Magnetic field-temperature phase diagram of multiferroic (NH4)2FeCl5??H2O

Owing to their overall low energy scales, flexible molecular architectures, and ease of chemical substitution, molecule-based multiferroics are extraordinarily responsive to external stimuli and exhibit remarkably rich phase diagrams. Even so, the stability and microscopic properties of various magnetic states in close proximity to quantum critical points are highly under-explored in these materials. Inspired by these opportunities, we combined pulsed-field magnetization, first-principles calculations, and numerical simulations to reveal the magnetic field???temperature (B???T) phase diagram of multiferroic (NH4)2FeCl5???H2O. In this system, a network of intermolecular hydrogen and halogen bonds creates a competing set of exchange interactions that generates additional structure in the phase diagram???both in the vicinity of the spin flop and near the 30 T transition to the fully saturated state. Consequently, the phase diagrams of (NH4)2FeCl5???H2O and its deuterated analog are much more complex than those of other molecule-based multiferroics. The entire series of coupled electric and magnetic transitions can be accessed with a powered magnet, opening the door to exploration and control of properties in this and related materials

Sustainability, lean, green and eco-efficiency symbioses

A literature review was conducted aiming at investigating the use of Sustainability, Lean, Green and eco-efficiency concepts, as well as meaningful combinations of those, on the field of Production and Operations Management. The study reports on the scientific papers published in all major journals in the field over the period 2001–2015. A set of 83 papers from 40 journals were selected for further analyzes, aiming at uncovering the existing level of awareness and use of the synergic and symbiotic relationship between Lean Manufacturing and Green Production. The findings show that a modest share of papers, about 30 %, explicitly recognize the Lean-Green joint approach. The same study testifies a clear growth pattern, which is patently reinforced in the last two and a half years, on the number of papers that behold a combined approach towards more efficient and cleaner production activities. The research has highlighted that the Lean-Green link does, in fact, exist and is gaining momentum, but requires further reinforcements from the scientific community, as well as from the companies, to deliver excelled and environmentally sound production systems.FCT Strategic Project PEst2015-2020, reference UID/CEC/00319/2013.info:eu-repo/semantics/publishedVersio