Managing Saltwater Intrusion and Agricultural Practices along the Boğaçay River, Turkey: Effects from Excavation and Land Source Pollution

Akiner, M.E. and Lačnjevac, C., 2022. Managing saltwater intrusion and agricultural practices along the Boğaçay River, Turkey: Effects from excavation and land source pollution. Journal of Coastal Research, 38(3), 567–577. Coconut Creek (Florida), ISSN 0749-0208. The Boğaçay is a river situated in the Konyaaltı district of Antalya. In 2017, Antalya Metropolitan Municipality implemented a large project in which the river bed was excavated to 1.5 m below sea level. The aquifer is vital for meeting the drinking water needs of the city of Antalya. The goal of this research is to discover the applications that may be made to combat seawater intrusion and nutrient contamination, both of which were brought to the forefront by the Boğaçay Project. In this work, modeling was used to estimate the extent to which agricultural best management practices (BMPs) will be efficient in reducing pollutant load. In BMP modeling with the soil and water assessment tool (SWAT), a decrease of 39%, 38%, and 38% is anticipated in the 5-day biochemical oxygen demand (BOD5), total phosphorus, and total Kjeldahl nitrogen loads, respectively. Sediment accumulated in the channel, and sediment transport occurred on the beach due to coastal erosion. Coastal erosion of up to 25 m was observed from the project's beginning to the present. Substantial land base pollution because of the diffused sources was found. Saltwater intrusion in the Boğaçay River estuary functions as a catalyst in the production of poor odor and appearance, as well as the rapid expansion of algae. The municipality is attempting to remedy this problem by periodic harvesting, which is an overly expensive and ineffective option. Instead, the elevation of the riverbed should be restored to preproject levels to prevent additional environmental and geographic damages

Fast Fourier Transform IR Characterization of Epoxy GY Systems Crosslinked with Aliphatic and Cycloaliphatic EH Polyamine Adducts

The use of fast FT-IR spectroscopy as a sensitive method to estimate a change of the crosslinking kinetics of epoxy resin with polyamine adducts is described in this study. A new epoxy formulation based on the use of polyamine adducts as the hardeners was analyzed. Crosslinking reactions of the different stoichiometric mixtures of the unmodified GY250 epoxy resin with the aliphatic EH606 and the cycloaliphatic EH637 polyamine adducts were studied using mid FT-IR spectroscopic techniques. As the crosslinking proceeded, the primary amine groups in polyamine adduct are converted to secondary and the tertiary amines. The decrease in the IR band intensity of epoxy groups at about 915 cm(-1), as well as at about 3,056 cm(-1), was observed due to process. Mid IR spectral analysis was used to calculate the content of the epoxy groups as a function of crosslinking time and the crosslinking degree of resin. The amount of all the epoxy species was estimated from IR spectra to changes during the crosslinking kinetics of epichlorhydrin

Effects of the acrylic polyol structure and the selectivity of the employed catalyst on the performance of two-component aqueous polyurethane coatings

Two kinds of aqueous acrylic polyols (single step and multi step synthesis type) have been investigated for their performance in the two-component aqueous polyurethane application, by using more selective catalysts. The aliphatic polyfunctional isocyanates based on hexamethylen diisocyanates have been employed as suitable hardeners. The complex of zirconium, commercially known as K-KAT(R)XC-6212, and manganese (III) complexes with mixed ligands based on the derivative of maleic acid have been used as catalysts in this study. Both of the aqueous polyols give good results, in terms of application and hardness, when elevated temperatures and more selective catalysts are applied. A more selective catalyst promotes the reaction between the isocyanate and polyol component. This increases the percentage of urethane bonds and the degree of hardness in the films formed from the two components of aqueous polyurethane lacquers. The polyol based on the single step synthesis route is favourable concerning potlife and hardness. The obtained results show that the performance of the two-component aqueous polyurethane coatings depends on the polymer structure of the polyols as well as on the selectivity of the employed catalyst

Fizičko-hemijska karakterizacija uzoraka vode sa teritorije Rasinskog okruga

The aim of the study was a preliminary examination on water quality (U01-U08) in Rasina area, through the standard physico-chemical parameters: temperature, pH, conductivity, turbidity and total organic matter. All samples were odorless and tasteless. The results for temperature, pH and conductivity were within the values defined by Regulation on the quality of drinking water, except for the pH value of the sample U05. Increased turbidity was observed in the sample U03 (13.5 NTU). On the basis of the results for total organic matter (1.2 to 5.5 mg O2/L) that were within the permissible range, it can be concluded that all the studied samples belong to the first (I) class water quality.Cilj rada bio je preliminarno ispitivanje kvaliteta voda sa područja Rasinskog okruga (U01-U08) određivanjem standardnih fizičko-hemijskih parametara: temperature, pH-vrednosti, provodljivost, mutnoće i ukupne organske materije. Svi uzorci su bili bez mirisa i ukusa. Dobijeni rezultati za temperaturu, pH i provodljivost bili su u okviru vrednosti predviđenih Pravilnikom o kvalitetu vode za piće, osim pH vrednost uzorka U05. Povišena mutnoća zabeležena je u uzorku U03 (13,5 NTU). Na osnovu vrednosti za ukupne organske materije (1,2-5,5 mg O2/L) koje su bile u granicama dozvoljenih može se zaključiti da svi ispitivani uzorci pripadaju vodama prve (I) klase kvaliteta

Characterisation of biocompatible layers of ZrO28%Y2O used in combination with other ceramics to modify the surface of implants

The aim of this study was to deposit multi-functional ZrO28%Y2O3 coating layers using the plasma spray technology and then to characterise such layers. In combination with other biomedical ceramics, this coating is intended for the application in implant surface modification. The examination was focused on the mechanical properties and microstructure layers. Using the atmospheric plasma spraying, duplex ZrO28%Y2O3/Ni22Cr10Al1Y coating system was deposited on the X15Cr13 stainless steel, with two different thicknesses of the bond and ceramic coatings. The microstructure was analysed using an optical microscope, including the assessment of the content of micropores. The morphology of powder particles and ceramic coating surfaces were examined on a scanning electron microscope (SEM). The quality of the ZrO28%Y2O3 layers makes them suitable for the application and combination with other materials to create a system of biomedical or multifunctional coatings

[Characterization of deposited plasma spray nicralcoy2o3 coating layers on almg1 alloy substrates] [Karakterizacija deponovanih slojeva plazma sprej prevlake nicralcoy2o3 na podlogama od legure almg1]

In this paper, analyzed are the effects of the plasma spray distance on the microstructure and mechanical properties of the NiCrAlCoY2O3 coating layers deposited at atmospheric pressure. The microstructure and mechanical properties of the coating layers are under the influence of the interaction of plasma particles (ions and electrons) with powder particles, providing the transfer of velocity and temperature of the plasma particles onto the powder particles. The effect of the interaction is directly dependent on the time the powder particles were present in the plasma which is defined by distance of the plasma gun from the substrate, depending on the granulation of the powder, the melting point and specific gravity. In order to obtain homogeneous and denser coating layers with high adhesion, in the experiment three distances from the substrate were used: 95 mm, 105 mm and 115 mm. The layers were deposited on thin sheets of AlMg1 aluminum thickness of 0.6 mm. Evaluation of mechanical properties of the layers was carried out by examining microhardness using the HV0.1 method and the bond strength by tensile testing. The morphology of the powder particles was examined on the SEM, while the microstructure of the layers was evaluated under a light microscope in accordance with the Pratt Whitney standard. The results of the experiment showed that the distance from the substrate substantially influenced the structure and mechanical properties of the coating layers. The best deposited layers were examined in the system with the ZrO224%MgO ceramic coating, which have proved to be reliable protectionfrom high temperature and abrasive rocket jet fuel

Sprečavanje korozije ploča od mekog čelika potopljenih u morsku vodu ekstraktom ulja nekih prirodnih proizvoda

The hull plates of the ship made of mild steel (MS) are always in contact with sea water are always in contact with aggressive ions such as chloride ions present in sea water.The corrosion resistance of the hull plates of the ship made of mild steel has been investigated by polarization study. Sandalwood oil extract containing 5 g each of Cardamom (disambiguation), Clove (disambiguation), Nutmeg, India Sambrani (loban), Chrysopogon zizanioides, commonly known as vetiver and Camphor was used as corrosion inhibitor along with Trisodium citrate (TSC), sodium dihydrogen phosphate (SDP) and Zn2+. The corrosion resistance was measured in the absence and presence of various inhibitor systems: Trisodium citrate (TSC) 100 ppm+ Zn2+ 50ppm system, sodium dihydrogen phosphate (SDP) 100 ppm+ Zn2+ 50ppm system, Oil coated (3days) MS, Oil coated (3days) MS +TSC 100 ppm+ Zn2+ 50 ppm system and Oil coated (3days) MS +SDP100 ppm+ Zn2+ 50 ppm system were used. It is observed that when mild steel is immersed in SW+TSC 100 ppm+ Zn2+ 50ppm system, the corrosion resistance of MS increases. When mild steel is immersed in SW+ SDP 100 ppm+ Zn2+ 50ppm system, the corrosion resistance of MS increases. When mild steel is immersed in Oil coated (3days) MS in Sea water system, the corrosion resistance of MS increases. When mild steel is immersed in Oil coated (3days) MS in SW+TSC 100 ppm+ Zn2+ 50ppm system, the corrosion resistance of MS increases. When mild steel is immersed in Oil coated (3 days) MS in SW+ SDP 100 ppm+ Zn2+ 50ppm system, the corrosion resistance of MS increases. This is revealed by the fact that there is increase in LPR value and decrease in corrosion current value. The corrosion potential is shifted to anodic side. This indicates that in this inhibitor system, the anodic reaction of metal dissolution is controlled predominantly. This implies that these inhibitor systems may be coated on mild steel surface used as hull plates to prevent corrosion of mild steel in sea water

zaštita opreme od korozije u sistemu za pasterizaciju mleka

In the course of the pasteurization treatment of milk and dairy products the temperature of the technological process is kept at a constant value. The regulation of the temperature is carried out by means of technological water that comes from certain pools cooled to the temperature of 5ºC. the water heated in the process of pasteurization is sent back through steel pipes to the pool where it is cooled to the working temperature. the pools for water cooling are fitted with a bundle of pipes made of plain carbon steel that corrode over the time. the protection of pipes against corrosion is possible to be performed in two ways: by use of inhibitors and by cathodic protection. The application of either method depends on a number of factors. It is cheaper to protect new pipes from corrosion using inhibitors, whereas pipes already attacked by corrosion are more efficiently protected against further corrosion by applying the cathodic protection.U toku postupka pasterizacije mleka i mlečnih proizvoda temperatura tehnološkog procesa održava se na konstantnoj temperaturi. Regulacija temperature se vrši pomoću tehnološke vode koja dolazi iz bazena rashlađena do temperature od 5°C. zagrejana voda iz procesa pasterizacije vraća se cevima u bazen gde se pomoću tečnog amonijaka hladi do radne temperature. U bazenima za hlađenje tehnološke vode nalazi se snop cevi od običnog čelika kroz koji prolazi tečni amonijak, a koje vremenom počinju da korodiraju. Zaštita cevi od korozije je moguća na dva načina: primenom određenih inhibitora korozije i primenom katodne zaštite. Koji će od ova dva načina da bude primenjen zavisi od više faktora. Za nove cevi je jeftinija zaštita od korozije primenom inhibitora. za cevi koje su već u upotrebi ili je kod njih počela korozija, primena katodne zaštite je efikasniji postupak dalje zaštite od korozije

DETEKTOVANJE PODVODNIH METALNIH OBJEKATA POMOĆU VEŠTAČKE INTELIGENCIJE I ZAŠTITA OD KOROZIJE PREDMETA OD MEKOG ČELIKA KORIŠĆENIH U PODVODNOJ STUDIJI-STUDIJA SLUČAJA DEO B-ZAštita od korozije predmeta od mekog čelika korišćenih u podvodnoj studiji

Buried metal objects in sea water may undergo corrosion because of the corrosive ions such as chloride ions present in seawater. However a paint coating may control the corrosion of the metal objects such as robots. Corrosion resistance of mild steel in 3.5 % sodium chloride solution before and after coating with Asian guard red paint has been evaluated by polarization study and AC impedance spectra. In presence of Asian guard red paint, the linear polarization resistance increases, corrosion current decreases, charge transfer resistance increases, double layer capacitance decreases and impedance value increases. That is corrosion resistance of mild steel objects in 3.5 % sodium chloride solution increases after coating with Asian guard red paint

DETEKTOVANJE PODVODNIH METALNIH OBJEKATA POMOĆU VEŠTAČKE INTELIGENCIJE I ZAŠTITA OD KOROZIJE PREDMETA OD MEKOG ČELIKA KORIŠĆENIH U PODVODNOJ STUDIJI-STUDIJA SLUČAJA Deo A-detektovanje podvodnih metalnih objekata pomoću veštačke inteligencije

Due to the importance of underwater exploration in the development and utilization of deep-sea resources, underwater autonomous operation is more and more important to avoid the dangerous high-pressure deep-sea environment. For underwater autonomous operation, the intelligent computer vision is the most important technology. In an underwater environment, weak illumination and low-quality image enhancement, as a pre-processing procedure, is necessary for underwater vision. In this paper, introduced the Deep learning based Underwater Metal object detection using input Image data by using several step to improve the model performance. In this experimentation we are using TURBID dataset 100 images to validate the performance. And also we compare the performance result by given the input images in different validation level. In first input image is initially preprocessed and that images is given to the KFCM-Segmentation. The segmented images are given to the DWT Extraction to extract the features from those images. And finally the Convolution Neural Network (CNN) is used to classify the images to detect the objects. Also this proposed model attained the classification accuracy of 98.83%. This method is much suitable for detect the objects in underwater robotically. Metallic parts of machines of ships or aero planes may submerge in sea water. They may undergo corrosion when they come in contact with sea water which contains 3.5% sodium chloride. This is most commonly responsible for the corrosive nature of the sea water. The robots made of materials such as mild steel may also undergo corrosion when they come in contact with sea water, while is search. If a paint coating is given, it will control the corrosion of these proposed materials. Hence this work is undertaken. Mild steel is coated with Asian guard red paint. Corrosion resistance of mild in3.5% sodium chloride solution is measured before coating and after coating by electrochemical studies such as such as polarization study and AC impedance spectra. The corrosion inhibition efficiency offered by red paint to mild steel in 3.5% sodium chloride is 99.98%