637 research outputs found
Evolution of Morphological Integration: Developmental Accommodation of Stress-Induced Variation
Extreme environmental change during growth often results in an increase in developmental abnormalities in the morphology of an organism. The evolutionary significance of such stress-induced variation depends on the recurrence of a stressor and on the degree to which developmental errors can be accommodated by an organism\u27s ontogeny without significant loss of function. We subjected populations of four species of soricid shrews to an extreme environment during growth and measured changes in the patterns of integration and accommodation of stress-induced developmental errors in a complex of mandibular traits. Adults that grew under an extreme environment had lower integration of morphological variation among mandibular traits and highly elevated fluctuating asymmetry in these traits, compared to individuals that grew under the control conditions. However, traits differed strongly in the magnitude of response to a stressor - traits within attachments of the same muscle (functionally integrated traits) had lower response and changed their integration less than other traits. Cohesiveness in functionally integrated complexes of traits under stress was maintained by close covariation of their developmental variation. Such developmental accommodation of stress-induced variation might enable the individual\u27s functioning and persistence under extreme environmental conditions and thus provides a link between individual adaptation to stress and the evolution of stress resistance
Long-Toed Salamanders in Harvested and Intact Douglas-Fir Forests of Western Montana
There is little known about how timber harvest practices have affected terrestrial amphibians in the northern Rocky Mountains. Especially lacking is information on the effects of revised harvest methods that fall within the framework of environmental or New Forestry. We estimated the relative abundance of a common forest amphibian, the long-toed salamander (Ambystoma macrodactylum) captured in pitfall arrays on intact, environmentally harvested, and overstory-removal harvested sites in mixed-conifer forests of western Montana. Pitfall data from 1994 through 1996 showed that previously logged sites contained significantly fewer long-toed salamanders regardless of harvest method used. The number of salamanders captured on intact sites (3.1 salamanders·[array]−1·[100 d]−1) was nearly three times the number captured on logged sites (1.2 salamanders·[array]−1·[100 d]−1). Habitat conditions measured in conjunction with trapping efforts indicated that lower amphibian abundance was associated with decreased numbers of large live trees. Declines in amphibian abundance occurred in the absence of changes in understory vegetation that typically occur when forest canopy is reduced. Our findings suggest that long-toed salamanders responded to changes in the physical environment, probably increased temperatures and decreased moisture. That salamanders should respond so dramatically indicates that immediate changes in physical conditions may profoundly alter habitat quality even when other components of the habitat are unaffected
Ab initio study of alanine polypeptide chains twisting
We have investigated the potential energy surfaces for alanine chains
consisting of three and six amino acids. For these molecules we have calculated
potential energy surfaces as a function of the Ramachandran angles Phi and Psi,
which are widely used for the characterization of the polypeptide chains. These
particular degrees of freedom are essential for the characterization of
proteins folding process. Calculations have been carried out within ab initio
theoretical framework based on the density functional theory and accounting for
all the electrons in the system. We have determined stable conformations and
calculated the energy barriers for transitions between them. Using a
thermodynamic approach, we have estimated the times of characteristic
transitions between these conformations. The results of our calculations have
been compared with those obtained by other theoretical methods and with the
available experimental data extracted from the Protein Data Base. This
comparison demonstrates a reasonable correspondence of the most prominent
minima on the calculated potential energy surfaces to the experimentally
measured angles Phi and Psi for alanine chains appearing in native proteins. We
have also investigated the influence of the secondary structure of polypeptide
chains on the formation of the potential energy landscape. This analysis has
been performed for the sheet and the helix conformations of chains of six amino
acids.Comment: 24 pages, 10 figure
Silicon chemistry in the mesosphere and lower thermosphere
Silicon is one of the most abundant elements in cosmic dust, and meteoric ablation injects a significant amount of Si into the atmosphere above 80 km. In this study, a new model for silicon chemistry in the mesosphere/lower thermosphere is described, based on recent laboratory kinetic studies of Si, SiO, SiO2, and Si+. Electronic structure calculations and statistical rate theory are used to show that the likely fate of SiO2 is a two-step hydration to silicic acid (Si(OH)4), which then polymerizes with metal oxides and hydroxides to form meteoric smoke particles. This chemistry is then incorporated into a whole atmosphere chemistry-climate model. The vertical profiles of Si+ and the Si+/Fe+ ratio are shown to be in good agreement with rocket-borne mass spectrometric measurements between 90 and 110 km. Si+ has consistently been observed to be the major meteoric ion around 110 km; this implies that the relative injection rate of Si from meteoric ablation, compared to metals such as Fe and Mg, is significantly larger than expected based on their relative chondritic abundances. Finally, the global abundances of SiO and Si(OH)4 show clear evidence of the seasonal meteoric input function, which is much less pronounced in the case of other meteoric species
Rotational cooling of heteronuclear molecular ions with ^1-Sigma, ^2-Sigma, ^3-Sigma and ^2-Pi electronic ground states
The translational motion of molecular ions can be effectively cooled
sympathetically to translational temperatures below 100 mK in ion traps through
Coulomb interactions with laser-cooled atomic ions. The ro-vibrational degrees
of freedom, however, are expected to be largely unaffected during translational
cooling. We have previously proposed schemes for cooling of the internal
degrees of freedom of such translationally cold but internally hot
heteronuclear diatomic ions in the simplest case of ^1-Sigma electronic ground
state molecules. Here we present a significant simplification of these schemes
and make a generalization to the most frequently encountered electronic ground
states of heteronuclear molecular ions: ^1-Sigma, ^2-Sigma, ^3-Sigma and ^2-Pi.
The schemes are relying on one or two laser driven transitions with the
possible inclusion of a tailored incoherent far infrared radiation field.Comment: 16 pages, 13 figure
When Reintroductions are Augmentations: The Genetic Legacy of Fishers (Martes Pennanti) in Montana
Fishers (Martes pennanti) were purportedly extirpated from Montana by 1930 and extant populations are assumed to be descended from translocated fishers. To determine the lineage of fisher populations, we sequenced 2 regions of the mitochondrial DNA genome from 207 tissue samples from British Columbia, Minnesota, Wisconsin, and Montana. In northwestern Montana, fishers share haplotypes with samples from the upper Midwest and British Columbia; in west-central Montana, we detected haplotypes found in British Columbia samples, but also detected a control region and cytochrome-b haplotype not found in source populations. Based on the unique haplotypes found in west-central Montana, we propose that individuals with these haplotypes are descended from a relic population. Fishers in northwestern Montana are likely descended from fishers from the Midwest and British Columbia
Impurity effects on the melting of Ni clusters
We demonstrate that the addition of a single carbon impurity leads to
significant changes in the thermodynamic properties of Ni clusters consisting
of more than a hundred atoms. The magnitude of the change induced is dependent
upon the parameters of the Ni-C interaction. Hence, thermodynamic properties of
Ni clusters can be effectively tuned by the addition of an impurity of a
particular type. We also show that the presence of a carbon impurity
considerably changes the mobility and diffusion of atoms in the Ni cluster at
temperatures close to its melting point. The calculated diffusion coefficients
of the carbon impurity in the Ni cluster can be used for a reliable estimate of
the growth rate of carbon nanotubes.Comment: 27 pages, 13 figure
Synthesis of a fullerene-based one-dimensional nanopolymer through topochemical transformation of the parent nanowire
Large-scale practical applications of fullerene (C60) in nanodevices could be
significantly facilitated if the commercially-available micrometer-scale raw
C60 powder were further processed into a one-dimensional (1D) nanowire-related
polymer displaying covalent bonding as molecular interlinks and resembling
traditional important conjugated polymers. However, there has been little study
thus far in this area despite the abundant literature on fullerene. Here we
report the synthesis and characterization of such a C60-based nanowire polymer,
(-C60TMB-)n, where TMB=1,2,4-trimethylbenzene, which displays a well-defined
crystalline structure, exceptionally large length-to-width ratio and excellent
thermal stability. The material is prepared by first growing the corresponding
nanowire through a solution phase of C60 followed by a topochemical
polymerization reaction in the solid state. Gas chromatography, mass
spectrometry and 13C nuclear magnetic resonance evidence is provided for the
nature of the covalent bonding mode adopted by the polymeric chains.
Theoretical analysis based on detailed calculations of the reaction energetics
and structural analysis provides an in-depth understanding of the
polymerization pathway. The nanopolymer promises important applications in
biological fields and in the development of optical, electrical, and magnetic
nanodevices.Comment: 30 pages, 12 figures, 2 table
Further investigation of confirmed urinary tract infection (UTI) in children under five years: a systematic review.
Background: Further investigation of confirmed UTI in children aims to prevent renal scarring and future complications. Methods: We conducted a systematic review to determine the most effective approach to the further investigation of confirmed urinary tract infection (UTI) in children under five years of age. Results: 73 studies were included. Many studies had methodological limitations or were poorly reported. Effectiveness of further investigations: One study found that routine imaging did not lead to a reduction in recurrent UTIs or renal scarring. Diagnostic accuracy: The studies do not support the use of less invasive tests such as ultrasound as an alternative to renal scintigraphy, either to rule out infection of the upper urinary tract (LR- = 0.57, 95%CI: 0.47, 0.68) and thus to exclude patients from further investigation or to detect renal scarring (LR+ = 3.5, 95% CI: 2.5, 4.8). None of the tests investigated can accurately predict the development of renal scarring. The available evidence supports the consideration of contrast-enhanced ultrasound techniques for detecting vesico-ureteric reflux (VUR), as an alternative to micturating cystourethrography (MCUG) (LR+ = 14.1, 95% CI: 9.5, 20.8; LR- = 0.20, 95%CI: 0.13, 0.29); these techniques have the advantage of not requiring exposure to ionising radiation. Conclusion: There is no evidence to support the clinical effectiveness of routine investigation of children with confirmed UTI. Primary research on the effectiveness, in terms of improved patient outcome, of testing at all stages in the investigation of confirmed urinary tract infection is urgently required
Win-Win for Wind and Wildlife: A Vision to Facilitate Sustainable Development
Wind energy offers the potential to reduce carbon emissions while increasing energy independence and bolstering economic development. However, wind energy has a larger land footprint per Gigawatt (GW) than most other forms of energy production, making appropriate siting and mitigation particularly important. Species that require large unfragmented habitats and those known to avoid vertical structures are particularly at risk from wind development. Developing energy on disturbed lands rather than placing new developments within large and intact habitats would reduce cumulative impacts to wildlife. The U.S. Department of Energy estimates that it will take 241 GW of terrestrial based wind development on approximately 5 million hectares to reach 20% electricity production for the U.S. by 2030. We estimate there are ∼7,700 GW of potential wind energy available across the U.S., with ∼3,500 GW on disturbed lands. In addition, a disturbance-focused development strategy would avert the development of ∼2.3 million hectares of undisturbed lands while generating the same amount of energy as development based solely on maximizing wind potential. Wind subsidies targeted at favoring low-impact developments and creating avoidance and mitigation requirements that raise the costs for projects impacting sensitive lands could improve public value for both wind energy and biodiversity conservation
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