1,401 research outputs found

    Mechanisms of devitrification of grain boundary glassy phases in Si3N4 materials

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    Changes in the grain boundary (g.b.) phases of Si3N4 are analyzed, the effects of composition and thermal history on devitrification of the g.b. phases are determined, devitrification of the g.b. phases of Si3N are related to mechanical behavior and oxidation sensitivity of the material. The phase relationships that occur within the grain boundaries of Si3N4 containing various densification aids are reviewed. Comparisons of the effects of MgO, Y2O3, CeO2, and Y2O3 + AL2O3 are made in terms of the phase equilibria of the Si3N4 + SiO2 + additive compositional system. Two new equilibrium phase diagrams for the Si3N4-SiO2 and Y2O3 and Si3N4-SiO2-Ce2O3 systems are preented. The effects of Y2O3 vs CeO2 densification aids on the fracture surfaces of Si3N4 are compared. Auger electron spectroscopy shows that both oxides are concentrated within the fracture surface. Scanning electron microscopy shows evidence that Si3N4 with CeO2 formed an intergranular structure of fine grained oxynitride reaction products, as predicted by phase quilibria, whereas the Y2O3 containing sample shows evidence of an intergranular glassy phase

    Ion Beam Sputtered Coatings of Bioglass

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    The ion beam sputtering technique available at the NASA-Lewis was used to apply coatings of bioglass to ceramic, metallic, and polymeric substrates. Experiments in vivo and in vitro described investigate these coatings. Some degree of substrate masking was obtained in all samples although stability and reactivity equivalent to bulk bioglass was not observed in all coated samples. Some degree of stability was seen in all coated samples that were reacted in vitro. Both metallic and ceramic substrates coated in this manner failed to show significantly improved coatings over those obtained with existing techniques. Implantation of the coated ceramic substrate samples in bone gave no definite bonding as seen with bulk glass; however, partial and patchy bonding was seen. Polymeric substrates in these studies showed promise of success. The coatings applied were sufficient to mask the underlying reactive test surface and tissue adhesion of collagen to bioglass was seen. Hydrophilic, hydrophobic, charged, and uncharged polymeric surfaces were successfully coated

    Observations of spatial flow patterns at the coral colony scale on a shallow reef flat

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    Although small-scale spatial flow variability can affect both larger-scale circulation patterns and biological processes on coral reefs, there are few direct measurements of spatial flow patterns across horizontal scales 1), had similarspatial patterns to wakes, while higher-frequency variations (0.05-0.1 Hz, KC<1) had no observable spatial structure. On the reef flat, both drag and inertial forces exerted by coral colonies could have significant effects on flow, but within different frequency ranges; drag dominates for low-frequency flow variations and inertial forces dominate for higher frequency variations, including the wave band. Our scaling analyses suggest that spatial flow patterns at colony and patch scales could have important implications or both physical and biological processes at larger reef scales through their effects on forces exerted on the flow, turbulent mixing, and dispersion. © 2013. American Geophysical Union. All Rights Reserved

    Transient Tidal Circulation and Momentum Balances at a Shallow Inlet

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    An analysis of transient momentum balances is carried out to elucidate circulation, dynamics, and exchange mechanisms at shallow barotropic tidal inlets. Circulation is computed using a depth-integrated, fully nonlinear, time-stepping, finite-element model with variably spaced grids having horizontal resolution down to 50 m. Velocity and elevation fields from the model are used to directly evaluate the contribution of each term in the momentum equations to the overall momentum balance. A transformation of the x-y momentum terms into an s-n coordinate system is used to simplify the interpretation of the dynamics and provide vivid illustrations of the forces and resulting accelerations in the flow. The analysis is conducted for an idealized inlet and contrasted with a highly detailed model of Beaufort Inlet, North Carolina. Results show that momentum balances in the immediate vicinity of these inlets vary significantly in time and space and oscillate between two dynamical states. Near maximum ebb or flood, the alongstream momentum balances are dominated by advective acceleration, pressure gradient, and bottom friction. Cross-stream balances are dominated by centrifugal acceleration and pressure gradients. Near slack, balances more closely follow linear wave dynamics, with local accelerations balancing pressure gradients, and (to a lesser degree) Coriolis. Comparisons between the idealized inlet and Beaufort Inlet show broad similarities in these momentum balances. However, natural inlet geometry and bottom topography, as well as the tidal transmission characteristics of the sounds behind Beaufort Inlet produce strong asymmetries. Moreover, momentum balances are highly localized, often with subkilometer length scales. The dynamics are used to explain the physical mechanisms for inlet exchange. In particular, the results indicate that the cross-stream dynamics generate a ''wall'' along the length of an inlet during the stronger phases of the tide. The wall is established by opposing cross-inlet pressure gradients and centrifugal forces, and it poses a significant barrier to cross-inlet exchange during the stronger phases of the tide but is absent near slack

    High frequency temperature variability reduces the risk of coral bleaching

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    Coral bleaching is the detrimental expulsion of algal symbionts from their cnidarian hosts, and predominantly occurs when corals are exposed to thermal stress. The incidence and severity of bleaching is often spatially heterogeneous within reef-scales (&lt;1 km), and is therefore not predictable using conventional remote sensing products. Here, we systematically assess the relationship between in situ measurements of 20 environmental variables, along with seven remotely sensed SST thermal stress metrics, and 81 observed bleaching events at coral reef locations spanning five major reef regions globally. We find that high-frequency temperature variability (i.e., daily temperature range) was the most influential factor in predicting bleaching prevalence and had a mitigating effect, such that a 1 °C increase in daily temperature range would reduce the odds of more severe bleaching by a factor of 33. Our findings suggest that reefs with greater high-frequency temperature variability may represent particularly important opportunities to conserve coral ecosystems against the major threat posed by warming ocean temperatures
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