregates enriched by CR are proved to be formed due to electrostatic forces, while beyond ca. 5 mM, aggregates enriched by surfactant occur due to the hydrophobic effect. Spectrophotometry monitoring of the solubilization of a hydrophobic dye, Orange OT, demonstrated that only the second type of mixed aggregate enriched by DABCO-16 is capable of binding the organic probe, while the mixed system where the surfactant is a minor component shows no binding capacity towards Orange OT. This finding can be used for the design of nanocontainers with controllable binding/release properties.Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG-geförderten) Allianz- bzw. Nationallizenz frei zugänglich