5,211 research outputs found
Large tunable image-charge effects in single-molecule junctions
The characteristics of molecular electronic devices are critically determined
by metal-organic interfaces, which influence the arrangement of the orbital
levels that participate in charge transport. Studies on self-assembled
monolayers (SAMs) show (molecule-dependent) level shifts as well as
transport-gap renormalization, suggesting that polarization effects in the
metal substrate play a key role in the level alignment with respect to the
metal's Fermi energy. Here, we provide direct evidence for an electrode-induced
gap renormalization in single-molecule junctions. We study charge transport in
single porphyrin-type molecules using electrically gateable break junctions. In
this set-up, the position of the occupied and unoccupied levels can be followed
in situ and with simultaneous mechanical control. When increasing the electrode
separation, we observe a substantial increase in the transport gap with level
shifts as high as several hundreds of meV for displacements of a few \aa
ngstroms. Analysis of this large and tunable gap renormalization with
image-charge calculations based on atomic charges obtained from density
functional theory confirms and clarifies the dominant role of image-charge
effects in single-molecule junctions
Eutrophication problems, causes and potential solutions, and exchange of reusable model building components for the integrated simulation of coastal eutrophication. ISECA Final Report D3.2
This report summarizes the stages of coastal and offshore eutrophication, followed by a description of the European indicators and institutional framework for marine eutrophication assessment. A summary is given of a number of biogeochemical models available to describe the process of eutrophication in the North Sea, and the model for atmospheric inputs which was developed in the ISECA project (see the Action 3 Report – Atmospheric Modelling for more details on this work). Furthermore, the report compares different solutions aimed at reducing the nitrogen inputs from the Scheldt basin, using the nitrogen apportionment model which was developed in the EU-FP6 project SPICOSA (www.spicosa.eu). The report is concluded with a discussion on the principles of component-based modelling and model libraries, using examples for the Scheldt model, and a general discussion on some challenges of modelling marine eutrophication
Can remote STI/HIV testing and eClinical Care be compatible with robust public health surveillance?
In this paper we outline the current data capture systems for human immunodeficiency virus (HIV) and sexually transmitted infection (STI) surveillance used by Public Health England (PHE), and how these will be affected by the introduction of novel testing platforms and changing patient pathways. We outline the Chlamydia Online Clinical Care Pathway (COCCP), developed as part of the Electronic Self-Testing for Sexually Transmitted Infections (eSTI(2)) Consortium, which ensures that surveillance data continue to be routinely collected and transmitted to PHE. We conclude that both novel diagnostic testing platforms and established data capture systems must be adaptable to ensure continued robust public health surveillance
Spin separation in digital ferromagnetic heterostructures
In a study of the ferromagnetic phase of a multilayer digital ferromagnetic
semiconductor in the mean-field and effective-mass approximations, we find the
exchange interaction to have the dominant energy scale of the problem,
effectively controlling the spatial distribution of the carrier spins in the
digital ferromagnetic heterostructures. In the ferromagnetic phase, the
majority and minority carriers tend to be in different regions of the space
(spin separation). Hence, the charge distribution of carriers also changes
noticeably from the ferromagnetic to the paramagnetic phase. An example of a
design to exploit these phenomena is given.Comment: 4 pages, 3 figures. Submitted to Phys. Rev.
Surfactant effect in heteroepitaxial growth. The Pb - Co/Cu(111) case
A MonteCarlo simulations study has been performed in order to study the
effect of Pb as surfactant on the initial growth stage of Co/Cu(111). The main
characteristics of Co growing over Cu(111) face, i.e. the decorated double
layer steps, the multiple layer islands and the pools of vacancies, disappear
with the pre-evaporation of a Pb monolayer. Through MC simulations, a full
picture of these complex processes is obtained. Co quickly diffuses through the
Pb monolayer exchanging place with Cu atoms at the substrate. The exchange
process diffusion inhibits the formation of pure Co islands, reducing the
surface stress and then the formation of multilayer islands and the pools of
vacancies. On the other hand, the random exchange also suppress the nucleation
preferential sites generated by Co atoms at Cu steps, responsible of the step
decoration.Comment: 4 pages, latex, 2 figures embedded in the tex
Theory of Diluted Magnetic Semiconductor Ferromagnetism
We present a theory of carrier-induced ferromagnetism in diluted magnetic
semiconductors (III_{1-x} Mn_x V) which allows for arbitrary itinerant-carrier
spin polarization and dynamic correlations. Both ingredients are essential in
identifying the system's elementary excitations and describing their
properties. We find a branch of collective modes, in addition to the spin waves
and Stoner continuum which occur in metallic ferromagnets, and predict that the
low-temperature spin stiffness is independent of the strength of the exchange
coupling between magnetic ions and itinerant carriers. We discuss the
temperature dependence of the magnetization and the heat capacity
Overview of the design of the ITER heating neutral beam injectors
The heating neutral beam injectors (HNBs) of ITER are designed to deliver 16.7MWof 1 MeVD0 or
0.87 MeVH0 to the ITER plasma for up to 3600 s. They will be the most powerful neutral beam\uf0a0(NB)
injectors ever, delivering higher energy NBs to the plasma in a tokamak for longer than any previous
systems have done. The design of the HNBs is based on the acceleration and neutralisation of negative
ions as the efficiency of conversion of accelerated positive ions is so low at the required energy that a
realistic design is not possible, whereas the neutralisation ofH 12 andD 12 remains acceptable ( 4856%).
The design of a long pulse negative ion based injector is inherently more complicated than that of
short pulse positive ion based injectors because:
\u2022 negative ions are harder to create so that they can be extracted and accelerated from the ion source;
\u2022 electrons can be co-extracted from the ion source along with the negative ions, and their
acceleration must be minimised to maintain an acceptable overall accelerator efficiency;
\u2022 negative ions are easily lost by collisions with the background gas in the accelerator;
\u2022 electrons created in the extractor and accelerator can impinge on the extraction and acceleration
grids, leading to high power loads on the grids;
\u2022 positive ions are created in the accelerator by ionisation of the background gas by the accelerated
negative ions and the positive ions are back-accelerated into the ion source creating a massive power
load to the ion source;
\u2022 electrons that are co-accelerated with the negative ions can exit the accelerator and deposit power on
various downstream beamline components.
The design of the ITER HNBs is further complicated because ITER is a nuclear installation which
will generate very large fluxes of neutrons and gamma rays. Consequently all the injector components
have to survive in that harsh environment. Additionally the beamline components and theNBcell,
where the beams are housed, will be activated and all maintenance will have to be performed remotely.
This paper describes the design of theHNBinjectors, but not the associated power supplies, cooling
system, cryogenic system etc, or the high voltage bushingwhich separates the vacuum of the beamline
fromthehighpressureSF6 of the high voltage (1MV) transmission line, through which the power, gas and
coolingwater are supplied to the beam source. Also themagnetic field reduction system is not described
Knee joint stabilization therapy in patients with osteoarthritis of the knee and knee instability: Subgroup analyses in a randomized, controlled trial
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