In-situ electrochemical quantification of active sites in Fe-N/C non-precious metal catalysts

The economic viability of low temperature fuel cells as clean energy devices is enhanced by the development of inexpensive oxygen reduction reaction catalysts. Heat treated iron and nitrogen containing carbon based materials (Fe–N/C) have shown potential to replace expensive precious metals. Although significant improvements have recently been made, their activity and durability is still unsatisfactory. The further development and a rational design of these materials has stalled due to the lack of an in situ methodology to easily probe and quantify the active site. Here we demonstrate a protocol that allows the quantification of active centres, which operate under acidic conditions, by means of nitrite adsorption followed by reductive stripping, and show direct correlation to the catalytic activity. The method is demonstrated for two differently prepared materials. This approach may allow researchers to easily assess the active site density and turnover frequency of Fe–N/C catalysts

A catalyst layer optimisation approach using electrochemical impedance spectroscopy for PEM fuel cells operated with pyrolysed transition metal-N-C catalysts

AbstractThe effect of the ionomer to carbon (I/C) ratio on the performance of single cell polymer electrolyte fuel cells is investigated for three different types of non-precious metal cathodic catalysts. Polarisation curves as well as impedance spectra are recorded at different potentials in the presence of argon or oxygen at the cathode and hydrogen at the anode. It is found that a optimised ionomer content is a key factor for improving the performance of the catalyst. Non-optimal ionomer loading can be assessed by two different factors from the impedance spectra. Hence this observation could be used as a diagnostic element to determine the ideal ionomer content and distribution in newly developed catalyst-electrodes. An electrode morphology based on the presence of inhomogeneous resistance distribution within the porous structure is suggested to explain the observed phenomena. The back-pressure and relative humidity effect on this feature is also investigated and supports the above hypothesis. We give a simple flowchart to aid optimisation of electrodes with the minimum number of trials

Fractal analysis of weld defect patterns obtained by radiographic tests

This paper presents a fractal analysis of radiographic patterns obtained from specimens with three types of inserted welding defects: lack of fusion, lack of penetration, and porosity. The study focused on patterns of carbon steel beads from radiographs of the International Institute of Welding (IIW). The radiographs were scanned using a greyscale with 256 levels, and the fractal features of the surfaces constructed from the radiographic images were characterized by means of Hurst, detrended-fluctuation, and minimal-cover analyses. A Karhunen-Loeve transformation was then used to classify the curves obtained from the fractal analyses of the various images, and a study of the classification errors was performed. The obtained results indicate that fractal analyses can be an effective additional tool for pattern recognition of weld defects in radiographic tests.Comment: 7 pages, 2 figures. To appear AIP Conference Proceedings - QNDE 200

How Does a Fundamental String Stretch its Horizon?

It has recently been shown that if we take into account a class of higher derivative corrections to the effective action of heterotic string theory, the entropy of the black hole solution representing elementary string states correctly reproduces the statistical entropy computed from the degeneracy of elementary string states. So far the form of the solution has been analyzed at distance scales large and small compared to the string scale. We analyze the solution that interpolates between these two limits and point out a subtlety in constructing such a solution due to the presence of higher derivative terms in the effective action. We also study the T-duality transformation rules to relate the moduli fields of the effective field theory to the physical compactification radius in the presence of higher derivative corrections and use these results to find the physical radius of compactification near the horizon of the black hole. The radius approaches a finite value even though the corresponding modulus field vanishes. Finally we discuss the non-leading contribution to the black hole entropy due to space-time quantum corrections to the effective action and the ambiguity involved in comparing this result to the statistical entropy.Comment: LaTeX file, 38 pages; v2: minor changes and added reference

Explaining growth in African countries – what matters?

In this work we analyze the role of the traditional determinants of economic growth, pointed by the literature, in African countries in the period between 1950 and 2012, using growth regressions. Due to the specificity and the single nature of each one of these countries, methods that take into account observed and unobserved heterogeneity are used. Results highlight the relevance of the growth rate of the capital stock to economic growth in African countries in the short-run, which is significant in all regressions. The growth rate of the government to GDP ratio is also important in all but one of the regressions in which appears, and its growth is harmful for the growth of GDP per capita in the short-run. On the other hand, variables related to the public debt do not present any relationship with economic growth. Human capital has a positive relationship with economic growth in regressions that do not include public debt. The growth rate of real GDP per capita also depends (negatively) on its past value, i.e., the lower the real GDP per capita the higher will be its growth rate.info:eu-repo/semantics/acceptedVersio

Exploring the value relevance of biological assets and bearer plants: An analysis with IAS 41 Revision

The purpose of this paper is to explore whether a relation exists between share market valuation and the accounting information about bearer plants and biological assets. The focus is supported in the most recent revision of IAS 41 Agriculture. This revision formally introduced the concept of bearer plants, moved them from biological assets to PP&E, and changed their prior measurement by the fair value model to the cost model. Our approach explores the usefulness of these changes under a valuation market approach. Our analysis settles that there is a positive association between share prices and agricultural-related assets. Overall, our results suggest that biological assets are value relevant and reveal that bearer plants are incrementally value relevant after IAS 41 revision. Besides, we envisage that these conclusions are driven by companies in countries where the value add of agriculture, forestry, and fishing as a percentage of the country’s GDP is lower.info:eu-repo/semantics/publishedVersio

Entropy Function for Heterotic Black Holes

We use the entropy function formalism to study the effect of the Gauss-Bonnet term on the entropy of spherically symmetric extremal black holes in heterotic string theory in four dimensions. Surprisingly the resulting entropy and the near horizon metric, gauge field strengths and the axion-dilaton field are identical to those obtained by Cardoso et. al. for a supersymmetric version of the theory that contains Weyl tensor squared term instead of the Gauss-Bonnet term. We also study the effect of holomorphic anomaly on the entropy using our formalism. Again the resulting attractor equations for the axion-dilaton field and the black hole entropy agree with the corresponding equations for the supersymmetric version of the theory. These results suggest that there might be a simpler description of supergravity with curvature squared terms in which we supersymmetrize the Gauss-Bonnet term instead of the Weyl tensor squared term.Comment: LaTeX file, 23 pages; v2: references added; v3: minor addition; v4: minor change