Microstructure and mechanical properties of Spark Plasma Sintered tungsten-copper– zinc composites

Tungsten/Copper (W/Cu) composites, generally used for applications whereby the combination of high heat resistance, high electrical and thermal conductivity and low thermal expansion is required, are suitable for hard working conditions such as intensive electrical sparks, gouging spark erosion, surface melting, welding, material transfer etc. However, the large disparity between the melting point of tungsten (3410 °C) and that of copper (1083 °C) make their production through traditional processes very difficult. Furthermore the difficulty of approaching near theoretical densities even by using liquid phase sintering, due to the negligible mutual solubility of the constituents and high wetting angle of liquid copper on tungsten is quite challenging. In the present work, the densification mechanisms during spark plasma sintering of tungsten/copper and the effect of the addition of zinc on both microstructural and mechanical properties were investigated. Commercially pure tungsten powders were dry mixed with varied amounts of copper (25, 30 and 50 wt.%) with the addition of different weight fractions of zinc (Zn) (5, 10, 15 and 20 wt.%) using a T2F Turbular mixer for 8 h and at a speed of 49 rpm. The blended composite powders were then sintered using spark plasma sintering system (model HHPD-25 from FCT Germany) with varying dwell times, sintering temperatures, pressures and a constant heating rate of 100oC min-1. The sintering of W/Cu was used as a base study prior to the addition of Zn for a better understanding of the interplaying mechanisms. Densification was monitored through the analysis of the recorded punch displacement and the measured density of the sintered samples using Archimedes method. Microstructural evolutions and phase changes were investigated using scanning electron microscope and X-ray diffraction techniques. The effect of Zn addition on the mechanical properties was investigated through hardness, three point bending flexural test and fracture toughness measurements as well as the analysis of fracture surfaces

Who needs a father? South African men reflect on being fathered

The legacy of apartheid and continued social and economic change have meant that many South African men and women have grown up in families from which biological fathers are missing. In both popular and professional knowledge and practice this has been posed as inherently a problem particularly for boys who are assumed to lack a positive male role model. In drawing on qualitative interviews with a group of South African men in which they speak about their understandings of being fathered as boys, this paper makes two key arguments. The first is that contemporary South African discourses tend to pathologize the absence of the biological father while simultaneously undermining the role of social fathers. Yet, this study shows that in the absence of biological fathers other men such as maternal or paternal uncles, grandfathers, neighbours, and teachers often serve as social fathers. Most of the men who participated in this study are able to identify men who - as social rather than biological fathers - played significant roles in their lives. Secondly, we suggest that while dominant discourses around social fatherhood foreground authoritarian and controlling behaviours, there are moments when alternative more nurturing and consultative versions of being a father and/or being fathered are evident in the experiences of this group of men.IS

Pullback attractors of nonautonomous and stochastic multivalued dynamical systems

In this paper we study the existence of pullback global attractors for multivalued processes generated by differential inclusions. First, we define multivalued dynamical processes, prove abstract results on the existence of !-limit sets and global attractors and study their topological properties (compactness, conectedness). Further, we apply the abstract results to nonautonomous differential inclusions of the reaction-diffusion type in which the forcing term can grow polynomially in time, and to stochastic differential inclusions as well

Concentration of antioxidant compounds from calendula officinalis through sustainable supercritical technologies, and computational study of their permeability in skin for cosmetic use

The growing interest in the cosmetic industry in using compounds of natural and sustainable origin that are safe for humans is encouraging the development of processes that can satisfy these needs. Chlorogenic acid (CHA), caffeic acid (CAF) and ferulic acid (FA) are three compounds widely used within the cosmetic industry due to their functionalities as antioxidants, collagen modifiers or even as radiation protectors. In this work, two advanced separation techniques with super-critical CO2 are used to obtain these three compounds from Calendula officinalis, and these are then evaluated using a computational skin permeability model. This model is encompassed by the COSMO-RS model, the calculations of which make it possible to study the behaviour of the compounds in the epidermis. The results show that both CAF and FA are retained in the stratum corneum, while CHA manages to penetrate to the stratum spinosum. These compounds were concentrated by antisolvent fractionation with super-critical CO2 using a Response Surface Methodology to study the effect of pressure and CO2 flow rate. CHA, CAF and FA were completely retained in the precipitation vessel, with concentrations between 40% and 70% greater than in the original extract. The conditions predicted that the optimal overall yield and enrichment achieved would be 153 bar and 42 g/min

Informal Caregiving for Diabetes and Diabetic Complications Among Elderly Americans

Objectives: Little is known regarding the amount of time spent by unpaid caregivers providing help to elderly individuals for disabilities associated with diabetes mellitus (DM). We sought to obtain nationally representative estimates of the time, and associated cost, of informal caregiving provided to the elderly with diabetes, and to determine the complications of DM that contribute most significantly to the subsequent need for informal care. Methods: We estimated multivariable regression models using data from the 1993 Asset and Health Dynamics (AHEAD) Study, a nationally representative survey of people aged 70 or older (N=7,443), to determine the weekly hours of informal caregiving and imputed cost of caregiver time for community-dwelling elderly with and without a diagnosis of DM. Results: Those without DM received an average of 6.1 hours per week of informal care, those with DM taking no medications received 10.5 hours, those with DM taking oral medications received 10.1 hours, and those with DM taking insulin received 14.4 hours of care (P

Measurement differences in the assessment of functional limitations for cognitive impairment classification across geographic locations

Introduction: The measurement of dementia in cross-national contexts relies on the assessment of functional limitations. We aimed to evaluate the performance of survey items on functional limitations across culturally diverse geographic settings. Methods: We used data from the Harmonized Cognitive Assessment Protocol Surveys (HCAP) in five countries (total N = 11,250) to quantify associations between items on functional limitations and cognitive impairment. Results: Many items performed better in the United States and England compared to South Africa, India, and Mexico. Items on the Community Screening Instrument for Dementia (CSID) had the least variability across countries (SD = 0.73 vs. 0.92 [Blessed] and 0.98 [Jorm IQCODE]), but also the weakest associations with cognitive impairment (median odds ratio [OR] = 2.23 vs. 3.01 [Blessed] and 2.75 [Jorm IQCODE]). Discussion: Differences in cultural norms for reporting functional limitations likely influences performance of items on functional limitations and may affect the interpretation of results from substantive studies. Highlights: There was substantial cross-country variation in item performance. Items from the Community Screening Instrument for Dementia (CSID) had less cross-country variability but lower performance. There was more variability in performance of instrumental activities of daily living (IADL) compared to activities of daily living (ADL) items. Variability in cultural expectations of older adults should be taken into account. Results highlight the need for novel approaches to assessing functional limitations

Caregiving for Older Adults with Obesity in the United States

Peer Reviewedhttps://deepblue.lib.umich.edu/bitstream/2027.42/138397/1/jgs14918_am.pdfhttps://deepblue.lib.umich.edu/bitstream/2027.42/138397/2/jgs14918.pd

Role of malnutrition and parasite infections in the spatial variation in children’s anaemia risk in Northern Angola

Anaemia has a significant impact on child development and mortality and is a severe public health problem in most countries in sub-Saharan Africa. Nutritional and infectious causes of anaemia are geographically variable and anaemia maps based on information on the major aetiologies of anaemia are important for identifying communities most in need and the relative contribution of major causes. We investigated the consistency between ecological and individual-level approaches to anaemia mapping, by building spatial anaemia models for children aged ≤15 years using different modeling approaches. We aimed to a) quantify the role of malnutrition, malaria, Schistosoma haematobium and soil-transmitted helminths (STH) for anaemia endemicity in children aged ≤15 years and b) develop a high resolution predictive risk map of anaemia for the municipality of Dande in Northern Angola. We used parasitological survey data on children aged ≤15 years to build Bayesian geostatistical models of malaria (PfPR≤15), S. haematobium, Ascaris lumbricoides and Trichuris trichiura and predict small-scale spatial variation in these infections. The predictions and their associated uncertainty were used as inputs for a model of anemia prevalence to predict small-scale spatial variation of anaemia. Stunting, PfPR≤15, and S. haematobium infections were significantly associated with anaemia risk. An estimated 12.5%, 15.6%, and 9.8%, of anaemia cases could be averted by treating malnutrition, malaria, S. haematobium, respectively. Spatial clusters of high risk of anaemia (>86%) were identified. Using an individual-level approach to anaemia mapping at a small spatial scale, we found that anaemia in children aged ≤15 years is highly heterogeneous and that malnutrition and parasitic infections are important contributors to the spatial variation in anemia risk. The results presented in this study can help inform the integration of the current provincial malaria control program with ancillary micronutrient supplementation and control of neglected tropical diseases, such as urogenital schistosomiasis and STH infection

Luminescence of GaN nanocolumns obtained by photon-assisted anodic etching

GaN nanocolumns with transverse dimensions of about 50 nm were obtained by illumination-assisted anodic etching of epilayers grown by metalorganic chemical vapor deposition on sapphire substrates. The photoluminescence spectroscopy characterization shows that the as-grown bulk GaN layers suffer from compressive biaxial strain of 0.5 GPa. The majority of nanocolumns are fully relaxed from strain, and the room-temperature luminescence is free excitonic. The high quality of the columnar nanostructures evidenced by the enhanced intensity of the exciton luminescence and by the decrease of the yellow luminescence is explained by the peculiarities of the anodic etching processing. © 2003 American Institute of Physics.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/69916/2/APPLAB-83-8-1551-1.pd