1,669 research outputs found

    Chemical Association via Exact Thermodynamic Formulations

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    It can be fruitful to view two-component physical systems of attractive monomers, A and B, ``chemically'' in terms of a reaction A + B C, where C = AB is an associated pair or complex. We show how to construct free energies in the three-component or chemical picture which, under mass-action equilibration, exactly reproduce any given two-component or ``physical'' thermodynamics. Order-by-order matching conditions and closed-form chemical representations reveal the freedom available to modify the A-C, B-C, and C-C interactions and to adjust the association constant. The theory (in the simpler one-component, i.e., A = B, case) is illustrated by treating a van der Waals fluid.Comment: 15 double-spaced pages (RevTeX), including 1 eps figur

    OH 1720 MHz Masers in Supernova Remnants --- C-Shock Indicators

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    Recent observations show that the OH 1720 MHz maser is a powerful probe of the shocked region where a supernova remnant strikes a molecular cloud. We perform a thorough study of the pumping of this maser and find tight constraints on the physical conditions needed for its production. The presence of the maser implies moderate temperatures (50 -- 125 K) and densities (105cm3\sim 10^5 cm^{-3}), and OH column densities of order 1016cm210^{16} cm^{-2}. We show that these conditions can exist only if the shocks are of C-type. J-shocks fail by such a wide margin that the presence of this maser could become the most powerful indicator of C-shocks. These conditions also mean that the 1720 MHz maser will be inherently weak compared to the other ground state OH masers. All the model predictions are in good agreement with the observations.Comment: 16 pages, 5 Postscript figures (included), uses aaspp4.sty. To appear in the Astrophysical Journa

    Why Do European Venture Capital Companies Syndicate?

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    Financial theory, resource-based theory and access to deal flow are used to explain syndication practices among European venture capital (VC) firms. The desire to share risk and increase portfolio diversification is a more important motive for syndication than the desire to access additional intangible resources or deal flow. Access to resources is, however, more important for non-lead than for lead investors. When resource-based motives are more important, the propensity to syndicate increases. Syndication intensity is higher for young VC firms and for VC firms, specialised in a specific investment stage. Finally, syndication strategies are similar across European countries, but differ from North American strategies

    Thermoelastic Damping in Micro- and Nano-Mechanical Systems

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    The importance of thermoelastic damping as a fundamental dissipation mechanism for small-scale mechanical resonators is evaluated in light of recent efforts to design high-Q micrometer- and nanometer-scale electro-mechanical systems (MEMS and NEMS). The equations of linear thermoelasticity are used to give a simple derivation for thermoelastic damping of small flexural vibrations in thin beams. It is shown that Zener's well-known approximation by a Lorentzian with a single thermal relaxation time slightly deviates from the exact expression.Comment: 10 pages. Submitted to Phys. Rev.
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