1,919 research outputs found
Dynamic absorption of carbon dioxide on microporous carbons
Adsorption of carbon dioxide on microporous carbon
Analysis of two-dimensional high-energy photoelectron momentum distributions in single ionization of atoms by intense laser pulses
We analyzed the two-dimensional (2D) electron momentum distributions of
high-energy photoelectrons of atoms in an intense laser field using the
second-order strong field approximation (SFA2). The SFA2 accounts for the
rescattering of the returning electron with the target ion to first order and
its validity is established by comparing with results obtained by solving the
time-dependent Schr\"{o}dinger equation (TDSE) for short pulses. By analyzing
the SFA2 theory, we confirmed that the yield along the back rescattered ridge
(BRR) in the 2D momentum spectra can be interpreted as due to the elastic
scattering in the backward directions by the returning electron wave packet.
The characteristics of the extracted electron wave packets for different laser
parameters are analyzed, including their dependence on the laser intensity and
pulse duration. For long pulses we also studied the wave packets from the first
and the later returns.Comment: 12 pages, 10 figure
DNA stabilized silver nanoclusters for ratiometric and visual detection of Hg2+ and its immobilization in hydrogels
The final publication is available at Elsevier via http://dx.doi.org/10.1016/j.bios.2013.04.002." © 2013. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/DNA oligomers are particularly interesting templates for making silver nanoclusters (AgNCs) as different emission colors can be obtained by varying the DNA sequence. Many AgNCs have been used as Hg2+ sensors since Hg2+ induces fluorescence quenching. From an analytical chemistry standpoint, however, these ‘light off’ sensors are undesirable. In this work, taking advantage of the fact that some AgNCs are not as effectively quenched by Hg2+, we design a sensor with AgNCs containing two emission peaks. The red peak is strongly quenched by Hg2+ while the green peak shows a concomitant increase, producing an orange-to-green visual fluorescence transformation. Using this AgNC, we demonstrate ratiometric detection with a detection limit of 4 nM Hg2+. This sensor is further immobilized in a hydrogel matrix and this gel is also capable of detecting Hg2+ with a visual response.University of Waterloo ||
Canadian Foundation for Innovation ||
Natural Sciences and Engineering Research Council ||
Ontario Ministry of Research and Innovation |
Quantitative rescattering theory for laser-induced high-energy plateau photoelectron spectra
A comprehensive quantitative rescattering (QRS) theory for describing the
production of high-energy photoelectrons generated by intense laser pulses is
presented. According to the QRS, the momentum distributions of these electrons
can be expressed as the product of a returning electron wave packet with the
elastic differential cross sections (DCS) between free electrons with the
target ion. We show that the returning electron wave packets are determined
mostly by the lasers only, and can be obtained from the strong field
approximation. The validity of the QRS model is carefully examined by checking
against accurate results from the solution of the time-dependent Schr\"odinger
equation for atomic targets within the single active electron approximation. We
further show that experimental photoelectron spectra for a wide range of laser
intensity and wavelength can be explained by the QRS theory, and that the DCS
between electrons and target ions can be extracted from experimental
photoelectron spectra. By generalizing the QRS theory to molecular targets, we
discuss how few-cycle infrared lasers offer a promising tool for dynamic
chemical imaging with temporal resolution of a few femtoseconds.Comment: 19 pages, 19 figure
Correlation of photobleaching, oxidation and metal induced fluorescence quenching of DNA-templated silver nanoclusters
Few-atom noble metal nanoclusters have attracted a lot of interest due to their potential applications in biosensor development, imaging and catalysis. DNA-templated silver nanoclusters (AgNCs) are of particular interest as different emission colors can be obtained by changing the DNA sequence. A popular analytical application is fluorescence quenching by Hg2+, where d10–d10 metallophilic interaction has often been proposed for associating Hg2+ with nanoclusters. However, it cannot explain the lack of response to other d10 ions such as Zn2+ and Cd2+. In our effort to elucidate the quenching mechanism, we studied a total of eight AgNCs prepared by different hairpin DNA sequences; they showed different sensitivity to Hg2+, and DNA with a larger cytosine loop size produced more sensitive AgNCs. In all the cases, samples strongly quenched by Hg2+ were also more easily photobleached. Light of shorter wavelengths bleached AgNCs more potently, and photobleached samples can be recovered by NaBH4. Strong fluorescence quenching was also observed with high redox potential metal ions such as Ag+, Au3+, Cu2+ and Hg2+, but not with low redox potential ions. Such metal induced quenching cannot be recovered by NaBH4. Electronic absorption and mass spectrometry studies offered further insights into the oxidation reaction. Our results correlate many important experimental observations and will fuel the further growth of this field.University of Waterloo ||
Canadian Foundation for Innovation ||
Ontario Ministry of Research & Innovation ||
Natural Sciences and Engineering Research Council |
Electrical Detection and Magnetic-Field Control of Spin States in Phosphorus-Doped Silicon
Electron paramagnetic resonance of ensembles of phosphorus donors in silicon
has been detected electrically with externally applied magnetic fields lower
than 200 G. Because the spin Hamiltonian was dominated by the contact hyperfine
term rather than by the Zeeman terms at such low magnetic fields, superposition
states and
were formed
between phosphorus electron and nuclear spins, and electron paramagnetic
resonance transitions between these superposition states and or states are observed clearly. A
continuous change of and with the magnetic field was
observed with a behavior fully consistent with theory of phosphorus donors in
silicon.Comment: 6 pages, 5 figure
Hadronic Masses and Regge Trajectories
A comprehensive phenomenological analysis of experimental data and some
theoretical models is presented here (for mesons) to critically discuss how
Regge trajectory parameters depend on flavor. Through analytic continuation of
physical trajectories (obtained from resonance data) into the space like
region, we derive the suppression factor for heavy flavor production. The case
of our D Regge exchange, both for D and production, is considered
in some detail. Good agreement with data is reached confirming that indeed the
slopes of heavier flavors decrease. This result suggests that the confinement
potential has a substantial dependence on the quark masses. In a simple
non-relativistic model, constrained to produce linear Regge trajectories, it is
shown that a linear quark mass dependence is required (in the confinement part
of the potential) in order for the slope to decrease in the appropriate way.Comment: 19 pages, 9 Figures, IV Table
Suggestions for a way forward to further evaluate ageing error for Southern Hemisphere minke whales.
Paper SC/59/O8 provides a very helpful perspective and suggestions to help clarify the use of Antarctic minke whale age data in the commercial and research permit periods. On the basis of the paper, some areas for further work suggest themselves and these are outlined below. We recognise that these involve, in some cases, quite substantial additional work but believe that this will assist considerably in addressing the issues raised inter alia at the JARPA review meeting as well as during past IA sub-committee meetings and allow the valuable analyses involving both commercial and scientific permit data to be undertaken. The second experiment is designed to confirm the proposal in SC/59/O8 to limit analyses to using only data for animals aged six years and over
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