Speciation without chromatography: Part I. Determination of tributyltin in aqueous samples by chloride generation, headspace solid-phase microextraction and inductively coupled plasma time of flight mass spectrometry

An analytical procedure was developed for the determination of tributyltin in aqueous samples. The relatively high volatility of the organometal halide species confers suitability for their headspace sampling from the vapour phase above natural waters or leached solid samples. Tributyltin was collected from the sample headspace above various chloride-containing matrices, including HCl, sodium chloride solution and sea-water, by passive sampling using a polydimethylsiloxane/divinylbenzene (PDMS/DVB)-coated solid-phase microextraction (SPME) fiber. Inductively coupled plasma time-of-flight mass spectrometry (ICP-TOFMS) was used for detection following thermal desorption of analytes from the fiber. A detection limit of 5.8 pg ml–1(as tin) was realized in aqueous samples. Method validation was achieved using NRCC PACS-2 (Sediment) certified reference material, for which reasonable agreement between certified and measured values for tributyltin content was obtained

Macular Bioaccelerometers on Earth and in Space

Space flight offers the opportunity to study linear bioaccelerometers (vestibular maculas) in the virtual absence of a primary stimulus, gravitational acceleration. Macular research in space is particularly important to NASA because the bioaccelerometers are proving to be weighted neural networks in which information is distributed for parallel processing. Neural networks are plastic and highly adaptive to new environments. Combined morphological-physiological studies of maculas fixed in space and following flight should reveal macular adaptive responses to microgravity, and their time-course. Ground-based research, already begun, using computer-assisted, 3-dimensional reconstruction of macular terminal fields will lead to development of computer models of functioning maculas. This research should continue in conjunction with physiological studies, including work with multichannel electrodes. The results of such a combined effort could usher in a new era in understanding vestibular function on Earth and in space. They can also provide a rational basis for counter-measures to space motion sickness, which may prove troublesome as space voyager encounter new gravitational fields on planets, or must re-adapt to 1 g upon return to earth

Gradient Echo Quantum Memory for Light using Two-level Atoms

We propose a quantum memory for light that is analogous to the NMR gradient echo. Our proposal is ideally perfectly efficient and provides simplifications to current 3-level quantum memory schemes based on controlled inhomogeneous broadening. Our scheme does not require auxiliary light fields. Instead the input optical pulse interacts only with two-level atoms that have linearly increasing Stark shifts. By simply reversing the sign of the atomic Stark shifts, the pulse is retrieved in the forward direction. We present analytical, numerical and experimental results of this scheme. We report experimental efficiencies of up to 15% and suggest simple realizable improvements to significantly increase the efficiency.Comment: 4 pages, 4 figure

Schubert Polynomials for the affine Grassmannian of the symplectic group

We study the Schubert calculus of the affine Grassmannian Gr of the symplectic group. The integral homology and cohomology rings of Gr are identified with dual Hopf algebras of symmetric functions, defined in terms of Schur's P and Q-functions. An explicit combinatorial description is obtained for the Schubert basis of the cohomology of Gr, and this is extended to a definition of the affine type C Stanley symmetric functions. A homology Pieri rule is also given for the product of a special Schubert class with an arbitrary one.Comment: 45 page

Cluster Production in Quark-Hadron Phase Transition

The problem of cluster formation and growth in first-order quark-hadron phase transition in heavy-ion collisions is considered. Behaving as Brownian particles, the clusters carry out random walks and can encounter one another, leading to coalescence and breakup. A simulation of the process in cellular automaton suggests the possibility of a scaling distribution in the cluster sizes. The experimental determination of the cluster-size distribution is urged as a means to find a clear signature of phase transition.Comment: 12 pages + 1 figure. Report # OITS-517. To be published in Phys. Rev. Lett. 71, xxx (1994

A quantum study of multi-bit phase coding for optical storage

We propose a scheme which encodes information in both the longitudinal and spatial transverse phases of a continuous-wave optical beam. A split detector-based interferometric scheme is then introduced to optimally detect both encoded phase signals. In contrast to present-day optical storage devices, our phase coding scheme has an information storage capacity which scales with the power of the read-out optical beam. We analyse the maximum number of encoding possibilities at the shot noise limit. In addition, we show that using squeezed light, the shot noise limit can be overcome and the number of encoding possibilities increased. We discuss a possible application of our phase coding scheme for increasing the capacities of optical storage devices.Comment: 8 pages, 7 figures (Please email author for a PDF file if the manuscript does not turn out properly

Novel methods of fabrication and metrology of superconducting nanostructures

As metrology extends toward the nanoscale, a number of potential applications and new challenges arise. By combining photolithography with focused ion beam and/or electron beam methods, superconducting quantum interference devices (SQUIDs) with loop dimensions down to 200 nm and superconducting bridge dimensions of the order 80 nm have been produced. These SQUIDs have a range of potential applications. As an illustration, we describe a method for characterizing the effective area and the magnetic penetration depth of a structured superconducting thin film in the extreme limit, where the superconducting penetration depth $lambda$ is much greater than the film thickness and is comparable with the lateral dimensions of the device

The Thermal Memory of Reionization History

The recent measurement by WMAP of a large electron scattering optical depth tau_e = 0.17 +- 0.04 is consistent with a simple model of reionization in which the intergalactic medium (IGM) is ionized at redshift z ~ 15, and remains highly ionized thereafter. Here, we show that existing measurements of the IGM temperature from the Lyman-alpha forest at z ~ 2 - 4 rule out this ``vanilla'' model. Under reasonable assumptions about the ionizing spectrum, as long as the universe is reionized before z = 10, and remains highly ionized thereafter, the IGM reaches an asymptotic thermal state which is too cold compared to observations. To simultaneously satisfy the CMB and forest constraints, the reionization history must be complex: reionization begins early at z >~ 15, but there must have been significant (order unity) changes in fractions of neutral hydrogen and/or helium at 6 < z < 10, and/or singly ionized helium at 4 < z < 10. We describe a physically motivated reionization model that satisfies all current observations. We also explore the impact of a stochastic reionization history and show that a late epoch of (HeII --> HeIII) reionization induces a significant scatter in the IGM temperature, but the scatter diminishes with time quickly. Finally, we provide an analytic formula for the thermal asymptote, and discuss possible additional heating mechanisms that might evade our constraints.Comment: 10 pages, submitted to ApJ, new references, additional discussion on earlier work and partial HeII reionizatio