Resonant X ray photoelectron spectroscopy identification of atomic contributions to valence states

Valence electronic structure is crucial for understanding and predicting reactivity. Valence non resonant Xray photoelectron spectroscopy NRXPS provides a direct method for probing the overall valence electronic structure. However, it is often difficult to separate the varying contributions to NRXPS; for example, contributions of solutes in solvents or functional groups in complex molecules. In this work we show that valence resonant X ray photoelectron spectroscopy RXPS is a vital tool for obtaining atomic contributions to valence states. We combine RXPS with NRXPS and density functional theory calculations to demonstrate the validity of using RXPS to identify atomic contributions for a range of solutes both neutral and ionic and solvents both molecular solvents and ionic liquids . Furthermore, the one electron picture of RXPS holds for all of the closed shell molecules ions studied, although the situation for an open shell metal complex is more complicated. Factors needed to obtain a strong RXPS signal are investigated in order to predict the types of systems RXPS will work best for; a balance of element electronegativity and bonding type is found to be important. Additionally, the dependence of RXPS spectra on both varying solvation environment and varying local covalent bonding is probed. We find that RXPS is a promising fingerprint method for identifying species in solution, due to the spectral shape having a strong dependence on local covalency but a weak dependence on solvation environmen

Broadband multi-wavelength properties of M87 during the 2017 Event Horizon Telescope campaign

High Energy AstrophysicsInstrumentatio

VerSoX B07-B: a high-throughput XPS and ambient pressure NEXAFS beamline at Diamond Light Source

The beamline optics and endstations at branch B of the Versatile Soft X-ray (VerSoX) beamline B07 at Diamond Light Source are described. B07-B provides medium-flux X-rays in the range 45–2200 eV from a bending magnet source, giving access to local electronic structure for atoms of all elements from Li to Y. It has an endstation for high-throughput X-ray photoelectron spectroscopy (XPS) and near-edge X-ray absorption fine-structure (NEXAFS) measurements under ultrahigh-vacuum (UHV) conditions. B07-B has a second endstation dedicated to NEXAFS at pressures from UHV to ambient pressure (1 atm). The combination of these endstations permits studies of a wide range of interfaces and materials. The beamline and endstation designs are discussed in detail, as well as their performance and the commissioning process

Hydrogen isotope separation for fusion power applications

Abstract The invited talk given at MH2014 in Salford ranged over many issues associated with hydrogen isotope separation, fusion machines and the hydrogen/metal systems found in the Joint European Torus (JET) machine located near Oxford. As this sort of talk does not lend itself well to a paper below I have attempted to highlight some of the more pertinent information. After a description of the Active Gas Handling System (AGHS) a brief summary of isotope separation systems is described followed by descriptions of three major projects currently being undertaken by the Tritium Engineering and Science Group (TESG), the upgrade to the Analytical Systems (AN-GC) at the AGH, the construction of a Water Detritiation System (WDS) and a Material Detritiation Facility (MDF). Finally, a review of some of the challenges facing fusion with respect to metal/hydrogen systems is presented