307 research outputs found
Structural and doping effects in the half-metallic double perovskite CrWO
he structural, transport, magnetic and optical properties of the double
perovskite CrWO with have been studied. By
varying the alkaline earth ion on the site, the influence of steric effects
on the Curie temperature and the saturation magnetization has been
determined. A maximum K was found for SrCrWO having an almost
undistorted perovskite structure with a tolerance factor . For
CaCrWO and BaCrWO structural changes result in a strong
reduction of . Our study strongly suggests that for the double perovskites
in general an optimum is achieved only for , that is, for an
undistorted perovskite structure. Electron doping in SrCrWO by a
partial substitution of Sr by La was found to reduce both
and the saturation magnetization . The reduction of could be
attributed both to band structure effects and the Cr/W antisites induced by
doping. Band structure calculations for SrCrWO predict an energy gap in
the spin-up band, but a finite density of states for the spin-down band. The
predictions of the band structure calculation are consistent with our optical
measurements. Our experimental results support the presence of a kinetic energy
driven mechanism in CrWO, where ferromagnetism is stabilized by a
hybridization of states of the nonmagnetic W-site positioned in between the
high spin Cr-sites.Comment: 14 pages, 10 figure
Use of Arthropod Rarity for Area Prioritisation: Insights from the Azorean Islands
We investigated the conservation concern of Azorean forest fragments and the entire Terceira Island surface using arthropod species vulnerability as defined by the Kattan index, which is based on species rarity. Species rarity was evaluated according to geographical distribution (endemic vs. non endemic species), habitat specialization (distribution across biotopes) and population size (individuals collected in standardized samples). Geographical rarity was considered at ‘global’ scale (species endemic to the Azorean islands) and ‘regional’ scale (single island endemics)
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